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Spontaneous hierarchical assembly of crown ether-like macrocycles into nanofibers and microfibers induced by alkali-metal and ammonium salts.

Chemistry (Weinheim an der Bergstrasse, Germany)

Hui JK, Frischmann PD, Tso CH, Michal CA, Maclachlan MJ.
PMID: 20066701
Chemistry. 2010 Feb 22;16(8):2453-60. doi: 10.1002/chem.200902712.

Schiff base macrocycle 1, which has a crown ether like central pore, was combined with different alkali-metal and ammonium salts in chloroform, resulting in one-dimensional supramolecular aggregates. The ion-induced self-assembly was studied with solid-state NMR spectroscopy, transmission electron microscopy...

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Hui JK, Frischmann PD, Tso CH, et al. Spontaneous hierarchical assembly of crown ether-like macrocycles into nanofibers and microfibers induced by alkali-metal and ammonium salts. Chemistry. 2010;16(8):2453-60doi: 10.1002/chem.200902712.
Hui, J. K., Frischmann, P. D., Tso, C. H., Michal, C. A., & Maclachlan, M. J. (2010). Spontaneous hierarchical assembly of crown ether-like macrocycles into nanofibers and microfibers induced by alkali-metal and ammonium salts. Chemistry (Weinheim an der Bergstrasse, Germany), 16(8), 2453-60. https://doi.org/10.1002/chem.200902712
Hui, Joseph K-H, et al. "Spontaneous hierarchical assembly of crown ether-like macrocycles into nanofibers and microfibers induced by alkali-metal and ammonium salts." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 16,8 (2010): 2453-60. doi: https://doi.org/10.1002/chem.200902712
Hui JK, Frischmann PD, Tso CH, Michal CA, Maclachlan MJ. Spontaneous hierarchical assembly of crown ether-like macrocycles into nanofibers and microfibers induced by alkali-metal and ammonium salts. Chemistry. 2010 Feb 22;16(8):2453-60. doi: 10.1002/chem.200902712. PMID: 20066701.
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Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks.

Chemical communications (Cambridge, England)

Lorusso G, Palacios MA, Nichol GS, Brechin EK, Roubeau O, Evangelisti M.
PMID: 22729217
Chem Commun (Camb). 2012 Aug 07;48(61):7592-4. doi: 10.1039/c2cc33485b. Epub 2012 Jun 25.

The magnetothermal properties of a coordination polymer and a metal-organic framework (MOF) based on Gd(3+) ions are reported. An equally large cryogenic magnetocaloric effect (MCE) is found, irrespective of the dimensionality. This combined with their robustness makes them appealing...

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Lorusso G, Palacios MA, Nichol GS, et al. Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks. Chem Commun (Camb). 2012;48(61):7592-4doi: 10.1039/c2cc33485b.
Lorusso, G., Palacios, M. A., Nichol, G. S., Brechin, E. K., Roubeau, O., & Evangelisti, M. (2012). Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks. Chemical communications (Cambridge, England), 48(61), 7592-4. https://doi.org/10.1039/c2cc33485b
Lorusso, Giulia, et al. "Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks." Chemical communications (Cambridge, England) vol. 48,61 (2012): 7592-4. doi: https://doi.org/10.1039/c2cc33485b
Lorusso G, Palacios MA, Nichol GS, Brechin EK, Roubeau O, Evangelisti M. Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks. Chem Commun (Camb). 2012 Aug 07;48(61):7592-4. doi: 10.1039/c2cc33485b. Epub 2012 Jun 25. PMID: 22729217.
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Stage, treatment and outcomes for patients with breast cancer in British Columbia in 2002: a population-based cohort study.

CMAJ open

Davidson A, Chia S, Olson R, Nichol A, Speers C, Coldman AJ, Bajdik C, Woods R, Tyldesley S.
PMID: 25077115
CMAJ Open. 2013 Nov 07;1(4):E134-41. doi: 10.9778/cmajo.20130017. eCollection 2013 Oct.

