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Bio-inspired design: bulk iron-nickel sulfide allows for efficient solvent-dependent CO.

Chemical science

Piontek S, Junge Puring K, Siegmund D, Smialkowski M, Sinev I, Tetzlaff D, Roldan Cuenya B, Apfel UP.
PMID: 30774904
Chem Sci. 2018 Nov 06;10(4):1075-1081. doi: 10.1039/c8sc03555e. eCollection 2019 Jan 28.

The electrocatalytic reduction of carbon dioxide (CO

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Piontek S, Junge Puring K, Siegmund D, et al. Bio-inspired design: bulk iron-nickel sulfide allows for efficient solvent-dependent CO. Chem Sci. 2018;10(4):1075-1081doi: 10.1039/c8sc03555e.
Piontek, S., Junge Puring, K., Siegmund, D., Smialkowski, M., Sinev, I., Tetzlaff, D., Roldan Cuenya, B., & Apfel, U. P. (2019). Bio-inspired design: bulk iron-nickel sulfide allows for efficient solvent-dependent CO. Chemical science, 10(4), 1075-1081. https://doi.org/10.1039/c8sc03555e
Piontek, Stefan, et al. "Bio-inspired design: bulk iron-nickel sulfide allows for efficient solvent-dependent CO." Chemical science vol. 10,4 (2019): 1075-1081. doi: https://doi.org/10.1039/c8sc03555e
Piontek S, Junge Puring K, Siegmund D, Smialkowski M, Sinev I, Tetzlaff D, Roldan Cuenya B, Apfel UP. Bio-inspired design: bulk iron-nickel sulfide allows for efficient solvent-dependent CO. Chem Sci. 2018 Nov 06;10(4):1075-1081. doi: 10.1039/c8sc03555e. eCollection 2019 Jan 28. PMID: 30774904; PMCID: PMC6346401.
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Pegbelfermin selectively reduces secondary bile acid concentrations in patients with non-alcoholic steatohepatitis.

JHEP reports : innovation in hepatology

Luo Y, Decato BE, Charles ED, Shevell DE, McNaney C, Shipkova P, Apfel A, Tirucherai GS, Sanyal AJ.
PMID: 34977519
JHEP Rep. 2021 Nov 12;4(1):100392. doi: 10.1016/j.jhepr.2021.100392. eCollection 2022 Jan.

BACKGROUND & AIMS: Increased serum bile acids (BAs) have been observed in patients with non-alcoholic steatohepatitis (NASH). Pegbelfermin (PGBF), a polyethylene glycol-modified (PEGylated) analogue of human fibroblast growth factor 21 (FGF21), significantly decreased hepatic steatosis and improved fibrosis biomarkers...

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Luo Y, Decato BE, Charles ED, et al. Pegbelfermin selectively reduces secondary bile acid concentrations in patients with non-alcoholic steatohepatitis. JHEP Rep. 2021;4(1):100392doi: 10.1016/j.jhepr.2021.100392.
Luo, Y., Decato, B. E., Charles, E. D., Shevell, D. E., McNaney, C., Shipkova, P., Apfel, A., Tirucherai, G. S., & Sanyal, A. J. (2022). Pegbelfermin selectively reduces secondary bile acid concentrations in patients with non-alcoholic steatohepatitis. JHEP reports : innovation in hepatology, 4(1), 100392. https://doi.org/10.1016/j.jhepr.2021.100392
Luo, Yi, et al. "Pegbelfermin selectively reduces secondary bile acid concentrations in patients with non-alcoholic steatohepatitis." JHEP reports : innovation in hepatology vol. 4,1 (2022): 100392. doi: https://doi.org/10.1016/j.jhepr.2021.100392
Luo Y, Decato BE, Charles ED, Shevell DE, McNaney C, Shipkova P, Apfel A, Tirucherai GS, Sanyal AJ. Pegbelfermin selectively reduces secondary bile acid concentrations in patients with non-alcoholic steatohepatitis. JHEP Rep. 2021 Nov 12;4(1):100392. doi: 10.1016/j.jhepr.2021.100392. eCollection 2022 Jan. PMID: 34977519; PMCID: PMC8689226.
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Enzyme-Inspired Iron Porphyrins for Improved Electrocatalytic Oxygen Reduction and Evolution Reactions.

Angewandte Chemie (International ed. in English)

Xie L, Zhang XP, Zhao B, Li P, Qi J, Guo X, Wang B, Lei H, Zhang W, Apfel UP, Cao R.
PMID: 33462971
Angew Chem Int Ed Engl. 2021 Mar 29;60(14):7576-7581. doi: 10.1002/anie.202015478. Epub 2021 Feb 26.

