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Aromaticity and aminopyrroles: desmotropy and solution tautomerism of 1H-pyrrol-3-aminium and 1H-pyrrol-3(2H)-iminium cation: a stable σ-complex.

The Journal of organic chemistry

De Rosa M, Arnold D.
PMID: 23272640
J Org Chem. 2013 Feb 01;78(3):1107-12. doi: 10.1021/jo302457y. Epub 2013 Jan 10.

Protonation of 3-aminopyrrole at C-2 gave the σ-complex 1H-pyrrol-3(2H)-iminium cation, whereas protonation at the exoamino group gave its 1H-pyrrol-3-aminium tautomer. Both tautomers were isolated as their respective tetrakis(pentafluorophenyl)borate salt, an example of desmotropy. In solution, the NH(3)-tautomer was favored...

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De Rosa M, Arnold D. Aromaticity and aminopyrroles: desmotropy and solution tautomerism of 1H-pyrrol-3-aminium and 1H-pyrrol-3(2H)-iminium cation: a stable σ-complex. J Org Chem. 2013;78(3):1107-12doi: 10.1021/jo302457y.
De Rosa, M., & Arnold, D. (2013). Aromaticity and aminopyrroles: desmotropy and solution tautomerism of 1H-pyrrol-3-aminium and 1H-pyrrol-3(2H)-iminium cation: a stable σ-complex. The Journal of organic chemistry, 78(3), 1107-12. https://doi.org/10.1021/jo302457y
De Rosa, Michael, and Arnold, David. "Aromaticity and aminopyrroles: desmotropy and solution tautomerism of 1H-pyrrol-3-aminium and 1H-pyrrol-3(2H)-iminium cation: a stable σ-complex." The Journal of organic chemistry vol. 78,3 (2013): 1107-12. doi: https://doi.org/10.1021/jo302457y
De Rosa M, Arnold D. Aromaticity and aminopyrroles: desmotropy and solution tautomerism of 1H-pyrrol-3-aminium and 1H-pyrrol-3(2H)-iminium cation: a stable σ-complex. J Org Chem. 2013 Feb 01;78(3):1107-12. doi: 10.1021/jo302457y. Epub 2013 Jan 10. PMID: 23272640.
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Chemical exposures at hazardous waste sites: Experiences from the United States and Poland.

Environmental toxicology and pharmacology

Pohl HR, Tarkowski S, Buczynska A, Fay M, De Rosa CT.
PMID: 21783864
Environ Toxicol Pharmacol. 2008 May;25(3):283-91. doi: 10.1016/j.etap.2007.12.005. Epub 2007 Dec 23.

The U.S. Agency for Toxic Substances and Disease Registry (ATSDR) and the Polish Nofer Institute of Occupational Health collaborate on issues related to hazardous chemical exposure at or near hazardous waste sites. This paper outlines the scope of hazardous...

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Pohl HR, Tarkowski S, Buczynska A, et al. Chemical exposures at hazardous waste sites: Experiences from the United States and Poland. Environ Toxicol Pharmacol. 2007;25(3):283-91doi: 10.1016/j.etap.2007.12.005.
Pohl, H. R., Tarkowski, S., Buczynska, A., Fay, M., & De Rosa, C. T. (2008). Chemical exposures at hazardous waste sites: Experiences from the United States and Poland. Environmental toxicology and pharmacology, 25(3), 283-91. https://doi.org/10.1016/j.etap.2007.12.005
Pohl, Hana R, et al. "Chemical exposures at hazardous waste sites: Experiences from the United States and Poland." Environmental toxicology and pharmacology vol. 25,3 (2008): 283-91. doi: https://doi.org/10.1016/j.etap.2007.12.005
Pohl HR, Tarkowski S, Buczynska A, Fay M, De Rosa CT. Chemical exposures at hazardous waste sites: Experiences from the United States and Poland. Environ Toxicol Pharmacol. 2008 May;25(3):283-91. doi: 10.1016/j.etap.2007.12.005. Epub 2007 Dec 23. PMID: 21783864.
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[Informed consent in psychotherapy: conceptual and complexity in clinical practice].

