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Intestinal Alkaline Phosphatase Combined with Voluntary Physical Activity Alleviates Experimental Colitis in Obese Mice. Involvement of Oxidative Stress, Myokines, Adipokines and Proinflammatory Biomarkers.

Antioxidants (Basel, Switzerland)

Danielak A, Wojcik D, Mazur-Bialy A, Surmiak M, Bilski J, Targosz A, Magierowski M, Chmura A, Strzalka M, Krzysiek-Maczka G, Magierowska K, Szczyrk U, Kwiecien S, Ptak-Belowska A, Brzozowski T.
PMID: 33557311
Antioxidants (Basel). 2021 Feb 04;10(2). doi: 10.3390/antiox10020240.

Intestinal alkaline phosphatase (IAP) is an essential mucosal defense factor involved in the process of maintenance of gut homeostasis. We determined the effect of moderate exercise (voluntary wheel running) with or without treatment with IAP on the course of...

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Danielak A, Wojcik D, Mazur-Bialy A, et al. Intestinal Alkaline Phosphatase Combined with Voluntary Physical Activity Alleviates Experimental Colitis in Obese Mice. Involvement of Oxidative Stress, Myokines, Adipokines and Proinflammatory Biomarkers. Antioxidants (Basel). 2021;10(2)doi: 10.3390/antiox10020240.
Danielak, A., Wojcik, D., Mazur-Bialy, A., Surmiak, M., Bilski, J., Targosz, A., Magierowski, M., Chmura, A., Strzalka, M., Krzysiek-Maczka, G., Magierowska, K., Szczyrk, U., Kwiecien, S., Ptak-Belowska, A., & Brzozowski, T. (2021). Intestinal Alkaline Phosphatase Combined with Voluntary Physical Activity Alleviates Experimental Colitis in Obese Mice. Involvement of Oxidative Stress, Myokines, Adipokines and Proinflammatory Biomarkers. Antioxidants (Basel, Switzerland), 10(2), . https://doi.org/10.3390/antiox10020240
Danielak, Aleksandra, et al. "Intestinal Alkaline Phosphatase Combined with Voluntary Physical Activity Alleviates Experimental Colitis in Obese Mice. Involvement of Oxidative Stress, Myokines, Adipokines and Proinflammatory Biomarkers." Antioxidants (Basel, Switzerland) vol. 10,2 (2021). doi: https://doi.org/10.3390/antiox10020240
Danielak A, Wojcik D, Mazur-Bialy A, Surmiak M, Bilski J, Targosz A, Magierowski M, Chmura A, Strzalka M, Krzysiek-Maczka G, Magierowska K, Szczyrk U, Kwiecien S, Ptak-Belowska A, Brzozowski T. Intestinal Alkaline Phosphatase Combined with Voluntary Physical Activity Alleviates Experimental Colitis in Obese Mice. Involvement of Oxidative Stress, Myokines, Adipokines and Proinflammatory Biomarkers. Antioxidants (Basel). 2021 Feb 04;10(2). doi: 10.3390/antiox10020240. PMID: 33557311; PMCID: PMC7914798.
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Profile for mRNA transcript abundances in the pig endometrium where inflammation was induced by Escherichia coli.

Animal reproduction science

Jana B, Kaczmarek MM, Romaniewicz M, Brzozowska M.
PMID: 34403834
Anim Reprod Sci. 2021 Sep;232:106824. doi: 10.1016/j.anireprosci.2021.106824. Epub 2021 Aug 08.

Uterine inflammation is a common reproductive disorder in domestic animals, leading to disturbances in many reproductive processes and economic losses. More information on inflammatory pathways, however, is needed to understand mechanisms of uterine inflammation. The aim of the study...