Nature uses Fe porphyrin sites for the oxygen reduction reaction (ORR). Synthetic Fe porphyrins have been extensively studied as ORR catalysts, but activity improvement is required. On the other hand, Fe porphyrins have been rarely shown to be efficient...

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Xie L, Zhang XP, Zhao B, et al. Enzyme-Inspired Iron Porphyrins for Improved Electrocatalytic Oxygen Reduction and Evolution Reactions. Angew Chem Int Ed Engl. 2021;60(14):7576-7581doi: 10.1002/anie.202015478.
Xie, L., Zhang, X. P., Zhao, B., Li, P., Qi, J., Guo, X., Wang, B., Lei, H., Zhang, W., Apfel, U. P., & Cao, R. (2021). Enzyme-Inspired Iron Porphyrins for Improved Electrocatalytic Oxygen Reduction and Evolution Reactions. Angewandte Chemie (International ed. in English), 60(14), 7576-7581. https://doi.org/10.1002/anie.202015478
Xie, Lisi, et al. "Enzyme-Inspired Iron Porphyrins for Improved Electrocatalytic Oxygen Reduction and Evolution Reactions." Angewandte Chemie (International ed. in English) vol. 60,14 (2021): 7576-7581. doi: https://doi.org/10.1002/anie.202015478
Xie L, Zhang XP, Zhao B, Li P, Qi J, Guo X, Wang B, Lei H, Zhang W, Apfel UP, Cao R. Enzyme-Inspired Iron Porphyrins for Improved Electrocatalytic Oxygen Reduction and Evolution Reactions. Angew Chem Int Ed Engl. 2021 Mar 29;60(14):7576-7581. doi: 10.1002/anie.202015478. Epub 2021 Feb 26. PMID: 33462971.
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Patient isolation for infection control and patient experience.

Infection control and hospital epidemiology

Siddiqui ZK, Conway SJ, Abusamaan M, Bertram A, Berry SA, Allen L, Apfel A, Farley H, Zhu J, Wu AW, Brotman DJ.
PMID: 30560748
Infect Control Hosp Epidemiol. 2019 Feb;40(2):194-199. doi: 10.1017/ice.2018.324. Epub 2018 Dec 18.

OBJECTIVE: Hospitalized patients placed in isolation due to a carrier state or infection with resistant or highly communicable organisms report higher rates of anxiety and loneliness and have fewer physician encounters, room entries, and vital sign records. We hypothesized...

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Siddiqui ZK, Conway SJ, Abusamaan M, et al. Patient isolation for infection control and patient experience. Infect Control Hosp Epidemiol. 2018;40(2):194-199doi: 10.1017/ice.2018.324.
Siddiqui, Z. K., Conway, S. J., Abusamaan, M., Bertram, A., Berry, S. A., Allen, L., Apfel, A., Farley, H., Zhu, J., Wu, A. W., & Brotman, D. J. (2019). Patient isolation for infection control and patient experience. Infection control and hospital epidemiology, 40(2), 194-199. https://doi.org/10.1017/ice.2018.324
Siddiqui, Zishan K, et al. "Patient isolation for infection control and patient experience." Infection control and hospital epidemiology vol. 40,2 (2019): 194-199. doi: https://doi.org/10.1017/ice.2018.324
Siddiqui ZK, Conway SJ, Abusamaan M, Bertram A, Berry SA, Allen L, Apfel A, Farley H, Zhu J, Wu AW, Brotman DJ. Patient isolation for infection control and patient experience. Infect Control Hosp Epidemiol. 2019 Feb;40(2):194-199. doi: 10.1017/ice.2018.324. Epub 2018 Dec 18. PMID: 30560748.
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Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO.

Dalton transactions (Cambridge, England : 2003)

Gerschel P, Warm K, Farquhar ER, Englert U, Reback ML, Siegmund D, Ray K, Apfel UP.
PMID: 30624449
Dalton Trans. 2019 May 07;48(18):5923-5932. doi: 10.1039/c8dt04740e.

The replacement of the opposing nitrogen atoms in 1,4,8,11-tetraazacyclotetradecane (cyclam) with two sulfur atoms in 1,8-dithia-4,11-diazacyclotetradecane (dithiacyclam) enables the electrochemical reduction of protons and CO2via the corresponding nickel(ii) complex at more positive potentials. In addition, a 10-fold enhancement in...

