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Detection of positive and negative ions from a flowing atmospheric pressure afterglow using a Mattauch-Herzog mass spectrograph equipped with a Faraday-strip array detector.

Journal of the American Society for Mass Spectrometry

Schilling GD, Shelley JT, Barnes JH, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM.
PMID: 19889553
J Am Soc Mass Spectrom. 2010 Jan;21(1):97-103. doi: 10.1016/j.jasms.2009.09.009. Epub 2009 Sep 20.

An ambient desorption/ionization (ADI) source, known as the flowing atmospheric pressure afterglow (FAPA), has been coupled to a Mattauch-Herzog mass spectrograph (MHMS) equipped with a focal plane camera (FPC) array detector. The FAPA ionization source enables direct mass spectral...

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Schilling GD, Shelley JT, Barnes JH, et al. Detection of positive and negative ions from a flowing atmospheric pressure afterglow using a Mattauch-Herzog mass spectrograph equipped with a Faraday-strip array detector. J Am Soc Mass Spectrom. 2009;21(1):97-103doi: 10.1016/j.jasms.2009.09.009.
Schilling, G. D., Shelley, J. T., Barnes, J. H., Sperline, R. P., Denton, M. B., Barinaga, C. J., Koppenaal, D. W., & Hieftje, G. M. (2010). Detection of positive and negative ions from a flowing atmospheric pressure afterglow using a Mattauch-Herzog mass spectrograph equipped with a Faraday-strip array detector. Journal of the American Society for Mass Spectrometry, 21(1), 97-103. https://doi.org/10.1016/j.jasms.2009.09.009
Schilling, Gregory D, et al. "Detection of positive and negative ions from a flowing atmospheric pressure afterglow using a Mattauch-Herzog mass spectrograph equipped with a Faraday-strip array detector." Journal of the American Society for Mass Spectrometry vol. 21,1 (2010): 97-103. doi: https://doi.org/10.1016/j.jasms.2009.09.009
Schilling GD, Shelley JT, Barnes JH, Sperline RP, Denton MB, Barinaga CJ, Koppenaal DW, Hieftje GM. Detection of positive and negative ions from a flowing atmospheric pressure afterglow using a Mattauch-Herzog mass spectrograph equipped with a Faraday-strip array detector. J Am Soc Mass Spectrom. 2010 Jan;21(1):97-103. doi: 10.1016/j.jasms.2009.09.009. Epub 2009 Sep 20. PMID: 19889553.
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Metal-promoted nucleophilic addition and cyclization of diamines with dicyanonitrosomethanide, [C(CN)2(NO)]-.

Chemistry, an Asian journal

Chesman AS, Turner DR, Deacon GB, Batten SR.
PMID: 19384902
Chem Asian J. 2009 May 04;4(5):761-9. doi: 10.1002/asia.200800323.

The metal-promoted nucleophilic addition of diaminoalkanes to dicyanonitrosomethanide, C(CN)2(NO)- (dcnm), and subsequent cyclization has been utilized in the synthesis of novel anionic species. The addition and cyclization of 1,2-diaminoethane (en) to both nitrile groups of dcnm forms the anion...

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Chesman AS, Turner DR, Deacon GB, et al. Metal-promoted nucleophilic addition and cyclization of diamines with dicyanonitrosomethanide, [C(CN)2(NO)]-. Chem Asian J. 2009;4(5):761-9doi: 10.1002/asia.200800323.
Chesman, A. S., Turner, D. R., Deacon, G. B., & Batten, S. R. (2009). Metal-promoted nucleophilic addition and cyclization of diamines with dicyanonitrosomethanide, [C(CN)2(NO)]-. Chemistry, an Asian journal, 4(5), 761-9. https://doi.org/10.1002/asia.200800323
Chesman, Anthony S R, et al. "Metal-promoted nucleophilic addition and cyclization of diamines with dicyanonitrosomethanide, [C(CN)2(NO)]-." Chemistry, an Asian journal vol. 4,5 (2009): 761-9. doi: https://doi.org/10.1002/asia.200800323
Chesman AS, Turner DR, Deacon GB, Batten SR. Metal-promoted nucleophilic addition and cyclization of diamines with dicyanonitrosomethanide, [C(CN)2(NO)]-. Chem Asian J. 2009 May 04;4(5):761-9. doi: 10.1002/asia.200800323. PMID: 19384902.
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Bidirectional "ping-pong" energy transfer and 3000-fold lifetime enhancement in a Re(I) charge transfer complex.

