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Showing 37 to 48 of 119 entries
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Separation of Branched Poly(bisphenol A carbonate) Structures by Solvent Gradient at Near-Critical Conditions and Two-Dimensional Liquid Chromatography.

Analytical chemistry

Apel N, Uliyanchenko E, Moyses S, Rommens S, Wold C, Macko T, Brüll R.
PMID: 29600700
Anal Chem. 2018 Apr 17;90(8):5422-5429. doi: 10.1021/acs.analchem.8b00618. Epub 2018 Apr 04.

Branching is a molecular metric that strongly influences the application properties of polymers. Consequently, detailed information on the microstructure is required to gain a deeper understanding of structure-property relationships. In the present case, we employ high-performance liquid chromatography to...

A new fluorescence-based reporter gene vector as a tool for analyzing and fishing cells with activated wnt signaling pathway.

ISRN oncology

Apfel J, Reischmann P, Müller O.
PMID: 24066239
ISRN Oncol. 2013 Aug 28;2013:603129. doi: 10.1155/2013/603129. eCollection 2013.

The dysregulated Wnt pathway is a major cause for the activation of cell proliferation and reduced differentiation in tumor cells. Therefore the Wnt signaling pathway is the on-top target in searching for new anticancer drugs or therapeutic strategies. Although...

In vitro detection of cavitation induced by a diagnostic ultrasound system.

IEEE transactions on ultrasonics, ferroelectrics, and frequency control

Holland CK, Roy RA, Apfel RE, Crum LA.
PMID: 18263123
IEEE Trans Ultrason Ferroelectr Freq Control. 1992;39(1):95-101. doi: 10.1109/58.166815.

Experiments were performed to determine whether a clinical diagnostic scanner, a Hewlett-Packard (HP) 77020A, could produce cavitation in water containing suspensions of either 0.245-mum polystyrene spheres or Albunex, 1-10 mum albumin-coated microbubbles. Two calibrated, phased-array HP imaging transducers with...

Incomplete guidelines.

Anesthesia and analgesia

Gan TJ, Meyer T, Apfel CC, Chung F, Davis PJ, Eubanks S, Kovac A, Philip B, Sessler DI, Temo J, Tramèr MR, Watcha M.
PMID: 14742407
Anesth Analg. 2004 Feb;98(2):550-551. doi: 10.1213/01.ANE.0000077703.55641.EC.

No abstract available.

Coupling an ultrasonic propagation code with a model of the heterogeneity of multipass welds to simulate ultrasonic testing.

Ultrasonics

Apfel A, Moysan J, Corneloup G, Fouquet T, Chassignole B.
PMID: 15823319
Ultrasonics. 2005 May;43(6):447-56. doi: 10.1016/j.ultras.2004.09.004.

The knowledge of the anisotropic and heterogeneous behaviour of the material is the key point for understanding ultrasonic testing. In the case of austenitic stainless steel multipass welds, there was no exact knowledge. The succession of passes and complex...

Graphical method to design multilayer phase retarders.

Applied optics

Apfel JH.
PMID: 20309253
Appl Opt. 1981 Mar 15;20(6):1024-9. doi: 10.1364/AO.20.001024.

When multilayer reflectors are used at nonnormal incidence, the two planes of polarization generally have different phase shifts. This difference, known as phase retardance, depends on the multilayer design, the incidence angle, and the wavelength. Heretofore, the design of...

Controlled Flexible Coordination in Tripodal Iron(II) Phosphane Complexes: Effects on Reactivity.

Inorganic chemistry

Petuker A, Merz K, Merten C, Apfel UP.
PMID: 26751622
Inorg Chem. 2016 Feb 01;55(3):1183-91. doi: 10.1021/acs.inorgchem.5b02361. Epub 2016 Jan 11.

The possibility to alter properties of metal complexes without significant steric changes is a useful tool to tailor the reactivity of the complexes. Herein we present the synthesis of iron complexes with the tripodal phosphane ligands Triphos and Triphos(Si)...

Modulation of the CO.

Dalton transactions (Cambridge, England : 2003)

Möller F, Castañeda-Losada L, Junqueira JRC, Miller RG, Reback ML, Mallick B, van Gastel M, Apfel UP.
PMID: 28220915
Dalton Trans. 2017 May 02;46(17):5680-5688. doi: 10.1039/c6dt04527h.

While bimetallic azacryptands are known to selectively coordinate CO

A dinuclear porphyrin-macrocycle as efficient catalyst for the hydrogen evolution reaction.

Chemical communications (Cambridge, England)

Jökel J, Schwer F, von Delius M, Apfel UP.
PMID: 33107896
Chem Commun (Camb). 2020 Nov 25;56(91):14179-14182. doi: 10.1039/d0cc05229a. Epub 2020 Oct 27.

We report an unprecedented dinuclear catalyst for the electrochemical hydrogen evolution reaction (HER). A macrocyclic porphyrin complex comprising two nickel centres connected via redox mediating linker molecules gives rise to efficient catalysis, significantly outperforming a mononuclear reference catalyst.

Introducing Water-Network-Assisted Proton Transfer for Boosted Electrocatalytic Hydrogen Evolution with Cobalt Corrole.

Angewandte Chemie (International ed. in English)

Li X, Lv B, Zhang XP, Jin X, Guo K, Zhou D, Bian H, Zhang W, Apfel UP, Cao R.
PMID: 34913230
Angew Chem Int Ed Engl. 2021 Dec 15; doi: 10.1002/anie.202114310. Epub 2021 Dec 15.

Proton transfer is vital for many biological and chemical reactions. Hydrogen-bonded water-containing networks are often found in enzymes to assist proton transfer, but similar strategy has been rarely presented by synthetic catalysts. We herein report the Co corrole 1...

Shedding Light on Proton and Electron Dynamics in [FeFe] Hydrogenases.

Journal of the American Chemical Society

Lorent C, Katz S, Duan J, Kulka CJ, Caserta G, Teutloff C, Yadav S, Apfel UP, Winkler M, Happe T, Horch M, Zebger I.
PMID: 32125830
J Am Chem Soc. 2020 Mar 25;142(12):5493-5497. doi: 10.1021/jacs.9b13075. Epub 2020 Mar 16.

[FeFe] hydrogenases are highly efficient catalysts for reversible dihydrogen evolution. H

Synthetic approaches to artificial photosynthesis: general discussion.

Faraday discussions

Aitchison CM, Andrei V, Antón-García D, Apfel UP, Badiani V, Beller M, Bocarsly AB, Bonnet S, Brueggeller P, Caputo CA, Cassiola F, Clausing ST, Cooper AI, Creissen CE, de la Peña O'Shea VA, Domcke W, Durrant JR, Grätzel M, Hammarström L, Hankin A, Hatzell MC, Karadas F, König B, Kuehnel MF, Lamaison S, Lin CY, Maneiro M, Minteer SD, R Paris A, Pastor E, Pornrungroj C, Reek JNH, Reisner E, Roy S, Sahm C, Shankar R, Shaw WJ, Shylin SI, Smith WA, Sokol K, Soo HS, Sprick RS, Viertl W, Vogel A, Wagner A, Wakerley D, Wang Q, Wielend D, Zwijnenburg MA.
PMID: 31236549
Faraday Discuss. 2019 Jul 04;215:242-281. doi: 10.1039/C9FD90024A.

No abstract available.

Showing 37 to 48 of 119 entries