BACKGROUND: There are very few long-term Canadian data on breast cancer outcomes by stage. We described the stage, treatment and outcomes of breast cancer at a population level for patients in British Columbia.METHODS: This population-based cohort study included almost...

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Davidson A, Chia S, Olson R, et al. Stage, treatment and outcomes for patients with breast cancer in British Columbia in 2002: a population-based cohort study. CMAJ Open. 2013;1(4):E134-41doi: 10.9778/cmajo.20130017.
Davidson, A., Chia, S., Olson, R., Nichol, A., Speers, C., Coldman, A. J., Bajdik, C., Woods, R., & Tyldesley, S. (2013). Stage, treatment and outcomes for patients with breast cancer in British Columbia in 2002: a population-based cohort study. CMAJ open, 1(4), E134-41. https://doi.org/10.9778/cmajo.20130017
Davidson, Ashley, et al. "Stage, treatment and outcomes for patients with breast cancer in British Columbia in 2002: a population-based cohort study." CMAJ open vol. 1,4 (2013): E134-41. doi: https://doi.org/10.9778/cmajo.20130017
Davidson A, Chia S, Olson R, Nichol A, Speers C, Coldman AJ, Bajdik C, Woods R, Tyldesley S. Stage, treatment and outcomes for patients with breast cancer in British Columbia in 2002: a population-based cohort study. CMAJ Open. 2013 Nov 07;1(4):E134-41. doi: 10.9778/cmajo.20130017. eCollection 2013 Oct. PMID: 25077115; PMCID: PMC3985980.
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Cell-laden microengineered pullulan methacrylate hydrogels promote cell proliferation and 3D cluster formation.

Soft matter

Bae H, Ahari AF, Shin H, Nichol JW, Hutson CB, Masaeli M, Kim SH, Aubin H, Yamanlar S, Khademhosseini A.
PMID: 21415929
Soft Matter. 2011 Jan 01;7(5):1903-1911. doi: 10.1039/C0SM00697A.

The ability to encapsulate cells in three-dimensional (3D) environments is potentially of benefit for tissue engineering and regenerative medicine. In this paper, we introduce pullulan methacrylate (PulMA) as a promising hydrogel platform for creating cell-laden microscale tissues. The hydration...

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Bae H, Ahari AF, Shin H, et al. Cell-laden microengineered pullulan methacrylate hydrogels promote cell proliferation and 3D cluster formation. Soft Matter. 2011;7(5):1903-1911doi: 10.1039/C0SM00697A.
Bae, H., Ahari, A. F., Shin, H., Nichol, J. W., Hutson, C. B., Masaeli, M., Kim, S. H., Aubin, H., Yamanlar, S., & Khademhosseini, A. (2011). Cell-laden microengineered pullulan methacrylate hydrogels promote cell proliferation and 3D cluster formation. Soft matter, 7(5), 1903-1911. https://doi.org/10.1039/C0SM00697A
Bae, Hojae, et al. "Cell-laden microengineered pullulan methacrylate hydrogels promote cell proliferation and 3D cluster formation." Soft matter vol. 7,5 (2011): 1903-1911. doi: https://doi.org/10.1039/C0SM00697A
Bae H, Ahari AF, Shin H, Nichol JW, Hutson CB, Masaeli M, Kim SH, Aubin H, Yamanlar S, Khademhosseini A. Cell-laden microengineered pullulan methacrylate hydrogels promote cell proliferation and 3D cluster formation. Soft Matter. 2011 Jan 01;7(5):1903-1911. doi: 10.1039/C0SM00697A. PMID: 21415929; PMCID: PMC3057074.
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Extending lead-free hybrid photovoltaic materials to new structures: thiazolium, aminothiazolium and imidazolium iodobismuthates.

Dalton transactions (Cambridge, England : 2003)

Li T, Wang Q, Nichol GS, Morrison CA, Han H, Hu Y, Robertson N.
PMID: 29741166
Dalton Trans. 2018 May 22;47(20):7050-7058. doi: 10.1039/c8dt00864g.