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Jana B, Kaczmarek MM, Romaniewicz M, et al. Profile for mRNA transcript abundances in the pig endometrium where inflammation was induced by Escherichia coli. Anim Reprod Sci. 2021;232:106824doi: 10.1016/j.anireprosci.2021.106824.
Jana, B., Kaczmarek, M. M., Romaniewicz, M., & Brzozowska, M. (2021). Profile for mRNA transcript abundances in the pig endometrium where inflammation was induced by Escherichia coli. Animal reproduction science, 232106824. https://doi.org/10.1016/j.anireprosci.2021.106824
Jana, Barbara, et al. "Profile for mRNA transcript abundances in the pig endometrium where inflammation was induced by Escherichia coli." Animal reproduction science vol. 232 (2021): 106824. doi: https://doi.org/10.1016/j.anireprosci.2021.106824
Jana B, Kaczmarek MM, Romaniewicz M, Brzozowska M. Profile for mRNA transcript abundances in the pig endometrium where inflammation was induced by Escherichia coli. Anim Reprod Sci. 2021 Sep;232:106824. doi: 10.1016/j.anireprosci.2021.106824. Epub 2021 Aug 08. PMID: 34403834.
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The direct α-C(sp(3))-H functionalisation of N-aryl tetrahydroisoquinolines via an iron-catalysed aerobic nitro-Mannich reaction and continuous flow processing.

Chemical communications (Cambridge, England)

Brzozowski M, Forni JA, Paul Savage G, Polyzos A.
PMID: 25407918
Chem Commun (Camb). 2015;51(2):334-7. doi: 10.1039/c4cc07913b.

An efficient nitro-Mannich type direct α-C(sp(3))-H functionalisation of N-aryl-1,2,3,4-tetrahydroisoquinolines catalysed by simple iron salts in combination with O2 as the terminal oxidant is described. The use of a Teflon AF-2400 membrane Tube-in-Tube reactor under continuous flow conditions allowed for...

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Brzozowski M, Forni JA, Paul Savage G, et al. The direct α-C(sp(3))-H functionalisation of N-aryl tetrahydroisoquinolines via an iron-catalysed aerobic nitro-Mannich reaction and continuous flow processing. Chem Commun (Camb). 2015;51(2):334-7doi: 10.1039/c4cc07913b.
Brzozowski, M., Forni, J. A., Paul Savage, G., & Polyzos, A. (2015). The direct α-C(sp(3))-H functionalisation of N-aryl tetrahydroisoquinolines via an iron-catalysed aerobic nitro-Mannich reaction and continuous flow processing. Chemical communications (Cambridge, England), 51(2), 334-7. https://doi.org/10.1039/c4cc07913b
Brzozowski, Martin, et al. "The direct α-C(sp(3))-H functionalisation of N-aryl tetrahydroisoquinolines via an iron-catalysed aerobic nitro-Mannich reaction and continuous flow processing." Chemical communications (Cambridge, England) vol. 51,2 (2015): 334-7. doi: https://doi.org/10.1039/c4cc07913b
Brzozowski M, Forni JA, Paul Savage G, Polyzos A. The direct α-C(sp(3))-H functionalisation of N-aryl tetrahydroisoquinolines via an iron-catalysed aerobic nitro-Mannich reaction and continuous flow processing. Chem Commun (Camb). 2015;51(2):334-7. doi: 10.1039/c4cc07913b. PMID: 25407918.
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Biocatalytic preparation of a chiral synthon for a vasopeptidase inhibitor: enzymatic conversion of N(2)-.

Enzyme and microbial technology

Patel RN, Banerjee A, Nanduri VB, Goldberg SL, Johnston RM, Hanson RL, McNamee CG, Brzozowski DB, Tully TP, Ko RY, LaPorte TL, Cazzulino DL, Swaminathan S, Chen C, Parker LW, Venit JJ.
PMID: 10938417
Enzyme Microb Technol. 2000 Sep 01;27(6):376-389. doi: 10.1016/s0141-0229(00)00233-7.

