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Kinetic resolution and unusual regioselectivity in palladium-catalyzed allylic alkylations with a chiral P,S ligand.

Organic letters

Faller JW, Wilt JC, Parr J.
PMID: 15070322
Org Lett. 2004 Apr 15;6(8):1301-4. doi: 10.1021/ol0497382.

Effective kinetic resolutions of acyclic allylic acetates and benzoates have been obtained using a palladium/(S)-BINAP(S) catalyst system. Unusually large preferences for the formation of branched alkylation products from 3-but-2-enyl and crotyl substrates have been observed. [reaction: see text]

Continuous system with microwave irradiation to obtain alkyl benzoates.

Talanta

Cáceres A, Jaimes M, Chávez G, Bravo B, Ysambertt F, Márquez N.
PMID: 18970330
Talanta. 2005 Dec 15;68(2):359-64. doi: 10.1016/j.talanta.2005.08.067. Epub 2005 Oct 07.

In this study, a continuous linear alcohol derivatization is developed. Reaction of alcohol group (ROH) with benzoyl chloride (BC) is carried out in an on-line system with UV detection. All reaction conditions, as flow rate (FR), ROH/BC molar ratio,...

Acetates and benzoates of alkyl catechols and evaluation of their antibacterial activity.

Pakistan journal of pharmaceutical sciences

Siddiqui BS, Begum S, Adil Q, Akber M, Firdous S, Khan KA, Khan SA, Khalid SM.
PMID: 16414796
Pak J Pharm Sci. 1997 Jul;10(2):1-12.

Potential biologically active alkyl catechol esters were prepared and their antibacterial activity was determined against 12 Gram-positive and 16 Gram-negative bacteria. Esterification (acetylation and benzoylation) of mono-, di- and tetra- substituted alkyl catechols afforded the di-acetyl and di-benzoyl derivatives...

Effect of o-methyl group on rate, mechanism, and resonance contribution: aminolysis of Y-substituted phenyl X-substituted 2-methylbenzoates.

The Journal of organic chemistry

Um IH, Lee JY, Lee HW, Nagano Y, Fujio M, Tsuno Y.
PMID: 15960495
J Org Chem. 2005 Jun 24;70(13):4980-7. doi: 10.1021/jo050172k.

Second-order rate constants have been determined spectrophotometrically for the reactions of 4-nitrophenyl X-substituted 2-methylbenzoates (2a-e) and Y-substituted phenyl 2-methylbenzoates (3a-e) with alicyclic secondary amines in 80 mol % H(2)O/20 mol % DMSO at 25.0 +/- 0.1 degrees C. The...

Chemotactic Preferences and Strain Variation in the Response of Phytophthora sojae Zoospores to Host Isoflavones.

Applied and environmental microbiology

Tyler BM, Wu M, Wang J, Cheung W, Morris PF.
PMID: 16535375
Appl Environ Microbiol. 1996 Aug;62(8):2811-7. doi: 10.1128/aem.62.8.2811-2817.1996.

The zoospores of Phytophthora sojae are chemotactically attracted to the isoflavones genistein and daidzein that are released by soybean roots. In this study we have examined the response of P. sojae zoospores to a wide range of compounds having...

Molecular evolution using intramolecular acyl migration on myo-inositol benzoates with thermodynamic and kinetic selectors.

Chemistry (Weinheim an der Bergstrasse, Germany)

Ahn YH, Chang YT.
PMID: 15252801
Chemistry. 2004 Jul 19;10(14):3543-7. doi: 10.1002/chem.200400234.

A molecular evolution model was successfully demonstrated by combining the intramolecular acyl migration on inositol tribenzoates and boron selectors. The addition of boric acid to 12 members of DCL (dynamic combinatorial library) induced the dramatic amplification of myo-I(2,4,6)Bz(3) (1)...

[Mn7O5(OR)2(O2CPh)9(terpy)] (R = Me, CH2Ph) complexes with a fused cubane/butterfly core and an S = 6 ground-state spin.

Inorganic chemistry

Mishra A, Wernsdorfer W, Abboud KA, Christou G.
PMID: 17140227
Inorg Chem. 2006 Dec 11;45(25):10197-206. doi: 10.1021/ic061334d.