We report on the synthesis, crystal structures, optoelectronic properties and solar cell device studies of three novel organic-inorganic iodobismuthates - [C3H4NS]3[Bi2I9] ([TH]3[Bi2I9]), [C3H4N2]3[Bi2I9] ([IM]3[Bi2I9]) and [C3H5N2S][BiI4] ([AT][BiI4]) as lead-free light harvesters. [TH]3[Bi2I9] and [IM]3[Bi2I9] show zero-dimensional structures, whereas a...

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Li T, Wang Q, Nichol GS, et al. Extending lead-free hybrid photovoltaic materials to new structures: thiazolium, aminothiazolium and imidazolium iodobismuthates. Dalton Trans. 2018;47(20):7050-7058doi: 10.1039/c8dt00864g.
Li, T., Wang, Q., Nichol, G. S., Morrison, C. A., Han, H., Hu, Y., & Robertson, N. (2018). Extending lead-free hybrid photovoltaic materials to new structures: thiazolium, aminothiazolium and imidazolium iodobismuthates. Dalton transactions (Cambridge, England : 2003), 47(20), 7050-7058. https://doi.org/10.1039/c8dt00864g
Li, Tianyue, et al. "Extending lead-free hybrid photovoltaic materials to new structures: thiazolium, aminothiazolium and imidazolium iodobismuthates." Dalton transactions (Cambridge, England : 2003) vol. 47,20 (2018): 7050-7058. doi: https://doi.org/10.1039/c8dt00864g
Li T, Wang Q, Nichol GS, Morrison CA, Han H, Hu Y, Robertson N. Extending lead-free hybrid photovoltaic materials to new structures: thiazolium, aminothiazolium and imidazolium iodobismuthates. Dalton Trans. 2018 May 22;47(20):7050-7058. doi: 10.1039/c8dt00864g. PMID: 29741166.
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Severe Late Toxicity After Adjuvant Breast Radiotherapy in a Patient with a Germline Ataxia Telangiectasia Mutated Gene: Future Treatment Decisions.

Cureus

Dosani M, Schrader KA, Nichol A, Sun S, Shenkier T, Lohn Z, Aubertin G, Tyldesley S.
PMID: 28929041
Cureus. 2017 Jul 11;9(7):e1458. doi: 10.7759/cureus.1458.

Ataxia telangiectasia mutated (ATM) gene mutations may confer increased sensitivity to ionizing radiation and increased risk of late toxicity for cancer patients. We present the case of a 55-year-old female treated with adjuvant breast and regional nodal radiation following...

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Dosani M, Schrader KA, Nichol A, et al. Severe Late Toxicity After Adjuvant Breast Radiotherapy in a Patient with a Germline Ataxia Telangiectasia Mutated Gene: Future Treatment Decisions. Cureus. 2017;9(7):e1458doi: 10.7759/cureus.1458.
Dosani, M., Schrader, K. A., Nichol, A., Sun, S., Shenkier, T., Lohn, Z., Aubertin, G., & Tyldesley, S. (2017). Severe Late Toxicity After Adjuvant Breast Radiotherapy in a Patient with a Germline Ataxia Telangiectasia Mutated Gene: Future Treatment Decisions. Cureus, 9(7), e1458. https://doi.org/10.7759/cureus.1458
Dosani, Maryam, et al. "Severe Late Toxicity After Adjuvant Breast Radiotherapy in a Patient with a Germline Ataxia Telangiectasia Mutated Gene: Future Treatment Decisions." Cureus vol. 9,7 (2017): e1458. doi: https://doi.org/10.7759/cureus.1458
Dosani M, Schrader KA, Nichol A, Sun S, Shenkier T, Lohn Z, Aubertin G, Tyldesley S. Severe Late Toxicity After Adjuvant Breast Radiotherapy in a Patient with a Germline Ataxia Telangiectasia Mutated Gene: Future Treatment Decisions. Cureus. 2017 Jul 11;9(7):e1458. doi: 10.7759/cureus.1458. PMID: 28929041; PMCID: PMC5593749.
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Cages on a plane: a structural matrix for molecular 'sheets'.

