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Showing 13 to 24 of 684 entries
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An actinide Zintl cluster: a tris(triamidouranium)μ3-η2:η2:η2-heptaphosphanortricyclane and its diverse synthetic utility.

Angewandte Chemie (International ed. in English)

Patel D, Tuna F, McInnes EJ, Lewis W, Blake AJ, Liddle ST.
PMID: 24127241
Angew Chem Int Ed Engl. 2013 Dec 09;52(50):13334-7. doi: 10.1002/anie.201306492. Epub 2013 Oct 14.

No abstract available.

Synthesis, characterization, and reactivity of a uranium(VI) carbene imido oxo complex.

Angewandte Chemie (International ed. in English)

Lu E, Cooper OJ, McMaster J, Tuna F, McInnes EJ, Lewis W, Blake AJ, Liddle ST.
PMID: 24842784
Angew Chem Int Ed Engl. 2014 Jun 23;53(26):6696-700. doi: 10.1002/anie.201403892. Epub 2014 May 19.

We report the uranium(VI) carbene imido oxo complex [U(BIPM(TMS))(NMes)(O)(DMAP)2] (5, BIPM(TMS) = C(PPh2 NSiMe3)2; Mes = 2,4,6-Me3C6H2; DMAP = 4-(dimethylamino)pyridine) which exhibits the unprecedented arrangement of three formal multiply bonded ligands to one metal center where the coordinated heteroatoms...

Anionogenic mixed valency in KxBa1-xO2-δ.

Inorganic chemistry

Giriyapura S, Zhang B, de Groot RA, de Wijs GA, Caretta A, van Loosdrecht PH, Kockelmann W, Palstra TT, Blake GR.
PMID: 24328297
Inorg Chem. 2014 Jan 06;53(1):496-502. doi: 10.1021/ic402493q. Epub 2013 Dec 11.

We have synthesized members of an isostructural solid solution series KxBa1-xO2-δ (x < 0.41, δ < 0.11) containing mixed-valent dioxygen anions. Synthesis in liquid ammonia solution allows a continuous range of compounds to be prepared. X-ray and neutron diffraction...

Dietary Lecithin Supplementation Can Improve the Quality of the M. Longissimus thoracis.

Animals : an open access journal from MDPI

D'Souza DN, Blake BL, Williams IH, Mullan BP, Pethick DW, Dunshea FR.
PMID: 26610579
Animals (Basel). 2015 Nov 25;5(4):1180-91. doi: 10.3390/ani5040405.

Forty crossbred (Large White × Landrace × Duroc) female pigs (16.4 kg ± 0.94 kg) were used to investigate the effect of dietary lecithin supplementation on growth performance and pork quality. Pigs were randomly allocated to a commercial diet...

Aurophilicity under pressure: a combined crystallographic and in situ spectroscopic study.

Chemical communications (Cambridge, England)

O'Connor AE, Mirzadeh N, Bhargava SK, Easun TL, Schröder M, Blake AJ.
PMID: 27009745
Chem Commun (Camb). 2016 May 21;52(41):6769-72. doi: 10.1039/c6cc00923a. Epub 2016 Mar 24.

High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(i) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an...

Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex.

Angewandte Chemie (International ed. in English)

Gardner BM, Balázs G, Scheer M, Wooles AJ, Tuna F, McInnes EJ, McMaster J, Lewis W, Blake AJ, Liddle ST.
PMID: 26510123
Angew Chem Int Ed Engl. 2015 Dec 07;54(50):15250-4. doi: 10.1002/anie.201508600. Epub 2015 Oct 28.

The HAsAsH molecule has hitherto only been proposed tentatively as a short-lived species generated in electrochemical or microwave-plasma experiments. After two centuries of inconclusive or disproven claims of HAsAsH formation in the condensed phase, we report the isolation and...

Cavitation and bubble dynamics: the Kelvin impulse and its applications.

Interface focus

Blake JR, Leppinen DM, Wang Q.
PMID: 26442141
Interface Focus. 2015 Oct 06;5(5):20150017. doi: 10.1098/rsfs.2015.0017.

Cavitation and bubble dynamics have a wide range of practical applications in a range of disciplines, including hydraulic, mechanical and naval engineering, oil exploration, clinical medicine and sonochemistry. However, this paper focuses on how a fundamental concept, the Kelvin...

Assessing Systemic Stress in Otolaryngology: Methodology and Feasibility of Hair and Salivary Cortisol Testing.

Journal of nature and science

Genther DJ, Laudenslager ML, Sung YK, Blake CR, Chen DS, Lin FR.
PMID: 26436139
J Nat Sci. 2015 Aug;1(8).

OBJECTIVE: Elevated systemic stress is a predictor of adverse health outcomes, and stress can be objectively quantified by cortisol concentration. Despite its utility, such testing is rarely performed in otolaryngology. This manuscript provides details on the principles, methodology, and...

Correction to Impact of Coordination Geometry, Bite Angle, and Trans Influence on Metal-Ligand Covalency in Phenyl-Substituted Phosphine Complexes of Ni and Pd.

Inorganic chemistry

Donahue CM, McCollom SP, Forrest CM, Blake AV, Bellott BJ, Keith JM, Daly SR.
PMID: 26280192
Inorg Chem. 2015 Sep 08;54(17):8857. doi: 10.1021/acs.inorgchem.5b01794. Epub 2015 Aug 17.

No abstract available.

Silicic volcanism on Mars evidenced by tridymite in high-SiO2 sedimentary rock at Gale crater.

Proceedings of the National Academy of Sciences of the United States of America

Morris RV, Vaniman DT, Blake DF, Gellert R, Chipera SJ, Rampe EB, Ming DW, Morrison SM, Downs RT, Treiman AH, Yen AS, Grotzinger JP, Achilles CN, Bristow TF, Crisp JA, Des Marais DJ, Farmer JD, Fendrich KV, Frydenvang J, Graff TG, Morookian JM, Stolper EM, Schwenzer SP.
PMID: 27298370
Proc Natl Acad Sci U S A. 2016 Jun 28;113(26):7071-6. doi: 10.1073/pnas.1607098113. Epub 2016 Jun 13.

Tridymite, a low-pressure, high-temperature (>870 °C) SiO2 polymorph, was detected in a drill sample of laminated mudstone (Buckskin) at Marias Pass in Gale crater, Mars, by the Chemistry and Mineralogy X-ray diffraction instrument onboard the Mars Science Laboratory rover...

Children reject inequity out of spite.

Biology letters

McAuliffe K, Blake PR, Warneken F.
PMID: 25540156
Biol Lett. 2014 Dec;10(12):20140743. doi: 10.1098/rsbl.2014.0743.

When confronted with inequality, human children and adults sacrifice personal gain to reduce the pay-offs of other individuals, exhibiting apparently spiteful motivations. By contrast, sacrifice of personal gain by non-human animals is often interpreted as frustration. Spite may thus...

Alkali metal derivatives of an ortho-phenylene diamine.

Dalton transactions (Cambridge, England : 2003)

Robinson S, Davies ES, Lewis W, Blake AJ, Liddle ST.
PMID: 24202065
Dalton Trans. 2014 Mar 21;43(11):4351-60. doi: 10.1039/c3dt52632a.

Treatment of the ortho-phenylene diamine C6H4-1,2-{N(H)Tripp}2 (1, PDAH2, Tripp = 2,4,6-triisopropylphenyl) with two equivalents of MR (M = Li, R = Bu(n); M = Na or K, R = CH2C6H5) afforded the dimetallated alkali metal ortho-phenylene diamide dianion complexes...

Showing 13 to 24 of 684 entries