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Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides.

Organic & biomolecular chemistry

Sedenkova KN, Averina EB, Grishin YK, Kolodyazhnaya JV, Rybakov VB, Kuznetsova TS, Hughes A, Gomes GDP, Alabugin IV, Zefirov NS.
PMID: 29095467
Org Biomol Chem. 2017 Nov 15;15(44):9433-9441. doi: 10.1039/c7ob02463k.

Tricyclic bis-adducts of cyclohexa-1,4-diene with bromofluorocarbene and non-symmetric adducts with both bromofluoro- and dichlorocarbenes were synthesised selectively. The treatment of the bis-adducts with nitrating reagents in acetonitrile affords the products of heterocyclization of a sole dihalogenocyclopropane into 4-fluoropyrimidine N-oxide....

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Sedenkova KN, Averina EB, Grishin YK, et al. Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides. Org Biomol Chem. 2017;15(44):9433-9441doi: 10.1039/c7ob02463k.
Sedenkova, K. N., Averina, E. B., Grishin, Y. K., Kolodyazhnaya, J. V., Rybakov, V. B., Kuznetsova, T. S., Hughes, A., Gomes, G. D. P., Alabugin, I. V., & Zefirov, N. S. (2017). Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides. Organic & biomolecular chemistry, 15(44), 9433-9441. https://doi.org/10.1039/c7ob02463k
Sedenkova, Kseniya N, et al. "Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides." Organic & biomolecular chemistry vol. 15,44 (2017): 9433-9441. doi: https://doi.org/10.1039/c7ob02463k
Sedenkova KN, Averina EB, Grishin YK, Kolodyazhnaya JV, Rybakov VB, Kuznetsova TS, Hughes A, Gomes GDP, Alabugin IV, Zefirov NS. Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides. Org Biomol Chem. 2017 Nov 15;15(44):9433-9441. doi: 10.1039/c7ob02463k. PMID: 29095467.
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Showing 61 to 61 of 61 entries