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Showing 217 to 228 of 228 entries
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Alkylammoniotrifluoroborate functionalized polystyrenes: polymeric pre-catalysts for the metal-free borylation of heteroarenes.

Dalton transactions (Cambridge, England : 2003)

Bouchard N, Fontaine FG.
PMID: 30869102
Dalton Trans. 2019 Apr 09;48(15):4846-4856. doi: 10.1039/c9dt00484j.

Three polymeric versions of ansa-N,N-dialkylammoniumtrifluoroborate ambiphilic molecules based on the styrene motif (poly(1-NMe2H+-2-BF3--4-styrene) (P-Me), poly(1-NEt2H+-2-BF3--4-styrene) (P-Et) and poly(1-piperidinyl-H+-2-BF3--4-styrene) (P-Pip)) were synthesized, characterized and tested as heterogeneous pre-catalysts for the borylation of electron-rich heteroarenes. These heterogeneous versions of previously reported...

Investigation of the Internal Chemical Composition of Chitosan-Based LbL Films by Depth-Profiling X-ray Photoelectron Spectroscopy (XPS) Analysis.

Langmuir : the ACS journal of surfaces and colloids

Taketa TB, Dos Santos DM, Fiamingo A, Vaz JM, Beppu MM, Campana-Filho SP, Cohen RE, Rubner MF.
PMID: 29307187
Langmuir. 2018 Jan 30;34(4):1429-1440. doi: 10.1021/acs.langmuir.7b04104. Epub 2018 Jan 19.

Chitosan-based thin films were assembled using the layer-by-layer technique, and the axial composition was accessed using X-ray photoelectron spectroscopy with depth profiling. Chitosan (CHI) samples possessing different degrees of acetylation ([Formula: see text]) and molecular weight ([Formula: see text])...

Universal size properties of a star-ring polymer structure in disordered environments.

Physical review. E

Haydukivska K, Blavatska V.
PMID: 29776140
Phys Rev E. 2018 Mar;97(3):032502. doi: 10.1103/PhysRevE.97.032502.

We consider the complex polymer system, consisting of a ring polymer connected to the f_{1}-branched starlike structure, in a good solvent in the presence of structural inhomogeneities. In particular cases f_{1}=1 and f_{1}=2, such a system restores the synthesized...

Optoelectronic Evaluation and Loss Analysis of PEDOT:PSS/Si Hybrid Heterojunction Solar Cells.

Nanoscale research letters

Yang Z, Fang Z, Sheng J, Ling Z, Liu Z, Zhu J, Gao P, Ye J.
PMID: 28070837
Nanoscale Res Lett. 2017 Dec;12(1):26. doi: 10.1186/s11671-016-1790-1. Epub 2017 Jan 09.

The organic/silicon (Si) hybrid heterojunction solar cells (HHSCs) have attracted considerable attention due to their potential advantages in high efficiency and low cost. However, as a newly arisen photovoltaic device, its current efficiency is still much worse than commercially...

Tuning the gas sensing performance of single PEDOT nanowire devices.

The Analyst

Hangarter CM, Hernandez SC, He X, Chartuprayoon N, Choa YH, Myung NV.
PMID: 21509374
Analyst. 2011 Jun 07;136(11):2350-8. doi: 10.1039/c0an01000f. Epub 2011 Apr 21.

This paper reports the synthesis and dopant dependent electrical and sensing properties of single poly(ethylenedioxythiophene) (PEDOT) nanowire sensors. Dopant type (i.e. polystyrenesulfonate (PSS(-)) and perchlorate (ClO(4)(-))) and solvent (i.e. acetonitrile and 1 : 1 water-acetonitrile mixture) were adjusted to...

Isospecific (Co)polymerization of Unmasked Polar Styrenes by Neutral Rare-Earth Metal Catalysts.

Angewandte Chemie (International ed. in English)

Jiang Y, Zhang Z, Li S, Cui D.
PMID: 34931421
Angew Chem Int Ed Engl. 2021 Dec 20;e202112966. doi: 10.1002/anie.202112966. Epub 2021 Dec 20.

Syndioselective polymerization of unprotected polar styrenes has achieved great success via specially designed catalysts and the establishment of "self-assisted" theory. In contrast, isospecific polymerization of polar styrenes has remained less explored. Herein, we present new racemic ansa-bis(benz[e]indenyl) rare-earth metal...