Inorganic chemistry

Yarnell JE, Deaton JC, McCusker CE, Castellano FN.
PMID: 21761837
Inorg Chem. 2011 Aug 15;50(16):7820-30. doi: 10.1021/ic200974h. Epub 2011 Jul 15.

The synthesis and photophysics of a new Re(I)-carbonyl diimine complex, Re(PNI-phen)(CO)(3)Cl, where the PNI-phen is N-(1,10-phenanthroline)-4-(1-piperidinyl)naphthalene-1,8-dicarboximide is reported. The metal-to-ligand charge transfer (MLCT) emission lifetime was increased approximately 3000-fold at room temperature with respect to that of the model...

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Yarnell JE, Deaton JC, McCusker CE, et al. Bidirectional "ping-pong" energy transfer and 3000-fold lifetime enhancement in a Re(I) charge transfer complex. Inorg Chem. 2011;50(16):7820-30doi: 10.1021/ic200974h.
Yarnell, J. E., Deaton, J. C., McCusker, C. E., & Castellano, F. N. (2011). Bidirectional "ping-pong" energy transfer and 3000-fold lifetime enhancement in a Re(I) charge transfer complex. Inorganic chemistry, 50(16), 7820-30. https://doi.org/10.1021/ic200974h
Yarnell, James E, et al. "Bidirectional "ping-pong" energy transfer and 3000-fold lifetime enhancement in a Re(I) charge transfer complex." Inorganic chemistry vol. 50,16 (2011): 7820-30. doi: https://doi.org/10.1021/ic200974h
Yarnell JE, Deaton JC, McCusker CE, Castellano FN. Bidirectional "ping-pong" energy transfer and 3000-fold lifetime enhancement in a Re(I) charge transfer complex. Inorg Chem. 2011 Aug 15;50(16):7820-30. doi: 10.1021/ic200974h. Epub 2011 Jul 15. PMID: 21761837.
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The chemistry and complexes of small cyano anions.

Chemical communications (Cambridge, England)

Turner DR, Chesman AS, Murray KS, Deacon GB, Batten SR.
PMID: 21773626
Chem Commun (Camb). 2011 Oct 07;47(37):10189-210. doi: 10.1039/c1cc11909e. Epub 2011 Jul 20.

The chemistry of the anions dicyanamide and tricyanomethanide (dca and tcm, respectively) has produced a plethora of discoveries over the past few decades, particularly in relation to transition-metal coordination polymers with magnetic coupling. Over recent years there have been...

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Turner DR, Chesman AS, Murray KS, et al. The chemistry and complexes of small cyano anions. Chem Commun (Camb). 2011;47(37):10189-210doi: 10.1039/c1cc11909e.
Turner, D. R., Chesman, A. S., Murray, K. S., Deacon, G. B., & Batten, S. R. (2011). The chemistry and complexes of small cyano anions. Chemical communications (Cambridge, England), 47(37), 10189-210. https://doi.org/10.1039/c1cc11909e
Turner, David R, et al. "The chemistry and complexes of small cyano anions." Chemical communications (Cambridge, England) vol. 47,37 (2011): 10189-210. doi: https://doi.org/10.1039/c1cc11909e
Turner DR, Chesman AS, Murray KS, Deacon GB, Batten SR. The chemistry and complexes of small cyano anions. Chem Commun (Camb). 2011 Oct 07;47(37):10189-210. doi: 10.1039/c1cc11909e. Epub 2011 Jul 20. PMID: 21773626.
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Agitation in pediatric brain injury: a useful communication or a hurdle to overcome?.