Vertex (Buenos Aires, Argentina)

De Rosa L.
PMID: 24255897
Vertex. 2013 May-Jun;24(109):165-8.

The objective of this literature review is to introduce the concept of informed consent. It outlines the definition of informed consent, which are the component parts and technical importance particularly in the field of psychotherapy applied to mental disorders....

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De Rosa L. El consentimiento informado en psicoterapia: revisión conceptual y complejidad en la práctica clínica. [Informed consent in psychotherapy: conceptual and complexity in clinical practice]. Vertex. 2013;24(109):165-8
De Rosa, L. (2013). El consentimiento informado en psicoterapia: revisión conceptual y complejidad en la práctica clínica. [Informed consent in psychotherapy: conceptual and complexity in clinical practice]. Vertex (Buenos Aires, Argentina), 24(109), 165-8.
De Rosa, Lorena. "El consentimiento informado en psicoterapia: revisión conceptual y complejidad en la práctica clínica." [Informed consent in psychotherapy: conceptual and complexity in clinical practice]. Vertex (Buenos Aires, Argentina) vol. 24,109 (2013): 165-8.
De Rosa L. El consentimiento informado en psicoterapia: revisión conceptual y complejidad en la práctica clínica. [Informed consent in psychotherapy: conceptual and complexity in clinical practice]. Vertex. 2013 May-Jun;24(109):165-8. Spanish. PMID: 24255897.
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Chemopreventive effects of the polyunsaturated fatty acids omega-3 on the carcinogenesis process of the upper aerodigestive tract induced by 4-nitroquinoline-1-oxide in Swiss mice.

Ecancermedicalscience

Gama RR, Giovanini A, de Rosa FS, Ogata DC, de Oliveira AL, Cardoso Costa AF, Talini C, Feniman D, Kamei D, Júnior CF, Coco A, Carvalho AL.
PMID: 24605132
Ecancermedicalscience. 2014 Jan 29;8:392. doi: 10.3332/ecancer.2014.392. eCollection 2014.

OBJECTIVE: To study the potential chemopreventive effects of polyunsaturated fatty acids omega-3 in Swiss mice submitted to oral and oesophageal carcinogenesis induction by 4-nitroquinoline-1-oxide (4-NQO).STUDY DESIGN: The animals underwent carcinogenesis induction with 50 µg/mL 4-NQO for eight weeks. The...

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Gama RR, Giovanini A, de Rosa FS, et al. Chemopreventive effects of the polyunsaturated fatty acids omega-3 on the carcinogenesis process of the upper aerodigestive tract induced by 4-nitroquinoline-1-oxide in Swiss mice. Ecancermedicalscience. 2014;8:392doi: 10.3332/ecancer.2014.392.
Gama, R. R., Giovanini, A., de Rosa, F. S., Ogata, D. C., de Oliveira, A. L., Cardoso Costa, A. F., Talini, C., Feniman, D., Kamei, D., Júnior, C. F., Coco, A., & Carvalho, A. L. (2014). Chemopreventive effects of the polyunsaturated fatty acids omega-3 on the carcinogenesis process of the upper aerodigestive tract induced by 4-nitroquinoline-1-oxide in Swiss mice. Ecancermedicalscience, 8392. https://doi.org/10.3332/ecancer.2014.392
Gama, Ricardo Ribeiro, et al. "Chemopreventive effects of the polyunsaturated fatty acids omega-3 on the carcinogenesis process of the upper aerodigestive tract induced by 4-nitroquinoline-1-oxide in Swiss mice." Ecancermedicalscience vol. 8 (2014): 392. doi: https://doi.org/10.3332/ecancer.2014.392
Gama RR, Giovanini A, de Rosa FS, Ogata DC, de Oliveira AL, Cardoso Costa AF, Talini C, Feniman D, Kamei D, Júnior CF, Coco A, Carvalho AL. Chemopreventive effects of the polyunsaturated fatty acids omega-3 on the carcinogenesis process of the upper aerodigestive tract induced by 4-nitroquinoline-1-oxide in Swiss mice. Ecancermedicalscience. 2014 Jan 29;8:392. doi: 10.3332/ecancer.2014.392. eCollection 2014. PMID: 24605132; PMCID: PMC3907402.
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The pharmacological options in the treatment of eating disorders.

