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Showing 1 to 12 of 16 entries
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Synthesis and Crystal and Electronic Structures of the Dinuclear Platinum Compounds [PEtPh(3)](2)[Pt(2)(&mgr;-PPh(2))(2)(C(6)F(5))(4)] and [Pt(2)(&mgr;-PPh(2))(2)(C(6)F(5))(4)]: A Computational Study by Density Functional Theory.

Inorganic chemistry

Alonso E, Casas JM, Cotton FA, Feng X, Forniés J, Fortuño C, Tomas M.
PMID: 11671247
Inorg Chem. 1999 Nov 01;38(22):5034-5040. doi: 10.1021/ic981437z.

The electrolytic behavior of the dinuclear complexes [NBu(4)](2)[MM'(&mgr;-PPh(2))(2)(C(6)F(5))(4)] (M = M' = Pt (1), Pd (1a); M = Pt, M' = Pd (1b)) has been studied, showing electrochemically irreversible oxidation and related reduction processes. The chemical oxidation of the...

Syntheses and Structures of the Complexes cis-[M(C(6)F(5))(2)(N&arcraise;X)] (M = Pd, Pt; N&arcraise;X = 2-Iodoaniline, 2-Benzoylpyridine) Containing N&arcraise;X Acting as a Didentate Chelating Ligand and Displaying I-->M or O-->M Interactions.

Inorganic chemistry

Casas JM, Falvello LR, Forniés J, Martín A.
PMID: 11666164
Inorg Chem. 1996 Jan 03;35(1):56-62. doi: 10.1021/ic950283+.

Complexes cis-[M(C(6)F(5))(2)(THF)(2)] (M = Pd, Pt) are weak Lewis acids and react with the halocarbon ligand 2-iodoaniline (R-I) yielding the corresponding cis-[M(C(6)F(5))(2)(R-I)] [M = Pd (1), Pt (2)]. In these complexes a (C-)I-M bond is present. The use of...

Synthesis of binuclear platinum complexes containing the ligands 8-naphthyridine, 2-aminopyridine, and 7-azaindolate. An experimental study of the steric hindrance of the bulky pentafluorophenyl ligands in the synthesis of binuclear complexes.

Inorganic chemistry

Casas JM, Diosdado BE, Forniés J, Martín A, Rueda AJ, Orpen AG.
PMID: 18767797
Inorg Chem. 2008 Oct 06;47(19):8767-75. doi: 10.1021/ic8006475. Epub 2008 Sep 04.

The bidentate N-donor ligands 2-aminopyridine (2-ampy), 7-azaindolate (aza) and 1,8-naphthyridine (napy) have been used to study the steric effect of pentafluorophenyl groups in the synthesis of binuclear platinum(II) complexes. The 2-ampy and aza ligands bridge two "Pt(C 6F 5)...

Pt-Ag clusters and their neutral mononuclear Pt(II) starting complexes: structural and luminescence studies.

Dalton transactions (Cambridge, England : 2003)

Forniés J, Sicilia V, Casas JM, Martín A, López JA, Larraz C, Borja P, Ovejero C.
PMID: 21311801
Dalton Trans. 2011 Mar 28;40(12):2898-912. doi: 10.1039/c0dt01451f. Epub 2011 Feb 11.

The mononuclear complexes [Pt(bzq)(S^S)] [S^S = pyrrolidinedithiocarbamate (pdtc 1), dimethyldithiocarbamate (dmdtc 2)] were prepared by reaction of [Pt(bzq)(NCMe)(2)]ClO(4) with an equimolecular amount of [NH(4)(pdtc)] and [Na(dmdtc)·2H(2)O] respectively in MeOH. Reactions of 1 and 2 with AgClO(4) in 1 :...

Gold(I) Fluorohalides: Theory and Experiment.

Chemistry (Weinheim an der Bergstrasse, Germany)

Baya M, Pérez-Bitrián A, Martínez-Salvador S, Casas JM, Menjón B, Orduna J.
PMID: 27933670
Chemistry. 2017 Jan 31;23(7):1512-1515. doi: 10.1002/chem.201605655. Epub 2017 Jan 12.

The anionic trifluoromethylgold(I) derivatives [CF

Hydrogen-bond mediation of supramolecular aggregation in neutral bis-(C6F5)Pt complexes with aromatic H-bond donating ligands. A synthetic and structural study.