NeuroRehabilitation

Deaton AV, Metzger S, Maillet Wheeler A.
PMID: 24525576
NeuroRehabilitation. 1995;5(4):317-21. doi: 10.3233/NRE-1995-5406.

Children and adolescents who sustain brain injuries often experience episodic agitation during the course of their recovery. In the early stages after an injury, agitation may be the direct effect of the neurological insult itself as well as the...

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Deaton AV, Metzger S, Maillet Wheeler A. Agitation in pediatric brain injury: a useful communication or a hurdle to overcome?. NeuroRehabilitation. 1995;5(4):317-21doi: 10.3233/NRE-1995-5406.
Deaton, A. V., Metzger, S., & Maillet Wheeler, A. (1995). Agitation in pediatric brain injury: a useful communication or a hurdle to overcome?. NeuroRehabilitation, 5(4), 317-21. https://doi.org/10.3233/NRE-1995-5406
Deaton, A V, et al. "Agitation in pediatric brain injury: a useful communication or a hurdle to overcome?." NeuroRehabilitation vol. 5,4 (1995): 317-21. doi: https://doi.org/10.3233/NRE-1995-5406
Deaton AV, Metzger S, Maillet Wheeler A. Agitation in pediatric brain injury: a useful communication or a hurdle to overcome?. NeuroRehabilitation. 1995;5(4):317-21. doi: 10.3233/NRE-1995-5406. PMID: 24525576.
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Lanthanoid-based ionic liquids incorporating the dicyanonitrosomethanide anion.

Chemistry (Weinheim an der Bergstrasse, Germany)

Chesman AS, Yang M, Spiccia ND, Deacon GB, Batten SR, Mudring AV.
PMID: 22744976
Chemistry. 2012 Jul 27;18(31):9580-9. doi: 10.1002/chem.201103379. Epub 2012 Jun 28.

A series of low-melting-point salts with hexakisdicyanonitrosomethanidolanthanoidate anions has been synthesised and characterised: (C(2) mim)(3) [Ln(dcnm)(6)] (1 Ln; 1 Ln=1 La, 1 Ce, 1 Pr, 1 Nd), (C(2) C(1) mim)(3) [Pr(dcnm)(6)] (2 Pr), (C(4) C(1) pyr)(3) [Ce(dcnm)(6)] (3 Ce),...

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Chesman AS, Yang M, Spiccia ND, et al. Lanthanoid-based ionic liquids incorporating the dicyanonitrosomethanide anion. Chemistry. 2012;18(31):9580-9doi: 10.1002/chem.201103379.
Chesman, A. S., Yang, M., Spiccia, N. D., Deacon, G. B., Batten, S. R., & Mudring, A. V. (2012). Lanthanoid-based ionic liquids incorporating the dicyanonitrosomethanide anion. Chemistry (Weinheim an der Bergstrasse, Germany), 18(31), 9580-9. https://doi.org/10.1002/chem.201103379
Chesman, Anthony S R, et al. "Lanthanoid-based ionic liquids incorporating the dicyanonitrosomethanide anion." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 18,31 (2012): 9580-9. doi: https://doi.org/10.1002/chem.201103379
Chesman AS, Yang M, Spiccia ND, Deacon GB, Batten SR, Mudring AV. Lanthanoid-based ionic liquids incorporating the dicyanonitrosomethanide anion. Chemistry. 2012 Jul 27;18(31):9580-9. doi: 10.1002/chem.201103379. Epub 2012 Jun 28. PMID: 22744976.
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Direct reaction of iodine-activated lanthanoid metals with 2,6-diisopropylphenol.

Dalton transactions (Cambridge, England : 2003)

Hamidi S, Deacon GB, Junk PC, Neumann P.
PMID: 22315047
Dalton Trans. 2012 Mar 28;41(12):3541-52. doi: 10.1039/c2dt11752e. Epub 2012 Feb 08.