ISRN pharmacology

Milano W, De Rosa M, Milano L, Riccio A, Sanseverino B, Capasso A.
PMID: 23956871
ISRN Pharmacol. 2013 Jul 15;2013:352865. doi: 10.1155/2013/352865. eCollection 2013.

The eating disorders (DCA) are complex systemic diseases with high social impact, which tend to become chronic with significant medical and psychiatric comorbidities. The literature data showed that there is good evidence to suggest the use of SSRIs, particularly...

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Milano W, De Rosa M, Milano L, et al. The pharmacological options in the treatment of eating disorders. ISRN Pharmacol. 2013;2013:352865doi: 10.1155/2013/352865.
Milano, W., De Rosa, M., Milano, L., Riccio, A., Sanseverino, B., & Capasso, A. (2013). The pharmacological options in the treatment of eating disorders. ISRN pharmacology, 2013352865. https://doi.org/10.1155/2013/352865
Milano, W, et al. "The pharmacological options in the treatment of eating disorders." ISRN pharmacology vol. 2013 (2013): 352865. doi: https://doi.org/10.1155/2013/352865
Milano W, De Rosa M, Milano L, Riccio A, Sanseverino B, Capasso A. The pharmacological options in the treatment of eating disorders. ISRN Pharmacol. 2013 Jul 15;2013:352865. doi: 10.1155/2013/352865. eCollection 2013. PMID: 23956871; PMCID: PMC3727200.
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Cancer prevalence in the city of Naples: Contribution of the GP database analyses to the cancer registries network.

Molecular and clinical oncology

Pizzi C, Arpino G, Acampora G, Aiello N, DE Rosa A, Diaferia I, DI Nunzio A, Fragna G, Franco A, Russo M, Sansone F, Scarpati C, Spinuso A, Arpino G, Luce A, Tommasielli G, Caraglia M, DE Placido S.
PMID: 24649236
Mol Clin Oncol. 2013 Jul;1(4):726-732. doi: 10.3892/mco.2013.101. Epub 2013 Apr 04.

The Italian cancer registries network has not been sufficiently developed in the Southern regions. General practitioners (GPs) are knowledgeable about the prevalence, incidence and mortality for different types of cancer in their patient populations. The aim of this pilot...

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Pizzi C, Arpino G, Acampora G, et al. Cancer prevalence in the city of Naples: Contribution of the GP database analyses to the cancer registries network. Mol Clin Oncol. 2013;1(4):726-732doi: 10.3892/mco.2013.101.
Pizzi, C., Arpino, G., Acampora, G., Aiello, N., DE Rosa, A., Diaferia, I., DI Nunzio, A., Fragna, G., Franco, A., Russo, M., Sansone, F., Scarpati, C., Spinuso, A., Arpino, G., Luce, A., Tommasielli, G., Caraglia, M., & DE Placido, S. (2013). Cancer prevalence in the city of Naples: Contribution of the GP database analyses to the cancer registries network. Molecular and clinical oncology, 1(4), 726-732. https://doi.org/10.3892/mco.2013.101
Pizzi, Claudia, et al. "Cancer prevalence in the city of Naples: Contribution of the GP database analyses to the cancer registries network." Molecular and clinical oncology vol. 1,4 (2013): 726-732. doi: https://doi.org/10.3892/mco.2013.101
Pizzi C, Arpino G, Acampora G, Aiello N, DE Rosa A, Diaferia I, DI Nunzio A, Fragna G, Franco A, Russo M, Sansone F, Scarpati C, Spinuso A, Arpino G, Luce A, Tommasielli G, Caraglia M, DE Placido S. Cancer prevalence in the city of Naples: Contribution of the GP database analyses to the cancer registries network. Mol Clin Oncol. 2013 Jul;1(4):726-732. doi: 10.3892/mco.2013.101. Epub 2013 Apr 04. PMID: 24649236; PMCID: PMC3915682.
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An Anthracene-Incorporated [8]Cycloparaphenylene Derivative as an Emitter in Photon Upconversion.