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Gerschel P, Warm K, Farquhar ER, et al. Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO. Dalton Trans. 2019;48(18):5923-5932doi: 10.1039/c8dt04740e.
Gerschel, P., Warm, K., Farquhar, E. R., Englert, U., Reback, M. L., Siegmund, D., Ray, K., & Apfel, U. P. (2019). Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO. Dalton transactions (Cambridge, England : 2003), 48(18), 5923-5932. https://doi.org/10.1039/c8dt04740e
Gerschel, P, et al. "Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO." Dalton transactions (Cambridge, England : 2003) vol. 48,18 (2019): 5923-5932. doi: https://doi.org/10.1039/c8dt04740e
Gerschel P, Warm K, Farquhar ER, Englert U, Reback ML, Siegmund D, Ray K, Apfel UP. Sulfur substitution in a Ni(cyclam) derivative results in lower overpotential for CO. Dalton Trans. 2019 May 07;48(18):5923-5932. doi: 10.1039/c8dt04740e. PMID: 30624449; PMCID: PMC6504587.
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Water-Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction.

Angewandte Chemie (International ed. in English)

Xie L, Tian J, Ouyang Y, Guo X, Zhang W, Apfel UP, Zhang W, Cao R.
PMID: 32458538
Angew Chem Int Ed Engl. 2020 Sep 07;59(37):15844-15848. doi: 10.1002/anie.202003836. Epub 2020 Jun 29.

Molecular design to improve catalyst performance is significant but challenging. In enzymes, residue groups that are close to reaction centers play critical roles in regulating activities. Using this bioinspired strategy, three water-soluble polymers were designed with appending Co porphyrins...

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Xie L, Tian J, Ouyang Y, et al. Water-Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction. Angew Chem Int Ed Engl. 2020;59(37):15844-15848doi: 10.1002/anie.202003836.
Xie, L., Tian, J., Ouyang, Y., Guo, X., Zhang, W., Apfel, U. P., Zhang, W., & Cao, R. (2020). Water-Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction. Angewandte Chemie (International ed. in English), 59(37), 15844-15848. https://doi.org/10.1002/anie.202003836
Xie, Lisi, et al. "Water-Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction." Angewandte Chemie (International ed. in English) vol. 59,37 (2020): 15844-15848. doi: https://doi.org/10.1002/anie.202003836
Xie L, Tian J, Ouyang Y, Guo X, Zhang W, Apfel UP, Zhang W, Cao R. Water-Soluble Polymers with Appending Porphyrins as Bioinspired Catalysts for the Hydrogen Evolution Reaction. Angew Chem Int Ed Engl. 2020 Sep 07;59(37):15844-15848. doi: 10.1002/anie.202003836. Epub 2020 Jun 29. PMID: 32458538.
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Enhancing the CO.

Chemistry (Weinheim an der Bergstrasse, Germany)

Pellumbi K, Smialkowski M, Siegmund D, Apfel UP.
PMID: 32368814
Chemistry. 2020 Aug 06;26(44):9938-9944. doi: 10.1002/chem.202001289. Epub 2020 Jul 08.

The electrochemical reduction of CO

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Pellumbi K, Smialkowski M, Siegmund D, et al. Enhancing the CO. Chemistry. 2020;26(44):9938-9944doi: 10.1002/chem.202001289.
Pellumbi, K., Smialkowski, M., Siegmund, D., & Apfel, U. P. (2020). Enhancing the CO. Chemistry (Weinheim an der Bergstrasse, Germany), 26(44), 9938-9944. https://doi.org/10.1002/chem.202001289
Pellumbi, Kevinjeorjios, et al. "Enhancing the CO." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 26,44 (2020): 9938-9944. doi: https://doi.org/10.1002/chem.202001289
Pellumbi K, Smialkowski M, Siegmund D, Apfel UP. Enhancing the CO. Chemistry. 2020 Aug 06;26(44):9938-9944. doi: 10.1002/chem.202001289. Epub 2020 Jul 08. PMID: 32368814; PMCID: PMC7496145.
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In Response.

Anesthesia and analgesia

Jin Z, Gan TJ, Belani KG, Bergese S, Chung F, Diemunsch P, Habib AS, Kovac AL, Meyer TA, Urman RD, Apfel CC, Ayad S, Beagley L, Candiotti K, Englesakis M, Hedrick TL, Kranke P, Lee S, Lipman D, Minkowitz HS, Morton J, Philip BK.
PMID: 33449569
Anesth Analg. 2021 Feb 01;132(2):e31-e33. doi: 10.1213/ANE.0000000000005280.

No abstract available.