Dalton transactions (Cambridge, England : 2003)

Fraser HWL, Nichol GS, Baldansuren A, McInnes EJL, Brechin EK.
PMID: 30338334
Dalton Trans. 2018 Nov 21;47(43):15530-15537. doi: 10.1039/c8dt03793k. Epub 2018 Oct 19.

A family of heterometallic Anderson-type 'wheels' of general formula [MM(hmp)

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Fraser HWL, Nichol GS, Baldansuren A, et al. Cages on a plane: a structural matrix for molecular 'sheets'. Dalton Trans. 2018;47(43):15530-15537doi: 10.1039/c8dt03793k.
Fraser, H. W. L., Nichol, G. S., Baldansuren, A., McInnes, E. J. L., & Brechin, E. K. (2018). Cages on a plane: a structural matrix for molecular 'sheets'. Dalton transactions (Cambridge, England : 2003), 47(43), 15530-15537. https://doi.org/10.1039/c8dt03793k
Fraser, Hector W L, et al. "Cages on a plane: a structural matrix for molecular 'sheets'." Dalton transactions (Cambridge, England : 2003) vol. 47,43 (2018): 15530-15537. doi: https://doi.org/10.1039/c8dt03793k
Fraser HWL, Nichol GS, Baldansuren A, McInnes EJL, Brechin EK. Cages on a plane: a structural matrix for molecular 'sheets'. Dalton Trans. 2018 Nov 21;47(43):15530-15537. doi: 10.1039/c8dt03793k. Epub 2018 Oct 19. PMID: 30338334.
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Bio-inspired Domino oxa-Michael/Diels-Alder/oxa-Michael Dimerization of para-Quinols.

Angewandte Chemie (International ed. in English)

Green NJ, Connolly CA, Rietdijk KPW, Nichol GS, Duarte F, Lawrence AL.
PMID: 29637681
Angew Chem Int Ed Engl. 2018 May 22;57(21):6198-6202. doi: 10.1002/anie.201802125. Epub 2018 Apr 25.

A bio-inspired, pyrrolidine-mediated, dimerization of para-quinols has been developed. It represents one of the most complex, yet general, dimerization reactions ever disclosed, selectively forming four new bonds, four new rings, and eight new contiguous stereogenic centres. The para-quinol starting...

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Green NJ, Connolly CA, Rietdijk KPW, et al. Bio-inspired Domino oxa-Michael/Diels-Alder/oxa-Michael Dimerization of para-Quinols. Angew Chem Int Ed Engl. 2018;57(21):6198-6202doi: 10.1002/anie.201802125.
Green, N. J., Connolly, C. A., Rietdijk, K. P. W., Nichol, G. S., Duarte, F., & Lawrence, A. L. (2018). Bio-inspired Domino oxa-Michael/Diels-Alder/oxa-Michael Dimerization of para-Quinols. Angewandte Chemie (International ed. in English), 57(21), 6198-6202. https://doi.org/10.1002/anie.201802125
Green, Nicholas J, et al. "Bio-inspired Domino oxa-Michael/Diels-Alder/oxa-Michael Dimerization of para-Quinols." Angewandte Chemie (International ed. in English) vol. 57,21 (2018): 6198-6202. doi: https://doi.org/10.1002/anie.201802125
Green NJ, Connolly CA, Rietdijk KPW, Nichol GS, Duarte F, Lawrence AL. Bio-inspired Domino oxa-Michael/Diels-Alder/oxa-Michael Dimerization of para-Quinols. Angew Chem Int Ed Engl. 2018 May 22;57(21):6198-6202. doi: 10.1002/anie.201802125. Epub 2018 Apr 25. PMID: 29637681.
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Corrigendum to "The physical mechanism of "inhomogeneous" magnetization transfer MRI" [J. Magn. Reson. 274 (2017) 125-136].