Remarkable untangled dynamics behavior of multicyclic branched polystyrenes.

Chemical communications (Cambridge, England)

Xue X, Chen Y, Li Y, Liang K, Huang W, Yang H, Jiang L, Jiang Q, Chen F, Jiang T, Lin B, Jiang B, Pu H.
PMID: 33326513
Chem Commun (Camb). 2021 Jan 14;57(3):399-402. doi: 10.1039/d0cc07129c.

A typical multicyclic branched-topology polystyrene (c-BPS) with high molecular weight (30 K ≤ Mw MALLS ≤ 300 K g mol-1) and narrow dispersity (1.2 ≤ Đ ≤ 1.3) was efficiently synthesized by combining atom transfer radical polymerization (ATRP) and...

Detection of polymer compatibility by means of self-organization: poly(ethylene oxide) and poly(sodium 4-styrenesulfonate).

Soft matter

Bercea M, Wolf BA.
PMID: 33949591
Soft Matter. 2021 May 26;17(20):5214-5220. doi: 10.1039/d1sm00170a.

Information on the miscibility of different polymers A and B on a molecular level is important in many ways. However, along the traditional lines this knowledge is difficult and time consuming to achieve. The current study presents a simple...

Anisotropy and anharmonicity in polystyrene stable glass.

The Journal of chemical physics

Raegen AN, Zhou Q, Forrest JA.
PMID: 33291898
J Chem Phys. 2020 Dec 07;153(21):214508. doi: 10.1063/5.0032153.

We have used ellipsometry to characterize the anisotropy in stable polymer glasses prepared by physical vapor deposition. These measurements reveal birefringence values (as measured by the magnitude of in-plane vs out-of-plane refractive index) less than 0.002 in vapor-deposited polystyrenes...

Efficient, long-range energy migration in Ru(II) polypyridyl derivatized polystyrenes in rigid media. Antennae for artificial photosynthesis.

Dalton transactions (Cambridge, England : 2003)

Fleming CN, Brennaman MK, Papanikolas JM, Meyer TJ.
PMID: 19440588
Dalton Trans. 2009 May 28;(20):3903-10. doi: 10.1039/b821162k. Epub 2009 Feb 26.

Results of CW and lifetime emission studies have been used to demonstrate facile intra-strand energy transfer in the derivatized polystyrene polymer [PS-4-CH(2)CH(2)NHC(O)-(Ru(II)(4,4'-(CONEt(2))(2)bpy)(2))(17)(Os(II)(bpy)(2)))(3)](PF(6))(40) in four rigid media: frozen 5:4 (v:v) propionitrile:butyronitrile solutions at 77 K, polymethyl-methacrylate (PMMA) and polyethylene glycol-dimethacrylate...

Synthesis of Terpyridine End-Modified Polystyrenes through ATRP for Facile Construction of Metallo-Supramolecular P3HT-.

Polymers

Tu TH, Chan YT.
PMID: 33260312
Polymers (Basel). 2020 Nov 29;12(12). doi: 10.3390/polym12122842.

Complementary complexation between 2,2':6',2″-terpyridine (tpy) and 6,6″-dianthracenyl-substituted tpy in the presence of Zn(II) ions provided an efficient strategy for construction of metallo-supramolecular diblock copolymers. To synthesize well-defined tpy-modified polystyrenes (PSs), an Fe(II) bis(tpy) complex bearing α-bromoester as a metallo-initiator...

Dynamic Polymer Free Volume Monitored by Single-Molecule Spectroscopy of a Dual Fluorescent Flapping Dopant.

Journal of the American Chemical Society

Goto Y, Omagari S, Sato R, Yamakado T, Achiwa R, Dey N, Suga K, Vacha M, Saito S.
PMID: 34448563
J Am Chem Soc. 2021 Sep 08;143(35):14306-14313. doi: 10.1021/jacs.1c06428. Epub 2021 Aug 27.

Single-molecule spectroscopy (SMS) of a dual fluorescent flapping molecular probe (N-FLAP) enabled real-time nanoscale monitoring of local free volume dynamics in polystyrenes. The SMS study was realized by structural improvement of a previously reported flapping molecule by nitrogen substitution,...

Showing 217 to 228 of 228 entries