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Jin Z, Gan TJ, Belani KG, et al. In Response. Anesth Analg. 2021;132(2):e31-e33doi: 10.1213/ANE.0000000000005280.
Jin, Z., Gan, T. J., Belani, K. G., Bergese, S., Chung, F., Diemunsch, P., Habib, A. S., Kovac, A. L., Meyer, T. A., Urman, R. D., Apfel, C. C., Ayad, S., Beagley, L., Candiotti, K., Englesakis, M., Hedrick, T. L., Kranke, P., Lee, S., Lipman, D., Minkowitz, H. S., Morton, J., & Philip, B. K. (2021). In Response. Anesthesia and analgesia, 132(2), e31-e33. https://doi.org/10.1213/ANE.0000000000005280
Jin, Zhaosheng, et al. "In Response." Anesthesia and analgesia vol. 132,2 (2021): e31-e33. doi: https://doi.org/10.1213/ANE.0000000000005280
Jin Z, Gan TJ, Belani KG, Bergese S, Chung F, Diemunsch P, Habib AS, Kovac AL, Meyer TA, Urman RD, Apfel CC, Ayad S, Beagley L, Candiotti K, Englesakis M, Hedrick TL, Kranke P, Lee S, Lipman D, Minkowitz HS, Morton J, Philip BK. In Response. Anesth Analg. 2021 Feb 01;132(2):e31-e33. doi: 10.1213/ANE.0000000000005280. PMID: 33449569.
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Sustainable and rapid preparation of nanosized Fe/Ni-pentlandite particles by mechanochemistry.

Chemical science

Tetzlaff D, Pellumbi K, Baier DM, Hoof L, Shastry Barkur H, Smialkowski M, Amin HMA, Grätz S, Siegmund D, Borchardt L, Apfel UP.
PMID: 34094479
Chem Sci. 2020 Nov 05;11(47):12835-12842. doi: 10.1039/d0sc04525j.

In recent years, metal-rich sulfides of the pentlandite type (M

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Tetzlaff D, Pellumbi K, Baier DM, et al. Sustainable and rapid preparation of nanosized Fe/Ni-pentlandite particles by mechanochemistry. Chem Sci. 2020;11(47):12835-12842doi: 10.1039/d0sc04525j.
Tetzlaff, D., Pellumbi, K., Baier, D. M., Hoof, L., Shastry Barkur, H., Smialkowski, M., Amin, H. M. A., Grätz, S., Siegmund, D., Borchardt, L., & Apfel, U. P. (2020). Sustainable and rapid preparation of nanosized Fe/Ni-pentlandite particles by mechanochemistry. Chemical science, 11(47), 12835-12842. https://doi.org/10.1039/d0sc04525j
Tetzlaff, David, et al. "Sustainable and rapid preparation of nanosized Fe/Ni-pentlandite particles by mechanochemistry." Chemical science vol. 11,47 (2020): 12835-12842. doi: https://doi.org/10.1039/d0sc04525j
Tetzlaff D, Pellumbi K, Baier DM, Hoof L, Shastry Barkur H, Smialkowski M, Amin HMA, Grätz S, Siegmund D, Borchardt L, Apfel UP. Sustainable and rapid preparation of nanosized Fe/Ni-pentlandite particles by mechanochemistry. Chem Sci. 2020 Nov 05;11(47):12835-12842. doi: 10.1039/d0sc04525j. PMID: 34094479; PMCID: PMC8163287.
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Local and Intra-articular Administration of Nonsteroidal Anti-inflammatory Drugs for Pain Management in Orthopedic Surgery.

American journal of therapeutics

Bernthal NM, Hart CM, Sheth KR, Bergese SD, Ho HS, Apfel CC, Stoicea N, Rojhani A, Jahr JS.
PMID: 33315593
Am J Ther. 2020 Dec 10; doi: 10.1097/MJT.0000000000001309. Epub 2020 Dec 10.

BACKGROUND: Although growing evidence demonstrates the benefits of locally administered nonsteroidal anti-inflammatory drugs (NSAIDs) for postoperative pain management, there is ongoing debate regarding NSAID use in orthopedic surgery.AREAS OF UNCERTAINTY: Current data largely support a local site of NSAID...