Dalton transactions (Cambridge, England : 2003)

Casas JM, Diosdado BE, Falvello LR, Forniés J, Martin A, Rueda AJ.
PMID: 15514759
Dalton Trans. 2004 Sep 07;(17):2733-40. doi: 10.1039/B407284G. Epub 2004 Jul 23.

Six pentafluorophenylplatinum(II) complexes containing proton acceptor atoms (F) and pyridine-like aromatic ligands able to act as proton donors have been synthesized and characterized, with emphasis on the factors that mediate their supramolecular aggregation in the solid state--hydrogen bonds and...

Anionic Derivatives of Perfluorinated Trimethylgold.

Chemistry (Weinheim an der Bergstrasse, Germany)

Pérez-Bitrián A, Martínez-Salvador S, Baya M, Casas JM, Martín A, Menjón B, Orduna J.
PMID: 28317201
Chemistry. 2017 May 17;23(28):6919-6929. doi: 10.1002/chem.201700927. Epub 2017 Apr 24.

The homoleptic compound [PPh

Synthesis and Reactivity of (Pentafluorophenyl)platinate(II) Complexes with Bridging 1,8-Naphthyridine (napy) and X Ligands (X = C(6)F(5), OH, Cl, Br, I, SPh). Crystal Structure of [NBu(4)][Pt(2)(&mgr;-napy)(&mgr;-OH)(C(6)F(5))(4)].CHCl(3).

Inorganic chemistry

Ara I, Casas JM, Forniés J, Rueda AJ.
PMID: 11666927
Inorg Chem. 1996 Dec 04;35(25):7345-7349. doi: 10.1021/ic960092m.

By reaction of [NBu(4)](2)[Pt(2)(&mgr;-C(6)F(5))(2)(C(6)F(5))(4)] with 1,8-naphthyridine (napy), [NBu(4)][Pt(C(6)F(5))(3)(napy)] (1) is obtained. This compound reacts with cis-[Pt(C(6)F(5))(2)(THF)(2)] to give the dinuclear derivative [NBu(4)][Pt(2)(&mgr;-napy)(&mgr;-C(6)F(5))(C(6)F(5))(4)] (2). The reaction of several HX species with 2 results in the substitution of the bridging C(6)F(5)...

Luminescent benzoquinolate-isocyanide platinum(II) complexes: effect of Pt⋅⋅⋅Pt and π⋅⋅⋅π interactions on their photophysical properties.

Chemistry, an Asian journal

Forniés J, Sicilia V, Borja P, Casas JM, Díez A, Lalinde E, Larraz C, Martín A, Moreno MT.
PMID: 22997177
Chem Asian J. 2012 Dec;7(12):2813-23. doi: 10.1002/asia.201200585. Epub 2012 Sep 20.

The neutral compounds [Pt(bzq)(CN)(CNR)] (R = tBu (1), Xyl (2), 2-Np (3); bzq = benzoquinolate, Xyl = 2,6-dimethylphenyl, 2-Np = 2-napthyl) were isolated as the pure isomers with a trans-C(bzq),CNR configuration, as confirmed by (13)C{(1)H} NMR spectroscopy in the...

Platinum-mediated monohydration of SO.

Dalton transactions (Cambridge, England : 2003)

Gimeno-Prat A, Cortés-Sanchón A, Martín A, Baya M, Casas JM.
PMID: 30468447
Dalton Trans. 2018 Dec 04;47(47):16846-16849. doi: 10.1039/c8dt04169e.

The monohydration of SO2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and...

[Cutaneous metastasis as a diagnostic manifestation of malign pleural mesothelioma].

Anales del sistema sanitario de Navarra

Acha MV, Valcayo A, Pascual MP, Narvajas D, Sánchez C, Casas JM.
PMID: 12891440
An Sist Sanit Navar. 1997 Sep-Dec;20(3):399-404. doi: 10.23938/ASSN.0632.

No abstract available.

(CF.

Chemistry (Weinheim an der Bergstrasse, Germany)

Pérez-Bitrián A, Baya M, Casas JM, Falvello LR, Martín A, Menjón B.
PMID: 28800187
Chemistry. 2017 Oct 20;23(59):14918-14930. doi: 10.1002/chem.201703352. Epub 2017 Sep 26.

The Lewis acidity of perfluorinated trimethylgold (CF

Showing 1 to 12 of 16 entries