[4S-(4I,7I,10aJ)]1-Octahydro-5-oxo-4-[phenylmethoxy)carbonyl]amino]-7H-pyrido-[2,1-b] [1,3]thiazepine-7-carboxylic acid methyl ester (BMS-199541-01) is a key chiral intermediate for the synthesis of Omapatrilat (BMS-186716), a new vasopeptidease inhibitor under development. By using a selective enrichment culture technique we have isolated a strain of Sphingomonas paucimobilis SC...

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Patel RN, Banerjee A, Nanduri VB, et al. Biocatalytic preparation of a chiral synthon for a vasopeptidase inhibitor: enzymatic conversion of N(2)-. Enzyme Microb Technol. 2000;27(6):376-389doi: 10.1016/s0141-0229(00)00233-7.
Patel, R. N., Banerjee, A., Nanduri, V. B., Goldberg, S. L., Johnston, R. M., Hanson, R. L., McNamee, C. G., Brzozowski, D. B., Tully, T. P., Ko, R. Y., LaPorte, T. L., Cazzulino, D. L., Swaminathan, S., Chen, C., Parker, L. W., & Venit, J. J. (2000). Biocatalytic preparation of a chiral synthon for a vasopeptidase inhibitor: enzymatic conversion of N(2)-. Enzyme and microbial technology, 27(6), 376-389. https://doi.org/10.1016/s0141-0229(00)00233-7
Patel, et al. "Biocatalytic preparation of a chiral synthon for a vasopeptidase inhibitor: enzymatic conversion of N(2)-." Enzyme and microbial technology vol. 27,6 (2000): 376-389. doi: https://doi.org/10.1016/s0141-0229(00)00233-7
Patel RN, Banerjee A, Nanduri VB, Goldberg SL, Johnston RM, Hanson RL, McNamee CG, Brzozowski DB, Tully TP, Ko RY, LaPorte TL, Cazzulino DL, Swaminathan S, Chen C, Parker LW, Venit JJ. Biocatalytic preparation of a chiral synthon for a vasopeptidase inhibitor: enzymatic conversion of N(2)-. Enzyme Microb Technol. 2000 Sep 01;27(6):376-389. doi: 10.1016/s0141-0229(00)00233-7. PMID: 10938417.
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Chemical characterization and immunomodulatory properties of polysaccharides isolated from probiotic Lactobacillus casei LOCK 0919.

Glycobiology

Górska S, Hermanova P, Ciekot J, Schwarzer M, Srutkova D, Brzozowska E, Kozakova H, Gamian A.
PMID: 28177465
Glycobiology. 2017 Mar 15;27(3):275-277. doi: 10.1093/glycob/cww107.

No abstract available.

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Górska S, Hermanova P, Ciekot J, et al. Chemical characterization and immunomodulatory properties of polysaccharides isolated from probiotic Lactobacillus casei LOCK 0919. Glycobiology. 2017;27(3):275-277doi: 10.1093/glycob/cww107.
Górska, S., Hermanova, P., Ciekot, J., Schwarzer, M., Srutkova, D., Brzozowska, E., Kozakova, H., & Gamian, A. (2017). Chemical characterization and immunomodulatory properties of polysaccharides isolated from probiotic Lactobacillus casei LOCK 0919. Glycobiology, 27(3), 275-277. https://doi.org/10.1093/glycob/cww107
Górska, S, et al. "Chemical characterization and immunomodulatory properties of polysaccharides isolated from probiotic Lactobacillus casei LOCK 0919." Glycobiology vol. 27,3 (2017): 275-277. doi: https://doi.org/10.1093/glycob/cww107
Górska S, Hermanova P, Ciekot J, Schwarzer M, Srutkova D, Brzozowska E, Kozakova H, Gamian A. Chemical characterization and immunomodulatory properties of polysaccharides isolated from probiotic Lactobacillus casei LOCK 0919. Glycobiology. 2017 Mar 15;27(3):275-277. doi: 10.1093/glycob/cww107. PMID: 28177465; PMCID: PMC5444261.
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Psychometric Comparisons of Benevolent and Corrective Humor across 22 Countries: The Virtue Gap in Humor Goes International.