Rare earth metals activated with ca. 2% iodine react directly with 2,6-diisopropylphenol (HOdip) in tetrahydrofuran (thf), 1,2-dimethoxyethane (dme), and dig-dme (dig = di(2-methoxyethyl) ether) to give solvated phenolate complexes [Ln(Odip)(3)(thf)(n)] (Ln = La, Nd, n = 3; Ln =...

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Hamidi S, Deacon GB, Junk PC, et al. Direct reaction of iodine-activated lanthanoid metals with 2,6-diisopropylphenol. Dalton Trans. 2012;41(12):3541-52doi: 10.1039/c2dt11752e.
Hamidi, S., Deacon, G. B., Junk, P. C., & Neumann, P. (2012). Direct reaction of iodine-activated lanthanoid metals with 2,6-diisopropylphenol. Dalton transactions (Cambridge, England : 2003), 41(12), 3541-52. https://doi.org/10.1039/c2dt11752e
Hamidi, Shima, et al. "Direct reaction of iodine-activated lanthanoid metals with 2,6-diisopropylphenol." Dalton transactions (Cambridge, England : 2003) vol. 41,12 (2012): 3541-52. doi: https://doi.org/10.1039/c2dt11752e
Hamidi S, Deacon GB, Junk PC, Neumann P. Direct reaction of iodine-activated lanthanoid metals with 2,6-diisopropylphenol. Dalton Trans. 2012 Mar 28;41(12):3541-52. doi: 10.1039/c2dt11752e. Epub 2012 Feb 08. PMID: 22315047.
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Synthesis and characterisation of alkaline earth bis(diphenylphosphano)metallocene complexes and heterobimetallic alkaline earth metal/platinum(II) complexes [Ae(thf)(x)(η5-C5H4PPh2)2Pt(Me)2] (Ae = Ca, Sr, Ba).

Dalton transactions (Cambridge, England : 2003)

Daniels DP, Deacon GB, Harakat D, Jaroschik F, Junk PC.
PMID: 22020558
Dalton Trans. 2012 Jan 07;41(1):267-77. doi: 10.1039/c1dt11324k. Epub 2011 Oct 21.

A series of alkaline earth metallocene complexes carrying the diphenylphosphanocyclopentadienyl ligand, [Ae(L)(x)(η(5)-C(5)H(4)PPh(2))(2)] (Ae = Ca, L = thf, x = 1 (6a); Ae = Ca, L = dme, x = 1 (6b); Ae = Sr, L = thf, x...

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Daniels DP, Deacon GB, Harakat D, et al. Synthesis and characterisation of alkaline earth bis(diphenylphosphano)metallocene complexes and heterobimetallic alkaline earth metal/platinum(II) complexes [Ae(thf)(x)(η5-C5H4PPh2)2Pt(Me)2] (Ae = Ca, Sr, Ba). Dalton Trans. 2011;41(1):267-77doi: 10.1039/c1dt11324k.
Daniels, D. P., Deacon, G. B., Harakat, D., Jaroschik, F., & Junk, P. C. (2012). Synthesis and characterisation of alkaline earth bis(diphenylphosphano)metallocene complexes and heterobimetallic alkaline earth metal/platinum(II) complexes [Ae(thf)(x)(η5-C5H4PPh2)2Pt(Me)2] (Ae = Ca, Sr, Ba). Dalton transactions (Cambridge, England : 2003), 41(1), 267-77. https://doi.org/10.1039/c1dt11324k
Daniels, Daisy P, et al. "Synthesis and characterisation of alkaline earth bis(diphenylphosphano)metallocene complexes and heterobimetallic alkaline earth metal/platinum(II) complexes [Ae(thf)(x)(η5-C5H4PPh2)2Pt(Me)2] (Ae = Ca, Sr, Ba)." Dalton transactions (Cambridge, England : 2003) vol. 41,1 (2012): 267-77. doi: https://doi.org/10.1039/c1dt11324k
Daniels DP, Deacon GB, Harakat D, Jaroschik F, Junk PC. Synthesis and characterisation of alkaline earth bis(diphenylphosphano)metallocene complexes and heterobimetallic alkaline earth metal/platinum(II) complexes [Ae(thf)(x)(η5-C5H4PPh2)2Pt(Me)2] (Ae = Ca, Sr, Ba). Dalton Trans. 2012 Jan 07;41(1):267-77. doi: 10.1039/c1dt11324k. Epub 2011 Oct 21. PMID: 22020558.
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A Striking, Multifaceted, Decalithium Aggregate with Carbanion, Organoamide, and Alkoxide Functionalities.

