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Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes.

Angewandte Chemie (International ed. in English)

Chan SC, Gupta P, Engelmann X, Ang ZZ, Ganguly R, Bill E, Ray K, Ye S, England J.
PMID: 30239076
Angew Chem Int Ed Engl. 2018 Nov 26;57(48):15717-15722. doi: 10.1002/anie.201809158. Epub 2018 Nov 02.

To probe the possibility that carbodicarbenes (CDCs) are redox active ligands, all four members of the redox series [Fe(1)

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Chan SC, Gupta P, Engelmann X, et al. Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes. Angew Chem Int Ed Engl. 2018;57(48):15717-15722doi: 10.1002/anie.201809158.
Chan, S. C., Gupta, P., Engelmann, X., Ang, Z. Z., Ganguly, R., Bill, E., Ray, K., Ye, S., & England, J. (2018). Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes. Angewandte Chemie (International ed. in English), 57(48), 15717-15722. https://doi.org/10.1002/anie.201809158
Chan, Siu-Chung, et al. "Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes." Angewandte Chemie (International ed. in English) vol. 57,48 (2018): 15717-15722. doi: https://doi.org/10.1002/anie.201809158
Chan SC, Gupta P, Engelmann X, Ang ZZ, Ganguly R, Bill E, Ray K, Ye S, England J. Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes. Angew Chem Int Ed Engl. 2018 Nov 26;57(48):15717-15722. doi: 10.1002/anie.201809158. Epub 2018 Nov 02. PMID: 30239076.
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Noncovalent Interactions of π Systems with Sulfur: The Atomic Chameleon of Molecular Recognition.

Angewandte Chemie (International ed. in English)

Motherwell WB, Moreno RB, Pavlakos I, Arendorf JRT, Arif T, Tizzard GJ, Coles SJ, Aliev AE.
PMID: 29194884
Angew Chem Int Ed Engl. 2018 Jan 26;57(5):1193-1198. doi: 10.1002/anie.201708485. Epub 2017 Dec 28.

The relative strength of noncovalent interactions between a thioether sulfur atom and various π systems in designed top pan molecular balances was determined by NMR spectroscopy. Compared to its oxygen counterpart, the sulfur atom displays a remarkable ability to...

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Motherwell WB, Moreno RB, Pavlakos I, et al. Noncovalent Interactions of π Systems with Sulfur: The Atomic Chameleon of Molecular Recognition. Angew Chem Int Ed Engl. 2017;57(5):1193-1198doi: 10.1002/anie.201708485.
Motherwell, W. B., Moreno, R. B., Pavlakos, I., Arendorf, J. R. T., Arif, T., Tizzard, G. J., Coles, S. J., & Aliev, A. E. (2018). Noncovalent Interactions of π Systems with Sulfur: The Atomic Chameleon of Molecular Recognition. Angewandte Chemie (International ed. in English), 57(5), 1193-1198. https://doi.org/10.1002/anie.201708485
Motherwell, William B, et al. "Noncovalent Interactions of π Systems with Sulfur: The Atomic Chameleon of Molecular Recognition." Angewandte Chemie (International ed. in English) vol. 57,5 (2018): 1193-1198. doi: https://doi.org/10.1002/anie.201708485
Motherwell WB, Moreno RB, Pavlakos I, Arendorf JRT, Arif T, Tizzard GJ, Coles SJ, Aliev AE. Noncovalent Interactions of π Systems with Sulfur: The Atomic Chameleon of Molecular Recognition. Angew Chem Int Ed Engl. 2018 Jan 26;57(5):1193-1198. doi: 10.1002/anie.201708485. Epub 2017 Dec 28. PMID: 29194884.
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Pushing the photodelivery of nitric oxide to the visible: are {FeNO}.

Dalton transactions (Cambridge, England : 2003)

Levin N, Perdoménico J, Bill E, Weyhermüller T, Slep LD.
PMID: 29119166
Dalton Trans. 2017 Nov 28;46(46):16058-16064. doi: 10.1039/c7dt03142d.