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Bernthal NM, Hart CM, Sheth KR, et al. Local and Intra-articular Administration of Nonsteroidal Anti-inflammatory Drugs for Pain Management in Orthopedic Surgery. Am J Ther. 2020;doi: 10.1097/MJT.0000000000001309.
Bernthal, N. M., Hart, C. M., Sheth, K. R., Bergese, S. D., Ho, H. S., Apfel, C. C., Stoicea, N., Rojhani, A., & Jahr, J. S. (2020). Local and Intra-articular Administration of Nonsteroidal Anti-inflammatory Drugs for Pain Management in Orthopedic Surgery. American journal of therapeutics, . https://doi.org/10.1097/MJT.0000000000001309
Bernthal, Nicholas M, et al. "Local and Intra-articular Administration of Nonsteroidal Anti-inflammatory Drugs for Pain Management in Orthopedic Surgery." American journal of therapeutics vol. (2020). doi: https://doi.org/10.1097/MJT.0000000000001309
Bernthal NM, Hart CM, Sheth KR, Bergese SD, Ho HS, Apfel CC, Stoicea N, Rojhani A, Jahr JS. Local and Intra-articular Administration of Nonsteroidal Anti-inflammatory Drugs for Pain Management in Orthopedic Surgery. Am J Ther. 2020 Dec 10; doi: 10.1097/MJT.0000000000001309. Epub 2020 Dec 10. PMID: 33315593.
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Characteristics of Rotator Cuff Repairs Revised to Shoulder Arthroplasty.

The archives of bone and joint surgery

Apfel A, Lin CC, Burfeind W, Dillon MT, Navarro RA.
PMID: 33088858
Arch Bone Jt Surg. 2020 Sep;8(5):575-580. doi: 10.22038/abjs.2020.39006.2042.

BACKGROUND: Successful repair of a torn rotator cuff may prevent progression to rotator cuff arthropathy. However, previous studies have shown a substantial rate of failure after rotator cuff repair and characteristics of surgically repaired rotator cuffs that go on...

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Apfel A, Lin CC, Burfeind W, et al. Characteristics of Rotator Cuff Repairs Revised to Shoulder Arthroplasty. Arch Bone Jt Surg. 2020;8(5):575-580doi: 10.22038/abjs.2020.39006.2042.
Apfel, A., Lin, C. C., Burfeind, W., Dillon, M. T., & Navarro, R. A. (2020). Characteristics of Rotator Cuff Repairs Revised to Shoulder Arthroplasty. The archives of bone and joint surgery, 8(5), 575-580. https://doi.org/10.22038/abjs.2020.39006.2042
Apfel, Allison, et al. "Characteristics of Rotator Cuff Repairs Revised to Shoulder Arthroplasty." The archives of bone and joint surgery vol. 8,5 (2020): 575-580. doi: https://doi.org/10.22038/abjs.2020.39006.2042
Apfel A, Lin CC, Burfeind W, Dillon MT, Navarro RA. Characteristics of Rotator Cuff Repairs Revised to Shoulder Arthroplasty. Arch Bone Jt Surg. 2020 Sep;8(5):575-580. doi: 10.22038/abjs.2020.39006.2042. PMID: 33088858; PMCID: PMC7547172.
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Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two-Electron and Four-Electron Oxygen Reduction with Cobalt Porphyrin Atropisomers.

Angewandte Chemie (International ed. in English)

Lv B, Li X, Guo K, Ma J, Wang Y, Lei H, Wang F, Jin X, Zhang Q, Zhang W, Long R, Xiong Y, Apfel UP, Cao R.
PMID: 33742485
Angew Chem Int Ed Engl. 2021 Jun 01;60(23):12742-12746. doi: 10.1002/anie.202102523. Epub 2021 Apr 16.

Achieving a selective 2 e

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Lv B, Li X, Guo K, et al. Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two-Electron and Four-Electron Oxygen Reduction with Cobalt Porphyrin Atropisomers. Angew Chem Int Ed Engl. 2021;60(23):12742-12746doi: 10.1002/anie.202102523.
Lv, B., Li, X., Guo, K., Ma, J., Wang, Y., Lei, H., Wang, F., Jin, X., Zhang, Q., Zhang, W., Long, R., Xiong, Y., Apfel, U. P., & Cao, R. (2021). Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two-Electron and Four-Electron Oxygen Reduction with Cobalt Porphyrin Atropisomers. Angewandte Chemie (International ed. in English), 60(23), 12742-12746. https://doi.org/10.1002/anie.202102523
Lv, Bin, et al. "Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two-Electron and Four-Electron Oxygen Reduction with Cobalt Porphyrin Atropisomers." Angewandte Chemie (International ed. in English) vol. 60,23 (2021): 12742-12746. doi: https://doi.org/10.1002/anie.202102523
Lv B, Li X, Guo K, Ma J, Wang Y, Lei H, Wang F, Jin X, Zhang Q, Zhang W, Long R, Xiong Y, Apfel UP, Cao R. Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two-Electron and Four-Electron Oxygen Reduction with Cobalt Porphyrin Atropisomers. Angew Chem Int Ed Engl. 2021 Jun 01;60(23):12742-12746. doi: 10.1002/anie.202102523. Epub 2021 Apr 16. PMID: 33742485.
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Showing 13 to 24 of 119 entries