Journal of magnetic resonance (San Diego, Calif. : 1997)

Manning AP, Chang KL, MacKay AL, Michal CA.
PMID: 28750205
J Magn Reson. 2017 Sep;282:37. doi: 10.1016/j.jmr.2017.07.005. Epub 2017 Aug 01.

No abstract available.

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Manning AP, Chang KL, MacKay AL, et al. Corrigendum to "The physical mechanism of "inhomogeneous" magnetization transfer MRI" [J. Magn. Reson. 274 (2017) 125-136]. J Magn Reson. 2017;282:37doi: 10.1016/j.jmr.2017.07.005.
Manning, A. P., Chang, K. L., MacKay, A. L., & Michal, C. A. (2017). Corrigendum to "The physical mechanism of "inhomogeneous" magnetization transfer MRI" [J. Magn. Reson. 274 (2017) 125-136]. Journal of magnetic resonance (San Diego, Calif. : 1997), 28237. https://doi.org/10.1016/j.jmr.2017.07.005
Manning, Alan P, et al. "Corrigendum to "The physical mechanism of "inhomogeneous" magnetization transfer MRI" [J. Magn. Reson. 274 (2017) 125-136]." Journal of magnetic resonance (San Diego, Calif. : 1997) vol. 282 (2017): 37. doi: https://doi.org/10.1016/j.jmr.2017.07.005
Manning AP, Chang KL, MacKay AL, Michal CA. Corrigendum to "The physical mechanism of "inhomogeneous" magnetization transfer MRI" [J. Magn. Reson. 274 (2017) 125-136]. J Magn Reson. 2017 Sep;282:37. doi: 10.1016/j.jmr.2017.07.005. Epub 2017 Aug 01. PMID: 28750205.
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Ligand coordination modulates reductive elimination from aluminium(iii).

Dalton transactions (Cambridge, England : 2003)

Urwin SJ, Rogers DM, Nichol GS, Cowley MJ.
PMID: 27530604
Dalton Trans. 2016 Sep 21;45(35):13695-9. doi: 10.1039/c6dt02698b. Epub 2016 Aug 17.

Oxidative addition of inert bonds at low-valent main-group centres is becoming a major class of reactivity for these species. The reverse reaction, reductive elimination, is possible in some cases but far rarer. Here, we present a mechanistic study of...

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Urwin SJ, Rogers DM, Nichol GS, et al. Ligand coordination modulates reductive elimination from aluminium(iii). Dalton Trans. 2016;45(35):13695-9doi: 10.1039/c6dt02698b.
Urwin, S. J., Rogers, D. M., Nichol, G. S., & Cowley, M. J. (2016). Ligand coordination modulates reductive elimination from aluminium(iii). Dalton transactions (Cambridge, England : 2003), 45(35), 13695-9. https://doi.org/10.1039/c6dt02698b
Urwin, Stephanie J, et al. "Ligand coordination modulates reductive elimination from aluminium(iii)." Dalton transactions (Cambridge, England : 2003) vol. 45,35 (2016): 13695-9. doi: https://doi.org/10.1039/c6dt02698b
Urwin SJ, Rogers DM, Nichol GS, Cowley MJ. Ligand coordination modulates reductive elimination from aluminium(iii). Dalton Trans. 2016 Sep 21;45(35):13695-9. doi: 10.1039/c6dt02698b. Epub 2016 Aug 17. PMID: 27530604.
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[(1,2,5,6-η)-Cyclo-octa-1,5-diene]bis-(1-isopropyl-3-methyl-imidazolin-2-yl-idene)rhodium(I) tetra-fluorido-borate.

Acta crystallographica. Section E, Structure reports online

Nichol GS, Rajaseelan J, Walton DP, Rajaseelan E.
PMID: 22199629
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 01;67:m1860-1. doi: 10.1107/S1600536811049890. Epub 2011 Nov 30.