Frontiers in psychology

Heintz S, Ruch W, Platt T, Pang D, Carretero-Dios H, Dionigi A, Argüello Gutiérrez C, Brdar I, Brzozowska D, Chen HC, Chłopicki W, Collins M, Ďurka R, Yahfoufi NYE, Quiroga-Garza A, Isler RB, Mendiburo-Seguel A, Ramis T, Saglam B, Shcherbakova OV, Singh K, Stokenberga I, Wong PSO, Torres-Marín J.
PMID: 29479326
Front Psychol. 2018 Feb 09;9:92. doi: 10.3389/fpsyg.2018.00092. eCollection 2018.

Recently, two forms of virtue-related humor, benevolent and corrective, have been introduced. Benevolent humor treats human weaknesses and wrongdoings benevolently, while corrective humor aims at correcting and bettering them. Twelve marker items for benevolent and corrective humor (the BenCor)...

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Heintz S, Ruch W, Platt T, et al. Psychometric Comparisons of Benevolent and Corrective Humor across 22 Countries: The Virtue Gap in Humor Goes International. Front Psychol. 2018;9:92doi: 10.3389/fpsyg.2018.00092.
Heintz, S., Ruch, W., Platt, T., Pang, D., Carretero-Dios, H., Dionigi, A., Argüello Gutiérrez, C., Brdar, I., Brzozowska, D., Chen, H. C., Chłopicki, W., Collins, M., Ďurka, R., Yahfoufi, N. Y. E., Quiroga-Garza, A., Isler, R. B., Mendiburo-Seguel, A., Ramis, T., Saglam, B., Shcherbakova, O. V., Singh, K., Stokenberga, I., Wong, P. S. O., & Torres-Marín, J. (2018). Psychometric Comparisons of Benevolent and Corrective Humor across 22 Countries: The Virtue Gap in Humor Goes International. Frontiers in psychology, 992. https://doi.org/10.3389/fpsyg.2018.00092
Heintz, Sonja, et al. "Psychometric Comparisons of Benevolent and Corrective Humor across 22 Countries: The Virtue Gap in Humor Goes International." Frontiers in psychology vol. 9 (2018): 92. doi: https://doi.org/10.3389/fpsyg.2018.00092
Heintz S, Ruch W, Platt T, Pang D, Carretero-Dios H, Dionigi A, Argüello Gutiérrez C, Brdar I, Brzozowska D, Chen HC, Chłopicki W, Collins M, Ďurka R, Yahfoufi NYE, Quiroga-Garza A, Isler RB, Mendiburo-Seguel A, Ramis T, Saglam B, Shcherbakova OV, Singh K, Stokenberga I, Wong PSO, Torres-Marín J. Psychometric Comparisons of Benevolent and Corrective Humor across 22 Countries: The Virtue Gap in Humor Goes International. Front Psychol. 2018 Feb 09;9:92. doi: 10.3389/fpsyg.2018.00092. eCollection 2018. PMID: 29479326; PMCID: PMC5812205.
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Cross-Linking/Mass Spectrometry Uncovers Details of Insulin-Like Growth Factor Interaction With Insect Insulin Binding Protein Imp-L2.

Frontiers in endocrinology

Pompach P, Viola CM, Radosavljević J, Lin J, Jiráček J, Brzozowski AM, Selicharová I.
PMID: 31649623
Front Endocrinol (Lausanne). 2019 Oct 09;10:695. doi: 10.3389/fendo.2019.00695. eCollection 2019.

Structural details of changes accompanying interaction between insulin-related hormones and their binding partners are often enigmatic. Here, cross-linking/mass spectrometry could complement structural techniques and reveal details of these protein-protein interfaces. We used such approach to clarify missing structural description...