Photodelivery of NO requires stable compounds which can be made reactive by irradiation with (visible) light. Traditional {MNO}

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Levin N, Perdoménico J, Bill E, et al. Pushing the photodelivery of nitric oxide to the visible: are {FeNO}. Dalton Trans. 2017;46(46):16058-16064doi: 10.1039/c7dt03142d.
Levin, N., Perdoménico, J., Bill, E., Weyhermüller, T., & Slep, L. D. (2017). Pushing the photodelivery of nitric oxide to the visible: are {FeNO}. Dalton transactions (Cambridge, England : 2003), 46(46), 16058-16064. https://doi.org/10.1039/c7dt03142d
Levin, Natalia, et al. "Pushing the photodelivery of nitric oxide to the visible: are {FeNO}." Dalton transactions (Cambridge, England : 2003) vol. 46,46 (2017): 16058-16064. doi: https://doi.org/10.1039/c7dt03142d
Levin N, Perdoménico J, Bill E, Weyhermüller T, Slep LD. Pushing the photodelivery of nitric oxide to the visible: are {FeNO}. Dalton Trans. 2017 Nov 28;46(46):16058-16064. doi: 10.1039/c7dt03142d. PMID: 29119166.
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Histopathologic and Ultrastructural Features of Inflamed Gingiva in the Baboon.

Journal of periodontology

Simpson DM, Avery BE.
PMID: 29538830
J Periodontol. 1974 Jul;45(7):500-510. doi: 10.1902/jop.1974.45.7.500.

No abstract available.

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Simpson DM, Avery BE. Histopathologic and Ultrastructural Features of Inflamed Gingiva in the Baboon. J Periodontol. 1974;45(7):500-510doi: 10.1902/jop.1974.45.7.500.
Simpson, D. M., & Avery, B. E. (1974). Histopathologic and Ultrastructural Features of Inflamed Gingiva in the Baboon. Journal of periodontology, 45(7), 500-510. https://doi.org/10.1902/jop.1974.45.7.500
Simpson, David M, and Avery, Bill E. "Histopathologic and Ultrastructural Features of Inflamed Gingiva in the Baboon." Journal of periodontology vol. 45,7 (1974): 500-510. doi: https://doi.org/10.1902/jop.1974.45.7.500
Simpson DM, Avery BE. Histopathologic and Ultrastructural Features of Inflamed Gingiva in the Baboon. J Periodontol. 1974 Jul;45(7):500-510. doi: 10.1902/jop.1974.45.7.500. PMID: 29538830.
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Redox Pairs of Diiron and Iron-Cobalt Complexes with High-Spin Ground States.

Inorganic chemistry

Miller DL, Siedschlag RB, Clouston LJ, Young VG, Chen YS, Bill E, Gagliardi L, Lu CC.
PMID: 27626109
Inorg Chem. 2016 Oct 03;55(19):9725-9735. doi: 10.1021/acs.inorgchem.6b01487. Epub 2016 Sep 14.

A series of iron and iron-cobalt bimetallic complexes were isolated: LFe

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Miller DL, Siedschlag RB, Clouston LJ, et al. Redox Pairs of Diiron and Iron-Cobalt Complexes with High-Spin Ground States. Inorg Chem. 2016;55(19):9725-9735doi: 10.1021/acs.inorgchem.6b01487.
Miller, D. L., Siedschlag, R. B., Clouston, L. J., Young, V. G., Chen, Y. S., Bill, E., Gagliardi, L., & Lu, C. C. (2016). Redox Pairs of Diiron and Iron-Cobalt Complexes with High-Spin Ground States. Inorganic chemistry, 55(19), 9725-9735. https://doi.org/10.1021/acs.inorgchem.6b01487
Miller, Deanna L, et al. "Redox Pairs of Diiron and Iron-Cobalt Complexes with High-Spin Ground States." Inorganic chemistry vol. 55,19 (2016): 9725-9735. doi: https://doi.org/10.1021/acs.inorgchem.6b01487
Miller DL, Siedschlag RB, Clouston LJ, Young VG, Chen YS, Bill E, Gagliardi L, Lu CC. Redox Pairs of Diiron and Iron-Cobalt Complexes with High-Spin Ground States. Inorg Chem. 2016 Oct 03;55(19):9725-9735. doi: 10.1021/acs.inorgchem.6b01487. Epub 2016 Sep 14. PMID: 27626109.
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Phenotypic Switching of Naïve T Cells to Immune-Suppressive Treg-Like Cells by Mutant KRAS.

Journal of clinical medicine

Kalvala A, Wallet P, Yang L, Wang C, Li H, Nam A, Nathan A, Mambetsariev I, Poroyko V, Gao H, Chu P, Sattler M, Bild A, Manuel ER, Lee PP, Jolly MK, Kulkarni P, Salgia R.
PMID: 31635338
J Clin Med. 2019 Oct 18;8(10). doi: 10.3390/jcm8101726.