The Journal of organic chemistry

Della Sala P, Capobianco A, Caruso T, Talotta C, De Rosa M, Neri P, Peluso A, Gaeta C.
PMID: 29231727
J Org Chem. 2018 Jan 05;83(1):220-227. doi: 10.1021/acs.joc.7b02590. Epub 2017 Dec 26.

The anthracene-incorporated [8]cycloparaphenylene 2 has been synthesized and its optoelectronic properties studied by UV-vis spectroscopy, cyclic voltammetry, and DFT calculations. NMR and computational studies indicate that the new cycloparaphenylene derivative possesses a C

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Della Sala P, Capobianco A, Caruso T, et al. An Anthracene-Incorporated [8]Cycloparaphenylene Derivative as an Emitter in Photon Upconversion. J Org Chem. 2017;83(1):220-227doi: 10.1021/acs.joc.7b02590.
Della Sala, P., Capobianco, A., Caruso, T., Talotta, C., De Rosa, M., Neri, P., Peluso, A., & Gaeta, C. (2018). An Anthracene-Incorporated [8]Cycloparaphenylene Derivative as an Emitter in Photon Upconversion. The Journal of organic chemistry, 83(1), 220-227. https://doi.org/10.1021/acs.joc.7b02590
Della Sala, Paolo, et al. "An Anthracene-Incorporated [8]Cycloparaphenylene Derivative as an Emitter in Photon Upconversion." The Journal of organic chemistry vol. 83,1 (2018): 220-227. doi: https://doi.org/10.1021/acs.joc.7b02590
Della Sala P, Capobianco A, Caruso T, Talotta C, De Rosa M, Neri P, Peluso A, Gaeta C. An Anthracene-Incorporated [8]Cycloparaphenylene Derivative as an Emitter in Photon Upconversion. J Org Chem. 2018 Jan 05;83(1):220-227. doi: 10.1021/acs.joc.7b02590. Epub 2017 Dec 26. PMID: 29231727.
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Corrigendum to 'Optimization of hyaluronan-based eye drop formulations'[carbohydrate polymers 153 (2016) 275-].

Carbohydrate polymers

Salzillo R, Schiraldi C, Corsuto L, D'Agostino A, Filosa R, De Rosa M, La Gatta A.
PMID: 29253953
Carbohydr Polym. 2018 Feb 01;181:1235-1236. doi: 10.1016/j.carbpol.2017.11.071. Epub 2017 Nov 26.

No abstract available.

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Salzillo R, Schiraldi C, Corsuto L, et al. Corrigendum to 'Optimization of hyaluronan-based eye drop formulations'[carbohydrate polymers 153 (2016) 275-]. Carbohydr Polym. 2017;181:1235-1236doi: 10.1016/j.carbpol.2017.11.071.
Salzillo, R., Schiraldi, C., Corsuto, L., D'Agostino, A., Filosa, R., De Rosa, M., & La Gatta, A. (2018). Corrigendum to 'Optimization of hyaluronan-based eye drop formulations'[carbohydrate polymers 153 (2016) 275-]. Carbohydrate polymers, 1811235-1236. https://doi.org/10.1016/j.carbpol.2017.11.071
Salzillo, Rosanna, et al. "Corrigendum to 'Optimization of hyaluronan-based eye drop formulations'[carbohydrate polymers 153 (2016) 275-]." Carbohydrate polymers vol. 181 (2018): 1235-1236. doi: https://doi.org/10.1016/j.carbpol.2017.11.071
Salzillo R, Schiraldi C, Corsuto L, D'Agostino A, Filosa R, De Rosa M, La Gatta A. Corrigendum to 'Optimization of hyaluronan-based eye drop formulations'[carbohydrate polymers 153 (2016) 275-]. Carbohydr Polym. 2018 Feb 01;181:1235-1236. doi: 10.1016/j.carbpol.2017.11.071. Epub 2017 Nov 26. PMID: 29253953.
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Novel Strategy for One-Pot Synthesis of Gold Nanoplates on Carbon Nanotube Sheet As an Effective Flexible SERS Substrate.