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Pompach P, Viola CM, Radosavljević J, et al. Cross-Linking/Mass Spectrometry Uncovers Details of Insulin-Like Growth Factor Interaction With Insect Insulin Binding Protein Imp-L2. Front Endocrinol (Lausanne). 2019;10:695doi: 10.3389/fendo.2019.00695.
Pompach, P., Viola, C. M., Radosavljević, J., Lin, J., Jiráček, J., Brzozowski, A. M., & Selicharová, I. (2019). Cross-Linking/Mass Spectrometry Uncovers Details of Insulin-Like Growth Factor Interaction With Insect Insulin Binding Protein Imp-L2. Frontiers in endocrinology, 10695. https://doi.org/10.3389/fendo.2019.00695
Pompach, Petr, et al. "Cross-Linking/Mass Spectrometry Uncovers Details of Insulin-Like Growth Factor Interaction With Insect Insulin Binding Protein Imp-L2." Frontiers in endocrinology vol. 10 (2019): 695. doi: https://doi.org/10.3389/fendo.2019.00695
Pompach P, Viola CM, Radosavljević J, Lin J, Jiráček J, Brzozowski AM, Selicharová I. Cross-Linking/Mass Spectrometry Uncovers Details of Insulin-Like Growth Factor Interaction With Insect Insulin Binding Protein Imp-L2. Front Endocrinol (Lausanne). 2019 Oct 09;10:695. doi: 10.3389/fendo.2019.00695. eCollection 2019. PMID: 31649623; PMCID: PMC6794382.
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Vertical and Horizontal M-Charts and Microperimetry for Assessment of the Visual Function in Patients after Vitrectomy with ILM Peeling due to Stage 4 Macular Hole.

Journal of ophthalmology

Wrzesińska D, Nowomiejska K, Nowakowska D, Brzozowska A, Avitabile T, Reibaldi M, Rejdak R, Toro M.
PMID: 31198606
J Ophthalmol. 2019 May 06;2019:4975973. doi: 10.1155/2019/4975973. eCollection 2019.

PURPOSE: To examine the relationship between the morphological and functional results in eyes after pars plana vitrectomy (PPV) with internal limiting membrane (ILM) peeling due to stage 4 full-thickness macular hole (FTMH).METHODS: The study included 22 eyes that underwent...

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Wrzesińska D, Nowomiejska K, Nowakowska D, et al. Vertical and Horizontal M-Charts and Microperimetry for Assessment of the Visual Function in Patients after Vitrectomy with ILM Peeling due to Stage 4 Macular Hole. J Ophthalmol. 2019;2019:4975973doi: 10.1155/2019/4975973.
Wrzesińska, D., Nowomiejska, K., Nowakowska, D., Brzozowska, A., Avitabile, T., Reibaldi, M., Rejdak, R., & Toro, M. (2019). Vertical and Horizontal M-Charts and Microperimetry for Assessment of the Visual Function in Patients after Vitrectomy with ILM Peeling due to Stage 4 Macular Hole. Journal of ophthalmology, 20194975973. https://doi.org/10.1155/2019/4975973
Wrzesińska, Dominika, et al. "Vertical and Horizontal M-Charts and Microperimetry for Assessment of the Visual Function in Patients after Vitrectomy with ILM Peeling due to Stage 4 Macular Hole." Journal of ophthalmology vol. 2019 (2019): 4975973. doi: https://doi.org/10.1155/2019/4975973
Wrzesińska D, Nowomiejska K, Nowakowska D, Brzozowska A, Avitabile T, Reibaldi M, Rejdak R, Toro M. Vertical and Horizontal M-Charts and Microperimetry for Assessment of the Visual Function in Patients after Vitrectomy with ILM Peeling due to Stage 4 Macular Hole. J Ophthalmol. 2019 May 06;2019:4975973. doi: 10.1155/2019/4975973. eCollection 2019. PMID: 31198606; PMCID: PMC6526516.
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Transient expression and stable transformation of soybean using the jellyfish green fluorescent protein.