Oncogenic (mutant) Ras protein Kirsten rat sarcoma viral oncogene homolog (KRAS) promotes uncontrolled proliferation, altered metabolism, and loss of genome integrity in a cell-intrinsic manner. Here, we demonstrate that CD4

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Kalvala A, Wallet P, Yang L, et al. Phenotypic Switching of Naïve T Cells to Immune-Suppressive Treg-Like Cells by Mutant KRAS. J Clin Med. 2019;8(10)doi: 10.3390/jcm8101726.
Kalvala, A., Wallet, P., Yang, L., Wang, C., Li, H., Nam, A., Nathan, A., Mambetsariev, I., Poroyko, V., Gao, H., Chu, P., Sattler, M., Bild, A., Manuel, E. R., Lee, P. P., Jolly, M. K., Kulkarni, P., & Salgia, R. (2019). Phenotypic Switching of Naïve T Cells to Immune-Suppressive Treg-Like Cells by Mutant KRAS. Journal of clinical medicine, 8(10), . https://doi.org/10.3390/jcm8101726
Kalvala, Arjun, et al. "Phenotypic Switching of Naïve T Cells to Immune-Suppressive Treg-Like Cells by Mutant KRAS." Journal of clinical medicine vol. 8,10 (2019). doi: https://doi.org/10.3390/jcm8101726
Kalvala A, Wallet P, Yang L, Wang C, Li H, Nam A, Nathan A, Mambetsariev I, Poroyko V, Gao H, Chu P, Sattler M, Bild A, Manuel ER, Lee PP, Jolly MK, Kulkarni P, Salgia R. Phenotypic Switching of Naïve T Cells to Immune-Suppressive Treg-Like Cells by Mutant KRAS. J Clin Med. 2019 Oct 18;8(10). doi: 10.3390/jcm8101726. PMID: 31635338; PMCID: PMC6832522.
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High Nuclearity Zn.

Angewandte Chemie (International ed. in English)

Lalioti N, Raptopoulou CP, Terzis A, Aliev AE, Gerothanassis IP, Manessi-Zoupa E, Perlepes SP.
PMID: 29712057
Angew Chem Int Ed Engl. 2001 Sep 03;40(17):3211-3214. doi: 10.1002/1521-3773(20010903)40:17<3211::AID-ANIE3211>3.0.CO;2-X.

The controlled cleavage of coordination polymers consisting of well-defined large units can be employed for the rational synthesis of high nuclearity clusters. This synthetic concept is demonstrated by the conversion (schematically shown) of a three-dimensional Zn

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Lalioti N, Raptopoulou CP, Terzis A, et al. High Nuclearity Zn. Angew Chem Int Ed Engl. 2001;40(17):3211-3214doi: 10.1002/1521-3773(20010903)40:17<3211::AID-ANIE3211>3.0.CO;2-X.
Lalioti, N., Raptopoulou, C. P., Terzis, A., Aliev, A. E., Gerothanassis, I. P., Manessi-Zoupa, E., & Perlepes, S. P. (2001). High Nuclearity Zn. Angewandte Chemie (International ed. in English), 40(17), 3211-3214. https://doi.org/10.1002/1521-3773(20010903)40:17<3211::AID-ANIE3211>3.0.CO;2-X
Lalioti, Nikolia, et al. "High Nuclearity Zn." Angewandte Chemie (International ed. in English) vol. 40,17 (2001): 3211-3214. doi: https://doi.org/10.1002/1521-3773(20010903)40:17<3211::AID-ANIE3211>3.0.CO;2-X
Lalioti N, Raptopoulou CP, Terzis A, Aliev AE, Gerothanassis IP, Manessi-Zoupa E, Perlepes SP. High Nuclearity Zn. Angew Chem Int Ed Engl. 2001 Sep 03;40(17):3211-3214. doi: 10.1002/1521-3773(20010903)40:17<3211::AID-ANIE3211>3.0.CO;2-X. PMID: 29712057.
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Hydration of Atmospheric Molecular Clusters II: Organic Acid-Water Clusters.

The journal of physical chemistry. A

Kildgaard JV, Mikkelsen KV, Bilde M, Elm J.
PMID: 30351100
J Phys Chem A. 2018 Nov 01;122(43):8549-8556. doi: 10.1021/acs.jpca.8b07713. Epub 2018 Oct 24.

Using computational methods, we study the gas phase hydration of three different atmospherically relevant organic acids with up to 10 water molecules. We study a dicarboxylic acid (pinic acid) and a tricarboxylic acid (3-methyl-1,2,3-butanetricarboxylic acid (mbtca)) that are both...