Angewandte Chemie (International ed. in English)

Andrews PC, Deacon GB, Forsyth CM, Scott NM.
PMID: 29712201
Angew Chem Int Ed Engl. 2001 Jun 01;40(11):2108-2111. doi: 10.1002/1521-3773(20010601)40:11<2108::AID-ANIE2108>3.0.CO;2-C.

The three most important "superbase" anionic building blocks are contained in the striking decalithium aggregate in the structure of which a single lithium atom is surrounded solely by an amide, an alkoxide, and a carbanion.

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Andrews PC, Deacon GB, Forsyth CM, et al. A Striking, Multifaceted, Decalithium Aggregate with Carbanion, Organoamide, and Alkoxide Functionalities. Angew Chem Int Ed Engl. 2001;40(11):2108-2111doi: 10.1002/1521-3773(20010601)40:11<2108::AID-ANIE2108>3.0.CO;2-C.
Andrews, P. C., Deacon, G. B., Forsyth, C. M., & Scott, N. M. (2001). A Striking, Multifaceted, Decalithium Aggregate with Carbanion, Organoamide, and Alkoxide Functionalities. Angewandte Chemie (International ed. in English), 40(11), 2108-2111. https://doi.org/10.1002/1521-3773(20010601)40:11<2108::AID-ANIE2108>3.0.CO;2-C
Andrews, Philip C, et al. "A Striking, Multifaceted, Decalithium Aggregate with Carbanion, Organoamide, and Alkoxide Functionalities." Angewandte Chemie (International ed. in English) vol. 40,11 (2001): 2108-2111. doi: https://doi.org/10.1002/1521-3773(20010601)40:11<2108::AID-ANIE2108>3.0.CO;2-C
Andrews PC, Deacon GB, Forsyth CM, Scott NM. A Striking, Multifaceted, Decalithium Aggregate with Carbanion, Organoamide, and Alkoxide Functionalities. Angew Chem Int Ed Engl. 2001 Jun 01;40(11):2108-2111. doi: 10.1002/1521-3773(20010601)40:11<2108::AID-ANIE2108>3.0.CO;2-C. PMID: 29712201.
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Supramolecular Architecture and a New Mode of Pyrazolate Coordination (η.

Angewandte Chemie (International ed. in English)

Deacon GB, Delbridge EE, Forsyth CM.
PMID: 29711199
Angew Chem Int Ed Engl. 1999 Jun 14;38(12):1766-1767. doi: 10.1002/(SICI)1521-3773(19990614)38:12<1766::AID-ANIE1766>3.0.CO;2-I.

A linear supramoleculecular array of anions and cations is present in the solvent-free potassium salt of the homoleptic erbium pyrazolate complex [K{Er(η

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Deacon GB, Delbridge EE, Forsyth CM. Supramolecular Architecture and a New Mode of Pyrazolate Coordination (η. Angew Chem Int Ed Engl. 1999;38(12):1766-1767doi: 10.1002/(SICI)1521-3773(19990614)38:12<1766::AID-ANIE1766>3.0.CO;2-I.
Deacon, G. B., Delbridge, E. E., & Forsyth, C. M. (1999). Supramolecular Architecture and a New Mode of Pyrazolate Coordination (η. Angewandte Chemie (International ed. in English), 38(12), 1766-1767. https://doi.org/10.1002/(SICI)1521-3773(19990614)38:12<1766::AID-ANIE1766>3.0.CO;2-I
Deacon, Glen B, et al. "Supramolecular Architecture and a New Mode of Pyrazolate Coordination (η." Angewandte Chemie (International ed. in English) vol. 38,12 (1999): 1766-1767. doi: https://doi.org/10.1002/(SICI)1521-3773(19990614)38:12<1766::AID-ANIE1766>3.0.CO;2-I
Deacon GB, Delbridge EE, Forsyth CM. Supramolecular Architecture and a New Mode of Pyrazolate Coordination (η. Angew Chem Int Ed Engl. 1999 Jun 14;38(12):1766-1767. doi: 10.1002/(SICI)1521-3773(19990614)38:12<1766::AID-ANIE1766>3.0.CO;2-I. PMID: 29711199.
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Electron Delocalization in Spectroelectrochemically and Computationally Characterized [Pt{(.