Plant cell reports

Ponappa T, Brzozowski AE, Finer JJ.
PMID: 30754760
Plant Cell Rep. 1999 Nov;19(1):6-12. doi: 10.1007/s002990050702.

 Embryogenic soybean [Glycine max (L.) Merrill.] suspension cultures were bombarded with five different gene constructions encoding the jellyfish (Aequorea victoria) green fluorescent protein (GFP). These constructions had altered codon usage compared to the native GFP gene and mutations...

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Ponappa T, Brzozowski AE, Finer JJ. Transient expression and stable transformation of soybean using the jellyfish green fluorescent protein. Plant Cell Rep. 1999;19(1):6-12doi: 10.1007/s002990050702.
Ponappa, T., Brzozowski, A. E., & Finer, J. J. (1999). Transient expression and stable transformation of soybean using the jellyfish green fluorescent protein. Plant cell reports, 19(1), 6-12. https://doi.org/10.1007/s002990050702
Ponappa, T, et al. "Transient expression and stable transformation of soybean using the jellyfish green fluorescent protein." Plant cell reports vol. 19,1 (1999): 6-12. doi: https://doi.org/10.1007/s002990050702
Ponappa T, Brzozowski AE, Finer JJ. Transient expression and stable transformation of soybean using the jellyfish green fluorescent protein. Plant Cell Rep. 1999 Nov;19(1):6-12. doi: 10.1007/s002990050702. PMID: 30754760.
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Site-selective C-C modification of proteins at neutral pH using organocatalyst-mediated cross aldol ligations.

Chemical science

Spears RJ, Brabham RL, Budhadev D, Keenan T, McKenna S, Walton J, Brannigan JA, Brzozowski AM, Wilkinson AJ, Plevin M, Fascione MA.
PMID: 30061990
Chem Sci. 2018 May 31;9(25):5585-5593. doi: 10.1039/c8sc01617h. eCollection 2018 Jul 07.

The bioconjugation of proteins with small molecules has proved an invaluable strategy for probing and perturbing biological mechanisms. The general use of chemical methods for protein functionalisation can be limited however by the requirement for complicated reaction partners to...

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Spears RJ, Brabham RL, Budhadev D, et al. Site-selective C-C modification of proteins at neutral pH using organocatalyst-mediated cross aldol ligations. Chem Sci. 2018;9(25):5585-5593doi: 10.1039/c8sc01617h.
Spears, R. J., Brabham, R. L., Budhadev, D., Keenan, T., McKenna, S., Walton, J., Brannigan, J. A., Brzozowski, A. M., Wilkinson, A. J., Plevin, M., & Fascione, M. A. (2018). Site-selective C-C modification of proteins at neutral pH using organocatalyst-mediated cross aldol ligations. Chemical science, 9(25), 5585-5593. https://doi.org/10.1039/c8sc01617h
Spears, Richard J, et al. "Site-selective C-C modification of proteins at neutral pH using organocatalyst-mediated cross aldol ligations." Chemical science vol. 9,25 (2018): 5585-5593. doi: https://doi.org/10.1039/c8sc01617h
Spears RJ, Brabham RL, Budhadev D, Keenan T, McKenna S, Walton J, Brannigan JA, Brzozowski AM, Wilkinson AJ, Plevin M, Fascione MA. Site-selective C-C modification of proteins at neutral pH using organocatalyst-mediated cross aldol ligations. Chem Sci. 2018 May 31;9(25):5585-5593. doi: 10.1039/c8sc01617h. eCollection 2018 Jul 07. PMID: 30061990; PMCID: PMC6049525.
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Are type I dural arteriovenous fistulas safe? Single-centre experience of endovascular treatment of dural arteriovenous fistulas.

Polish journal of radiology

Brzozowski K, Narloch J, Piasecki P, Zięcina P, Koziarski A.
PMID: 31481988
Pol J Radiol. 2019 Apr 05;84:e179-e184. doi: 10.5114/pjr.2019.84602. eCollection 2019.