ACS applied materials & interfaces

Xin W, Yang JM, Li C, Goorsky MS, Carlson L, De Rosa IM.
PMID: 28106364
ACS Appl Mater Interfaces. 2017 Feb 22;9(7):6246-6254. doi: 10.1021/acsami.6b10560. Epub 2017 Feb 07.

In this work, we demonstrate a novel route for one-pot synthesis of two-dimensional gold nanoplates (2-D AuNPLs) on carbon nanotube (CNT) sheet. Well-defined AuNPLs are grafted onto CNT sheet via a facile hydrothermal reduction process, during which bromine ions...

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Xin W, Yang JM, Li C, et al. Novel Strategy for One-Pot Synthesis of Gold Nanoplates on Carbon Nanotube Sheet As an Effective Flexible SERS Substrate. ACS Appl Mater Interfaces. 2017;9(7):6246-6254doi: 10.1021/acsami.6b10560.
Xin, W., Yang, J. M., Li, C., Goorsky, M. S., Carlson, L., & De Rosa, I. M. (2017). Novel Strategy for One-Pot Synthesis of Gold Nanoplates on Carbon Nanotube Sheet As an Effective Flexible SERS Substrate. ACS applied materials & interfaces, 9(7), 6246-6254. https://doi.org/10.1021/acsami.6b10560
Xin, Wenbo, et al. "Novel Strategy for One-Pot Synthesis of Gold Nanoplates on Carbon Nanotube Sheet As an Effective Flexible SERS Substrate." ACS applied materials & interfaces vol. 9,7 (2017): 6246-6254. doi: https://doi.org/10.1021/acsami.6b10560
Xin W, Yang JM, Li C, Goorsky MS, Carlson L, De Rosa IM. Novel Strategy for One-Pot Synthesis of Gold Nanoplates on Carbon Nanotube Sheet As an Effective Flexible SERS Substrate. ACS Appl Mater Interfaces. 2017 Feb 22;9(7):6246-6254. doi: 10.1021/acsami.6b10560. Epub 2017 Feb 07. PMID: 28106364.
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RTS,S/AS01E Malaria Vaccine Induces Memory and Polyfunctional T Cell Responses in a Pediatric African Phase III Trial.

Frontiers in immunology

Moncunill G, De Rosa SC, Ayestaran A, Nhabomba AJ, Mpina M, Cohen KW, Jairoce C, Rutishauser T, Campo JJ, Harezlak J, Sanz H, Díez-Padrisa N, Williams NA, Morris D, Aponte JJ, Valim C, Daubenberger C, Dobaño C, McElrath MJ.
PMID: 28878775
Front Immunol. 2017 Aug 23;8:1008. doi: 10.3389/fimmu.2017.01008. eCollection 2017.

Comprehensive assessment of cellular responses to the RTS,S/AS01E vaccine is needed to understand potential correlates and ultimately mechanisms of protection against malaria disease. Cellular responses recognizing the RTS,S/AS01E-containing circumsporozoite protein (CSP) and Hepatitis B surface antigen (HBsAg) were assessed...

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Moncunill G, De Rosa SC, Ayestaran A, et al. RTS,S/AS01E Malaria Vaccine Induces Memory and Polyfunctional T Cell Responses in a Pediatric African Phase III Trial. Front Immunol. 2017;8:1008doi: 10.3389/fimmu.2017.01008.
Moncunill, G., De Rosa, S. C., Ayestaran, A., Nhabomba, A. J., Mpina, M., Cohen, K. W., Jairoce, C., Rutishauser, T., Campo, J. J., Harezlak, J., Sanz, H., Díez-Padrisa, N., Williams, N. A., Morris, D., Aponte, J. J., Valim, C., Daubenberger, C., Dobaño, C., & McElrath, M. J. (2017). RTS,S/AS01E Malaria Vaccine Induces Memory and Polyfunctional T Cell Responses in a Pediatric African Phase III Trial. Frontiers in immunology, 81008. https://doi.org/10.3389/fimmu.2017.01008
Moncunill, Gemma, et al. "RTS,S/AS01E Malaria Vaccine Induces Memory and Polyfunctional T Cell Responses in a Pediatric African Phase III Trial." Frontiers in immunology vol. 8 (2017): 1008. doi: https://doi.org/10.3389/fimmu.2017.01008
Moncunill G, De Rosa SC, Ayestaran A, Nhabomba AJ, Mpina M, Cohen KW, Jairoce C, Rutishauser T, Campo JJ, Harezlak J, Sanz H, Díez-Padrisa N, Williams NA, Morris D, Aponte JJ, Valim C, Daubenberger C, Dobaño C, McElrath MJ. RTS,S/AS01E Malaria Vaccine Induces Memory and Polyfunctional T Cell Responses in a Pediatric African Phase III Trial. Front Immunol. 2017 Aug 23;8:1008. doi: 10.3389/fimmu.2017.01008. eCollection 2017. PMID: 28878775; PMCID: PMC5572329.
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High-speed multi-THz-range mode-hop-free tunable mid-IR laser spectrometer.

