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Femtosecond X-ray Spectroscopy Directly Quantifies Transient Excited-State Mixed Valency.

The journal of physical chemistry letters

Liekhus-Schmaltz C, Fox ZW, Andersen A, Kjaer KS, Alonso-Mori R, Biasin E, Carlstad J, Chollet M, Gaynor JD, Glownia JM, Hong K, Kroll T, Lee JH, Poulter BI, Reinhard M, Sokaras D, Zhang Y, Doumy G, March AM, Southworth SH, Mukamel S, Cordones AA, Schoenlein RW, Govind N, Khalil M.
PMID: 34985900
J Phys Chem Lett. 2022 Jan 13;13(1):378-386. doi: 10.1021/acs.jpclett.1c03613. Epub 2022 Jan 05.

Quantifying charge delocalization associated with short-lived photoexcited states of molecular complexes in solution remains experimentally challenging, requiring local element specific femtosecond experimental probes of time-evolving electron transfer. In this study, we quantify the evolving valence hole charge distribution in...

Showing 301 to 301 of 301 entries