INTRODUCTION: There are mixed reports on the incidence of intracranial haemorrhage in patients with dural arteriovenous fistulas. We assessed new proposed risk factors (i.a. number of outflows and outflow diameter) of intracerebral haemorrhage due to intracranial dural arteriovenous fistula...

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Brzozowski K, Narloch J, Piasecki P, et al. Are type I dural arteriovenous fistulas safe? Single-centre experience of endovascular treatment of dural arteriovenous fistulas. Pol J Radiol. 2019;84:e179-e184doi: 10.5114/pjr.2019.84602.
Brzozowski, K., Narloch, J., Piasecki, P., Zięcina, P., & Koziarski, A. (2019). Are type I dural arteriovenous fistulas safe? Single-centre experience of endovascular treatment of dural arteriovenous fistulas. Polish journal of radiology, 84e179-e184. https://doi.org/10.5114/pjr.2019.84602
Brzozowski, Krzysztof, et al. "Are type I dural arteriovenous fistulas safe? Single-centre experience of endovascular treatment of dural arteriovenous fistulas." Polish journal of radiology vol. 84 (2019): e179-e184. doi: https://doi.org/10.5114/pjr.2019.84602
Brzozowski K, Narloch J, Piasecki P, Zięcina P, Koziarski A. Are type I dural arteriovenous fistulas safe? Single-centre experience of endovascular treatment of dural arteriovenous fistulas. Pol J Radiol. 2019 Apr 05;84:e179-e184. doi: 10.5114/pjr.2019.84602. eCollection 2019. PMID: 31481988; PMCID: PMC6717945.
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Experimental and Computational Study of an Unexpected Iron-Catalyzed Carboetherification by Cooperative Metal and Ligand Substrate Interaction and Proton Shuttling.

Angewandte Chemie (International ed. in English)

El-Sepelgy O, Brzozowska A, Azofra LM, Jang YK, Cavallo L, Rueping M.
PMID: 28949059
Angew Chem Int Ed Engl. 2017 Nov 20;56(47):14863-14867. doi: 10.1002/anie.201708240. Epub 2017 Oct 24.

An iron-catalyzed cycloisomerization of allenols to deoxygenated pyranose glycals has been developed. Combined experimental and computational studies show that the iron complex exhibits a dual catalytic role in that the non-innocent cyclopentadienone ligand acts as proton shuttle by initial...

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El-Sepelgy O, Brzozowska A, Azofra LM, et al. Experimental and Computational Study of an Unexpected Iron-Catalyzed Carboetherification by Cooperative Metal and Ligand Substrate Interaction and Proton Shuttling. Angew Chem Int Ed Engl. 2017;56(47):14863-14867doi: 10.1002/anie.201708240.
El-Sepelgy, O., Brzozowska, A., Azofra, L. M., Jang, Y. K., Cavallo, L., & Rueping, M. (2017). Experimental and Computational Study of an Unexpected Iron-Catalyzed Carboetherification by Cooperative Metal and Ligand Substrate Interaction and Proton Shuttling. Angewandte Chemie (International ed. in English), 56(47), 14863-14867. https://doi.org/10.1002/anie.201708240
El-Sepelgy, Osama, et al. "Experimental and Computational Study of an Unexpected Iron-Catalyzed Carboetherification by Cooperative Metal and Ligand Substrate Interaction and Proton Shuttling." Angewandte Chemie (International ed. in English) vol. 56,47 (2017): 14863-14867. doi: https://doi.org/10.1002/anie.201708240
El-Sepelgy O, Brzozowska A, Azofra LM, Jang YK, Cavallo L, Rueping M. Experimental and Computational Study of an Unexpected Iron-Catalyzed Carboetherification by Cooperative Metal and Ligand Substrate Interaction and Proton Shuttling. Angew Chem Int Ed Engl. 2017 Nov 20;56(47):14863-14867. doi: 10.1002/anie.201708240. Epub 2017 Oct 24. PMID: 28949059.
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