Optics letters

Courtois J, Bouchendira R, Cadoret M, Ricciardi I, Mosca S, De Rosa M, De Natale P, Zondy JJ.
PMID: 23722807
Opt Lett. 2013 Jun 01;38(11):1972-4. doi: 10.1364/OL.38.001972.

We report on a widely (2.25 THz or 75 cm(-1)) and rapidly (4.5 THz/s) mode-hop-free (MHF) tunable mid-IR laser source at ~3.3 μm, consisting of a 5%-MgO:LiNbO(3) singly resonant optical parametric oscillator (SRO) pumped by an automated broadly MHF...

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Courtois J, Bouchendira R, Cadoret M, et al. High-speed multi-THz-range mode-hop-free tunable mid-IR laser spectrometer. Opt Lett. 2013;38(11):1972-4doi: 10.1364/OL.38.001972.
Courtois, J., Bouchendira, R., Cadoret, M., Ricciardi, I., Mosca, S., De Rosa, M., De Natale, P., & Zondy, J. J. (2013). High-speed multi-THz-range mode-hop-free tunable mid-IR laser spectrometer. Optics letters, 38(11), 1972-4. https://doi.org/10.1364/OL.38.001972
Courtois, Jérémie, et al. "High-speed multi-THz-range mode-hop-free tunable mid-IR laser spectrometer." Optics letters vol. 38,11 (2013): 1972-4. doi: https://doi.org/10.1364/OL.38.001972
Courtois J, Bouchendira R, Cadoret M, Ricciardi I, Mosca S, De Rosa M, De Natale P, Zondy JJ. High-speed multi-THz-range mode-hop-free tunable mid-IR laser spectrometer. Opt Lett. 2013 Jun 01;38(11):1972-4. doi: 10.1364/OL.38.001972. PMID: 23722807.
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Same .

Clinical medicine insights. Case reports

Liccardo R, De Rosa M, Duraturo F.
PMID: 29383008
Clin Med Insights Case Rep. 2018 Jan 23;11:1179547617753943. doi: 10.1177/1179547617753943. eCollection 2018.

Lynch syndrome is an autosomal dominant syndrome that can be subdivided into Lynch syndrome I, or site-specific colonic cancer, and Lynch syndrome II, or extracolonic cancers, particularly carcinomas of the stomach, endometrium, biliary and pancreatic systems, and urinary tract....

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Liccardo R, De Rosa M, Duraturo F. Same . Clin Med Insights Case Rep. 2018;11:1179547617753943doi: 10.1177/1179547617753943.
Liccardo, R., De Rosa, M., & Duraturo, F. (2018). Same . Clinical medicine insights. Case reports, 111179547617753943. https://doi.org/10.1177/1179547617753943
Liccardo, Raffaella, et al. "Same ." Clinical medicine insights. Case reports vol. 11 (2018): 1179547617753943. doi: https://doi.org/10.1177/1179547617753943
Liccardo R, De Rosa M, Duraturo F. Same . Clin Med Insights Case Rep. 2018 Jan 23;11:1179547617753943. doi: 10.1177/1179547617753943. eCollection 2018. PMID: 29383008; PMCID: PMC5784535.
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