Two new heptanuclear Mn clusters, [Mn7O5(OMe)2(O2CPh)9(terpy)] (1) and [Mn7O5(OCH2Ph)2(O2CPh)9(terpy)] (2), were prepared from the partial alcoholysis of the trinuclear complex [Mn3O(O2CPh)6(py)2(H2O)] (3) in the presence of terpy (terpy = 2,2':6',2' '-terpyridine). Complexes 1 and 2 crystallize in the triclinic...

Regioselective control in the oxidative cleavage of 4,6-O-benzylidene acetals of glycopyranosides by dimethyldioxirane.

The Journal of organic chemistry

Stévenin A, Boyer FD, Beau JM.
PMID: 20136154
J Org Chem. 2010 Mar 05;75(5):1783-6. doi: 10.1021/jo9026098.

The oxidative cleavage of 4,6-O-benzylidene acetals of glycopyranosides using dimethyldioxirane (DMDO) leads to the corresponding hydroxy-benzoates in excellent yields. With a proper choice of the neighboring protecting groups, this oxidative fragmentation provides the 6- or 4-hydroxyl derivatives in a...

Gold-catalyzed homogeneous oxidative C-O bond formation: efficient synthesis of 1-benzoxyvinyl ketones.

Journal of the American Chemical Society

Peng Y, Cui L, Zhang G, Zhang L.
PMID: 19301899
J Am Chem Soc. 2009 Apr 15;131(14):5062-3. doi: 10.1021/ja901048w.

A novel Au-catalyzed homogeneous oxidative C-O bond-forming reaction involving a Au(I)/Au(III) catalytic cycle is developed. Mechanistic studies reveal the involvement of a unique intramolecular carboxy migration. From readily available propargylic benzoates, this chemistry allows efficient access to captodative alkenes...

Structural characterization and quantitation of compound loading of disubstituted benzoates bound to Wang resin through high-resolution magic angle spinning NMR spectroscopy.

Magnetic resonance in chemistry : MRC

Blas J, Rivera-Sagredo A, Ferritto R, Espinosa JF.
PMID: 15386546
Magn Reson Chem. 2004 Nov;42(11):950-4. doi: 10.1002/mrc.1478.

The combination of 1D and 2D high-resolution magic angle spinning NMR experiments led to the assignment of the proton and carbon resonances for several disubstituted benzoates bound to a polystyrene resin through a Wang linker. It is shown that...

[Enantioseparation of 1,1'-bi-2-naphthol benzoates using high performance liquid chromatography].

Se pu = Chinese journal of chromatography

Wang L, Xu X, Chen G, Ruan Y.
PMID: 20549984
Se Pu. 2010 Mar;28(3):305-10. doi: 10.3724/sp.j.1123.2010.00305.

The enantioseparations of 2'-hydroxy-1,1'-binaphthyl-2-yl benzoate (HBNB), 1,1'-binaphthyl-2,2'-diyl dibenzoate (BNDB) and 2'-methoxy-1,1'-binaphthyl-2-yl benzoate (MBNB) were studied on Chirex (S)-LEU & (S)-NEA, cellulose tris (3,5-dimethylphenylcarbamate) (Chiralcel OD-H) and amylose tris (3,5-dimethylphenyl-carbamate) (Chiralpak AD-H) columns, respectively, using high performance liquid chromatography. The...

Nanophase segregation in binary mixtures of a bent-core and a rodlike liquid-crystal molecule.

Physical review. E, Statistical, nonlinear, and soft matter physics

Zhu C, Chen D, Shen Y, Jones CD, Glaser MA, Maclennan JE, Clark NA.
PMID: 20365388
Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Jan;81(1):011704. doi: 10.1103/PhysRevE.81.011704. Epub 2010 Jan 22.

We studied mixtures of the achiral bent-core mesogen NOBOW 1,3-phenylene bis[4-(4-9-alkoxyphenyliminonetyl)benzoates] (P-9-O-PIMB) and the small, rodlike liquid crystal 8CB using high-resolution synchrotron x-ray diffraction, freeze fracture transmission electron microscopy, and differential scanning calorimetry. NOBOW and 8CB mix in an...

Showing 13 to 24 of 215 entries