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Kildgaard JV, Mikkelsen KV, Bilde M, et al. Hydration of Atmospheric Molecular Clusters II: Organic Acid-Water Clusters. J Phys Chem A. 2018;122(43):8549-8556doi: 10.1021/acs.jpca.8b07713.
Kildgaard, J. V., Mikkelsen, K. V., Bilde, M., & Elm, J. (2018). Hydration of Atmospheric Molecular Clusters II: Organic Acid-Water Clusters. The journal of physical chemistry. A, 122(43), 8549-8556. https://doi.org/10.1021/acs.jpca.8b07713
Kildgaard, Jens Vive, et al. "Hydration of Atmospheric Molecular Clusters II: Organic Acid-Water Clusters." The journal of physical chemistry. A vol. 122,43 (2018): 8549-8556. doi: https://doi.org/10.1021/acs.jpca.8b07713
Kildgaard JV, Mikkelsen KV, Bilde M, Elm J. Hydration of Atmospheric Molecular Clusters II: Organic Acid-Water Clusters. J Phys Chem A. 2018 Nov 01;122(43):8549-8556. doi: 10.1021/acs.jpca.8b07713. Epub 2018 Oct 24. PMID: 30351100.
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Supplementation of docosahexaenoic acid (DHA), vitamin D.

BMC nutrition

Hansen SL, Ritterband-Rosenbaum A, Voigt CB, Hellgren LI, Sørensen AM, Jacobsen C, Greve LZ, Jørgensen KD, Bilde PE, Kiens B, Nielsen JB.
PMID: 32153817
BMC Nutr. 2017 Apr 17;3:37. doi: 10.1186/s40795-017-0155-1. eCollection 2017.

BACKGROUND: Learning and memory have been shown to be influenced by combination of dietary supplements and exercise in animal models, but there is little available evidence from human subjects. The aim of this pilot study was to investigate the...

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Hansen SL, Ritterband-Rosenbaum A, Voigt CB, et al. Supplementation of docosahexaenoic acid (DHA), vitamin D. BMC Nutr. 2017;3:37doi: 10.1186/s40795-017-0155-1.
Hansen, S. L., Ritterband-Rosenbaum, A., Voigt, C. B., Hellgren, L. I., Sørensen, A. M., Jacobsen, C., Greve, L. Z., Jørgensen, K. D., Bilde, P. E., Kiens, B., & Nielsen, J. B. (2017). Supplementation of docosahexaenoic acid (DHA), vitamin D. BMC nutrition, 337. https://doi.org/10.1186/s40795-017-0155-1
Hansen, Solvejg L, et al. "Supplementation of docosahexaenoic acid (DHA), vitamin D." BMC nutrition vol. 3 (2017): 37. doi: https://doi.org/10.1186/s40795-017-0155-1
Hansen SL, Ritterband-Rosenbaum A, Voigt CB, Hellgren LI, Sørensen AM, Jacobsen C, Greve LZ, Jørgensen KD, Bilde PE, Kiens B, Nielsen JB. Supplementation of docosahexaenoic acid (DHA), vitamin D. BMC Nutr. 2017 Apr 17;3:37. doi: 10.1186/s40795-017-0155-1. eCollection 2017. PMID: 32153817; PMCID: PMC7050862.
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Electron Paramagnetic Resonance Signature of Tetragonal Low Spin Iron(V)-Nitrido and -Oxo Complexes Derived from the Electronic Structure Analysis of Heme and Non-Heme Archetypes.

Journal of the American Chemical Society

Chang HC, Mondal B, Fang H, Neese F, Bill E, Ye S.
PMID: 30620571
J Am Chem Soc. 2019 Feb 13;141(6):2421-2434. doi: 10.1021/jacs.8b11429. Epub 2019 Jan 30.

Iron(V)-nitrido and -oxo complexes have been proposed as key intermediates in a diverse array of chemical transformations. Herein we present a detailed electronic-structure analysis of [Fe