In the title compound, [Rh(C(8)H(12))(C(7)H(12)N(2))(2)]BF(4), the square-planar Rh complex cation and the BF(4) (-) anion are both bis-ected by a crystallographic twofold rotation axis. The Rh and B atoms lie on this axis and all others are in general...

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Nichol GS, Rajaseelan J, Walton DP, et al. [(1,2,5,6-η)-Cyclo-octa-1,5-diene]bis-(1-isopropyl-3-methyl-imidazolin-2-yl-idene)rhodium(I) tetra-fluorido-borate. Acta Crystallogr Sect E Struct Rep Online. 2011;67:m1860-1doi: 10.1107/S1600536811049890.
Nichol, G. S., Rajaseelan, J., Walton, D. P., & Rajaseelan, E. (2011). [(1,2,5,6-η)-Cyclo-octa-1,5-diene]bis-(1-isopropyl-3-methyl-imidazolin-2-yl-idene)rhodium(I) tetra-fluorido-borate. Acta crystallographica. Section E, Structure reports online, 67m1860-1. https://doi.org/10.1107/S1600536811049890
Nichol, Gary S, et al. "[(1,2,5,6-η)-Cyclo-octa-1,5-diene]bis-(1-isopropyl-3-methyl-imidazolin-2-yl-idene)rhodium(I) tetra-fluorido-borate." Acta crystallographica. Section E, Structure reports online vol. 67 (2011): m1860-1. doi: https://doi.org/10.1107/S1600536811049890
Nichol GS, Rajaseelan J, Walton DP, Rajaseelan E. [(1,2,5,6-η)-Cyclo-octa-1,5-diene]bis-(1-isopropyl-3-methyl-imidazolin-2-yl-idene)rhodium(I) tetra-fluorido-borate. Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 01;67:m1860-1. doi: 10.1107/S1600536811049890. Epub 2011 Nov 30. PMID: 22199629; PMCID: PMC3238752.
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Visualizing Kinetically Robust Co.

Journal of the American Chemical Society

Burke BP, Grantham W, Burke MJ, Nichol GS, Roberts D, Renard I, Hargreaves R, Cawthorne C, Archibald SJ, Lusby PJ.
PMID: 30485075
J Am Chem Soc. 2018 Dec 12;140(49):16877-16881. doi: 10.1021/jacs.8b09582. Epub 2018 Dec 03.

Noncovalent encapsulation is an attractive approach for modifying the efficacy and physiochemical properties of both therapeutic and diagnostic species. Abiotic self-assembled constructs have shown promise, yet many hurdles between in vitro and (pre)clinical studies remain, not least the challenges...

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Burke BP, Grantham W, Burke MJ, et al. Visualizing Kinetically Robust Co. J Am Chem Soc. 2018;140(49):16877-16881doi: 10.1021/jacs.8b09582.
Burke, B. P., Grantham, W., Burke, M. J., Nichol, G. S., Roberts, D., Renard, I., Hargreaves, R., Cawthorne, C., Archibald, S. J., & Lusby, P. J. (2018). Visualizing Kinetically Robust Co. Journal of the American Chemical Society, 140(49), 16877-16881. https://doi.org/10.1021/jacs.8b09582
Burke, Benjamin P, et al. "Visualizing Kinetically Robust Co." Journal of the American Chemical Society vol. 140,49 (2018): 16877-16881. doi: https://doi.org/10.1021/jacs.8b09582
Burke BP, Grantham W, Burke MJ, Nichol GS, Roberts D, Renard I, Hargreaves R, Cawthorne C, Archibald SJ, Lusby PJ. Visualizing Kinetically Robust Co. J Am Chem Soc. 2018 Dec 12;140(49):16877-16881. doi: 10.1021/jacs.8b09582. Epub 2018 Dec 03. PMID: 30485075.
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