Inorganic chemistry

Ojha R, Boas JF, Best SP, Canty AJ, Junk PC, Deacon GB, Bond AM.
PMID: 34851646
Inorg Chem. 2021 Dec 01; doi: 10.1021/acs.inorgchem.1c02682. Epub 2021 Dec 01.

[Pt{(

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Ojha R, Boas JF, Best SP, et al. Electron Delocalization in Spectroelectrochemically and Computationally Characterized [Pt{(. Inorg Chem. 2021;doi: 10.1021/acs.inorgchem.1c02682.
Ojha, R., Boas, J. F., Best, S. P., Canty, A. J., Junk, P. C., Deacon, G. B., & Bond, A. M. (2021). Electron Delocalization in Spectroelectrochemically and Computationally Characterized [Pt{(. Inorganic chemistry, . https://doi.org/10.1021/acs.inorgchem.1c02682
Ojha, Ruchika, et al. "Electron Delocalization in Spectroelectrochemically and Computationally Characterized [Pt{(." Inorganic chemistry vol. (2021). doi: https://doi.org/10.1021/acs.inorgchem.1c02682
Ojha R, Boas JF, Best SP, Canty AJ, Junk PC, Deacon GB, Bond AM. Electron Delocalization in Spectroelectrochemically and Computationally Characterized [Pt{(. Inorg Chem. 2021 Dec 01; doi: 10.1021/acs.inorgchem.1c02682. Epub 2021 Dec 01. PMID: 34851646.
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Europium is Different: Solvent and Ligand Effects on Oxidation State Outcomes and C-F Activation in Reactions Between Europium Metal and Pentafluorophenylsilver.

Chemistry (Weinheim an der Bergstrasse, Germany)

Guo Z, Blair VL, Deacon GB, Junk PC.
PMID: 34859510
Chemistry. 2021 Dec 02; doi: 10.1002/chem.202103865. Epub 2021 Dec 02.

Unique outcomes have emerged from the redox transmetallation/ protolysis (RTP) reactions of europium metal with [Ag(C

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Guo Z, Blair VL, Deacon GB, et al. Europium is Different: Solvent and Ligand Effects on Oxidation State Outcomes and C-F Activation in Reactions Between Europium Metal and Pentafluorophenylsilver. Chemistry. 2021;doi: 10.1002/chem.202103865.
Guo, Z., Blair, V. L., Deacon, G. B., & Junk, P. C. (2021). Europium is Different: Solvent and Ligand Effects on Oxidation State Outcomes and C-F Activation in Reactions Between Europium Metal and Pentafluorophenylsilver. Chemistry (Weinheim an der Bergstrasse, Germany), . https://doi.org/10.1002/chem.202103865
Guo, Zhifang, et al. "Europium is Different: Solvent and Ligand Effects on Oxidation State Outcomes and C-F Activation in Reactions Between Europium Metal and Pentafluorophenylsilver." Chemistry (Weinheim an der Bergstrasse, Germany) vol. (2021). doi: https://doi.org/10.1002/chem.202103865
Guo Z, Blair VL, Deacon GB, Junk PC. Europium is Different: Solvent and Ligand Effects on Oxidation State Outcomes and C-F Activation in Reactions Between Europium Metal and Pentafluorophenylsilver. Chemistry. 2021 Dec 02; doi: 10.1002/chem.202103865. Epub 2021 Dec 02. PMID: 34859510.
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