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Chang HC, Mondal B, Fang H, et al. Electron Paramagnetic Resonance Signature of Tetragonal Low Spin Iron(V)-Nitrido and -Oxo Complexes Derived from the Electronic Structure Analysis of Heme and Non-Heme Archetypes. J Am Chem Soc. 2019;141(6):2421-2434doi: 10.1021/jacs.8b11429.
Chang, H. C., Mondal, B., Fang, H., Neese, F., Bill, E., & Ye, S. (2019). Electron Paramagnetic Resonance Signature of Tetragonal Low Spin Iron(V)-Nitrido and -Oxo Complexes Derived from the Electronic Structure Analysis of Heme and Non-Heme Archetypes. Journal of the American Chemical Society, 141(6), 2421-2434. https://doi.org/10.1021/jacs.8b11429
Chang, Hao-Ching, et al. "Electron Paramagnetic Resonance Signature of Tetragonal Low Spin Iron(V)-Nitrido and -Oxo Complexes Derived from the Electronic Structure Analysis of Heme and Non-Heme Archetypes." Journal of the American Chemical Society vol. 141,6 (2019): 2421-2434. doi: https://doi.org/10.1021/jacs.8b11429
Chang HC, Mondal B, Fang H, Neese F, Bill E, Ye S. Electron Paramagnetic Resonance Signature of Tetragonal Low Spin Iron(V)-Nitrido and -Oxo Complexes Derived from the Electronic Structure Analysis of Heme and Non-Heme Archetypes. J Am Chem Soc. 2019 Feb 13;141(6):2421-2434. doi: 10.1021/jacs.8b11429. Epub 2019 Jan 30. PMID: 30620571; PMCID: PMC6728100.
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Role of Valence Band States and Plasmonic Enhancement in Electron-Transfer-Induced Transformation of Nitrothiophenol.

The journal of physical chemistry letters

Schürmann R, Ebel K, Nicolas C, Milosavljević AR, Bald I.
PMID: 31117676
J Phys Chem Lett. 2019 Jun 06;10(11):3153-3158. doi: 10.1021/acs.jpclett.9b00848. Epub 2019 May 28.

Hot-electron-induced reactions are more and more recognized as a critical and ubiquitous reaction in heterogeneous catalysis. However, the kinetics of these reactions is still poorly understood, which is also due to the complexity of plasmonic nanostructures. We determined the...

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Schürmann R, Ebel K, Nicolas C, et al. Role of Valence Band States and Plasmonic Enhancement in Electron-Transfer-Induced Transformation of Nitrothiophenol. J Phys Chem Lett. 2019;10(11):3153-3158doi: 10.1021/acs.jpclett.9b00848.
Schürmann, R., Ebel, K., Nicolas, C., Milosavljević, A. R., & Bald, I. (2019). Role of Valence Band States and Plasmonic Enhancement in Electron-Transfer-Induced Transformation of Nitrothiophenol. The journal of physical chemistry letters, 10(11), 3153-3158. https://doi.org/10.1021/acs.jpclett.9b00848
Schürmann, Robin, et al. "Role of Valence Band States and Plasmonic Enhancement in Electron-Transfer-Induced Transformation of Nitrothiophenol." The journal of physical chemistry letters vol. 10,11 (2019): 3153-3158. doi: https://doi.org/10.1021/acs.jpclett.9b00848
Schürmann R, Ebel K, Nicolas C, Milosavljević AR, Bald I. Role of Valence Band States and Plasmonic Enhancement in Electron-Transfer-Induced Transformation of Nitrothiophenol. J Phys Chem Lett. 2019 Jun 06;10(11):3153-3158. doi: 10.1021/acs.jpclett.9b00848. Epub 2019 May 28. PMID: 31117676; PMCID: PMC6569622.
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A metastable Ru.

Chemical communications (Cambridge, England)

Park SV, Fry CG, Bill E, Berry JF.
PMID: 32789338
Chem Commun (Camb). 2020 Sep 15;56(73):10738-10741. doi: 10.1039/d0cc04426a.

The metastable purple [(Py5Me2)RuIII(N3)]2+ ion reacts with PPh3 at room temperature to form the phosphinimine complex [(Py5Me2)RuII(N(H)PPh3)]2+ and free [H2NPPh3]+ in a combined 23% conversion. Mechanistic studies suggest that this is the first metallo-Staudinger reaction of a late transition...

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Park SV, Fry CG, Bill E, et al. A metastable Ru. Chem Commun (Camb). 2020;56(73):10738-10741doi: 10.1039/d0cc04426a.
Park, S. V., Fry, C. G., Bill, E., & Berry, J. F. (2020). A metastable Ru. Chemical communications (Cambridge, England), 56(73), 10738-10741. https://doi.org/10.1039/d0cc04426a
Park, Sungho V, et al. "A metastable Ru." Chemical communications (Cambridge, England) vol. 56,73 (2020): 10738-10741. doi: https://doi.org/10.1039/d0cc04426a
Park SV, Fry CG, Bill E, Berry JF. A metastable Ru. Chem Commun (Camb). 2020 Sep 15;56(73):10738-10741. doi: 10.1039/d0cc04426a. PMID: 32789338.
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