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Showing 13 to 24 of 136 entries
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A Rapid Synthesis of Some 1,4-aryldiazines by the Use of Lithium Chloride as an Effective Catalyst.

Acta chimica Slovenica

Karami B, Rooydel R, Saeed K.
PMID: 24061189
Acta Chim Slov. 2012 Mar;59(1):183-8.

The synthesis of some 1,4-aryldiazines (novel and known dibenzo[a,c]phenazines and quinoxalines) based on the condensation of 1,2-aryldiamines with aromatic 1,2-dicarbonyl compounds in the presence of lithium chloride as a heterogeneous catalyst is presented as convenient and efficient strategy. This...

Eco-friendly approach to access of quinoxaline derivatives using nanostructured pyrophosphate Na.

BMC chemistry

Dânoun K, Essamlali Y, Amadine O, Mahi H, Zahouily M.
PMID: 32025664
BMC Chem. 2020 Feb 03;14(1):6. doi: 10.1186/s13065-020-0662-z. eCollection 2020 Dec.

In the present study, we report the synthesis of various quinoxaline derivatives from direct condensation of substituted aromatic 1,2-diamine with 1,2-dicarbonyl catalyzed by nanostructured pyrophosphate Na

Green Hydrothermal Synthesis of Fluorescent 2,3-Diarylquinoxalines and Large-Scale Computational Comparison to Existing Alternatives.

ChemSusChem

Amaya-García F, Caldera M, Koren A, Kubicek S, Menche J, Unterlass MM.
PMID: 33662183
ChemSusChem. 2021 Apr 22;14(8):1853-1863. doi: 10.1002/cssc.202100433. Epub 2021 Mar 26.

Here, the hydrothermal synthesis (HTS) of 2,3-diarylquinoxalines from 1,2-diketones and o-phenylendiamines (o-PDAs) was achieved. The synthesis is simple, fast, and generates high yields, without requiring any organic solvents, strong acids or toxic catalysts. Reaction times down to 90 %...

Manganese catalyzed C-alkylation of methyl N-heteroarenes with primary alcohols.

Chemical communications (Cambridge, England)

Jana A, Kumar A, Maji B.
PMID: 33624678
Chem Commun (Camb). 2021 Mar 25;57(24):3026-3029. doi: 10.1039/d1cc00181g. Epub 2021 Feb 24.

C-Alkylations of nine different classes of methyl-substituted N-heteroarenes, including quinolines, quinoxalines, benzimidazoles, benzoxazoles, pyrazines, pyrimidines, pyridazines, pyridines, and triazines are disclosed. A bench stable earth-abundant Mn(i)-complex catalyzed the chemoselective hydrogen-transfer reaction utilizing a diverse range of primary alcohols as...

Natural vs. Synthetic Phosphate as Efficient Heterogeneous Compounds for Synthesis of Quinoxalines.

International journal of molecular sciences

Amini A, Fallah A, Sedaghat A, Gholami A, Cheng C, Gupta AR.
PMID: 34948460
Int J Mol Sci. 2021 Dec 20;22(24). doi: 10.3390/ijms222413665.

Natural phosphate (NP) and synthetic fluorapatite phosphate (SFAP) were proposed as stable, inexpensive, readily available and recyclable catalysts for the condensation of 1,2-diamines with 1,2-dicarbonyls in methanol to afford quinoxaline at room temperature. NP provided as high as 92-99%...

Nickel-Catalyzed Direct Synthesis of Quinoxalines from 2-Nitroanilines and Vicinal Diols: Identifying Nature of the Active Catalyst.

The Journal of organic chemistry

Shee S, Panja D, Kundu S.
PMID: 31903762
J Org Chem. 2020 Feb 21;85(4):2775-2784. doi: 10.1021/acs.joc.9b03104. Epub 2020 Jan 17.

The inexpensive and simple NiBr

Y-shaped ferrocene/non-ferrocene conjugated quinoxalines for colorimetric and fluorimetric detection of picric acid.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy

Rajalakshmi AV, Palanisami N.
PMID: 31787532
Spectrochim Acta A Mol Biomol Spectrosc. 2020 Mar 05;228:117812. doi: 10.1016/j.saa.2019.117812. Epub 2019 Nov 19.

New Y-shaped ferrocene and non-ferrocene conjugated quinoxaline derivatives {[R-(CH)

Electrochemical Characterization of Aromatic Molecules with 1,4-Diaza Groups for Flow Battery Applications.

Molecules (Basel, Switzerland)

Pasadakis-Kavounis A, Baj V, Hjelm J.
PMID: 33921498
Molecules. 2021 Apr 12;26(8). doi: 10.3390/molecules26082227.

The aqueous redox flow battery is a promising technology for large-scale low cost energy storage. The rich possibilities for the tailoring of organic molecules and the possibility to discover active materials of lower cost and decreased environmental impact continue...

Singly and Doubly Quinoxaline-Fused B.

Chemistry (Weinheim an der Bergstrasse, Germany)

Kise K, Osuka A.
PMID: 31692130
Chemistry. 2019 Dec 05;25(68):15493-15497. doi: 10.1002/chem.201904151. Epub 2019 Nov 06.

B-Phenyl B

New fluorescent light-up quinoxalines differentiate between parallel and nonparallel G-quadruplex topologies using different excitation/emission channels.

Chemical communications (Cambridge, England)

Hu MH, Chen X.
PMID: 32215383
Chem Commun (Camb). 2020 Apr 14;56(30):4168-4171. doi: 10.1039/d0cc01242d.

In this study, new fluorescent quinoxalines were developed as G4 topology-selective probes. Among them, the most promising one could light up parallel G4s at two separate excitation wavelengths, exhibiting dual-channel emission, and light up nonparallel G4s at one excitation...

2,3-(Dibenzimidazol-2-yl)quinoxalines: Unexpected Dynamical Effect on Steady-State Electronic Absorption Spectra.

The journal of physical chemistry. B

Burganov TI, Monari A, Katsyuba SA, Mamedov VA, Zhukova NA, Assfeld X.
PMID: 31192599
J Phys Chem B. 2019 Jul 05;123(26):5514-5523. doi: 10.1021/acs.jpcb.9b00974. Epub 2019 Jun 26.

We report on the electronic absorption spectra, conformational behavior, and intra- and intermolecular hydrogen bonds of 2,3-(dibenzimidazol-2-yl)-quinoxaline (DBIQ). The experimentally found strong solvent dependence of the absorption spectra of DBIQ solutions cannot be assigned to electronic excitations of the...

Phosphine free Mn-complex catalysed dehydrogenative C-C and C-heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine, benzothiazole and quinoline derivatives.

Chemical communications (Cambridge, England)

Das K, Mondal A, Srimani D.
PMID: 30167623
Chem Commun (Camb). 2018 Sep 18;54(75):10582-10585. doi: 10.1039/c8cc05877f.

Herein the first sustainable synthesis of quinoxalines, pyrazines and benzothiazoles catalysed by a phosphine free Mn(i) complex via acceptorless dehydrogenative coupling (ADC) is reported. This method is also applied successfully to synthesize quinolines via the dehydrogenation (removal of H2)...

Showing 13 to 24 of 136 entries