Advanced Search
Display options
Filter resources
Text Availability
Article type
Publication date
Species
Language
Sex
Age
Showing 37 to 45 of 45 entries
Sorted by: Best Match Show Resources per page
Overcoming challenges in the palladium-catalyzed synthesis of electron deficient ortho-substituted aryl acetonitriles.

Organic & biomolecular chemistry

Brannock MC, Behof WJ, Morrison G, Gorman CB.
PMID: 21365100
Org Biomol Chem. 2011 Apr 21;9(8):2661-6. doi: 10.1039/c0ob00903b. Epub 2011 Mar 02.

Highly electron deficient monoaryl, di-aryl and bis-diaryl acetonitriles were effectively synthesized using either a nucleophilic aromatic substitution (NAS) or a palladium-mediated coupling pathway. Synthesis of di-aryl acetonitriles most conveniently proceeded via NAS--palladium-mediated coupling was not required. This reaction, however,...

Cite
Brannock MC, Behof WJ, Morrison G, et al. Overcoming challenges in the palladium-catalyzed synthesis of electron deficient ortho-substituted aryl acetonitriles. Org Biomol Chem. 2011;9(8):2661-6doi: 10.1039/c0ob00903b.
Brannock, M. C., Behof, W. J., Morrison, G., & Gorman, C. B. (2011). Overcoming challenges in the palladium-catalyzed synthesis of electron deficient ortho-substituted aryl acetonitriles. Organic & biomolecular chemistry, 9(8), 2661-6. https://doi.org/10.1039/c0ob00903b
Brannock, Molly C, et al. "Overcoming challenges in the palladium-catalyzed synthesis of electron deficient ortho-substituted aryl acetonitriles." Organic & biomolecular chemistry vol. 9,8 (2011): 2661-6. doi: https://doi.org/10.1039/c0ob00903b
Brannock MC, Behof WJ, Morrison G, Gorman CB. Overcoming challenges in the palladium-catalyzed synthesis of electron deficient ortho-substituted aryl acetonitriles. Org Biomol Chem. 2011 Apr 21;9(8):2661-6. doi: 10.1039/c0ob00903b. Epub 2011 Mar 02. PMID: 21365100.
Copy Download .nbib Format: NLM
First row transition metal(II) thiocyanate complexes, and formation of 1-, 2-, and 3-dimensional extended network structures of M(NCS)2(solvent)2 (M = Cr, Mn, Co) composition.

Inorganic chemistry

Shurdha E, Moore CE, Rheingold AL, Lapidus SH, Stephens PW, Arif AM, Miller JS.
PMID: 23981238
Inorg Chem. 2013 Sep 16;52(18):10583-94. doi: 10.1021/ic401558f. Epub 2013 Aug 27.

The reaction of first row transition M(II) ions with KSCN in various solvents form tetrahedral (NMe4)2[M(II)(NCS)4] (M = Fe, Co), octahedral trans-M(II)(NCS)2(Sol)4 (M = Fe, V, Ni; Sol = MeCN, THF), and K4[M(II)(NCS)6] (M = V, Ni). The reaction...

Cite
Shurdha E, Moore CE, Rheingold AL, et al. First row transition metal(II) thiocyanate complexes, and formation of 1-, 2-, and 3-dimensional extended network structures of M(NCS)2(solvent)2 (M = Cr, Mn, Co) composition. Inorg Chem. 2013;52(18):10583-94doi: 10.1021/ic401558f.
Shurdha, E., Moore, C. E., Rheingold, A. L., Lapidus, S. H., Stephens, P. W., Arif, A. M., & Miller, J. S. (2013). First row transition metal(II) thiocyanate complexes, and formation of 1-, 2-, and 3-dimensional extended network structures of M(NCS)2(solvent)2 (M = Cr, Mn, Co) composition. Inorganic chemistry, 52(18), 10583-94. https://doi.org/10.1021/ic401558f
Shurdha, Endrit, et al. "First row transition metal(II) thiocyanate complexes, and formation of 1-, 2-, and 3-dimensional extended network structures of M(NCS)2(solvent)2 (M = Cr, Mn, Co) composition." Inorganic chemistry vol. 52,18 (2013): 10583-94. doi: https://doi.org/10.1021/ic401558f
Shurdha E, Moore CE, Rheingold AL, Lapidus SH, Stephens PW, Arif AM, Miller JS. First row transition metal(II) thiocyanate complexes, and formation of 1-, 2-, and 3-dimensional extended network structures of M(NCS)2(solvent)2 (M = Cr, Mn, Co) composition. Inorg Chem. 2013 Sep 16;52(18):10583-94. doi: 10.1021/ic401558f. Epub 2013 Aug 27. PMID: 23981238.
Copy Download .nbib Format: NLM
Reactions of 3-(.

Beilstein journal of organic chemistry

Sağırlı A, Dürüst Y.
PMID: 30591824
Beilstein J Org Chem. 2018 Dec 10;14:3011-3017. doi: 10.3762/bjoc.14.280. eCollection 2018.

The present work describes an unfamiliar reaction of 5-(chloromethyl)-3-substituted-phenyl-1,2,4-oxadiazoles with KCN affording trisubstituted 1,2,4-oxadiazol-5-ylacetonitriles and their parent alkanes, namely, 1,2,3-trisubstituted-1,2,4-oxadiazol-5-ylpropanes. To the best of our knowledge, the current synthetic route leading to decyanated products will be the first in...

Cite
Sağırlı A, Dürüst Y. Reactions of 3-(. Beilstein J Org Chem. 2018;14:3011-3017doi: 10.3762/bjoc.14.280.
Sağırlı, A., & Dürüst, Y. (2018). Reactions of 3-(. Beilstein journal of organic chemistry, 143011-3017. https://doi.org/10.3762/bjoc.14.280
Sağırlı, Akın, and Dürüst, Yaşar. "Reactions of 3-(." Beilstein journal of organic chemistry vol. 14 (2018): 3011-3017. doi: https://doi.org/10.3762/bjoc.14.280
Sağırlı A, Dürüst Y. Reactions of 3-(. Beilstein J Org Chem. 2018 Dec 10;14:3011-3017. doi: 10.3762/bjoc.14.280. eCollection 2018. PMID: 30591824; PMCID: PMC6296410.
Copy Download .nbib Format: NLM
Nickel-catalyzed hydrogen-borrowing strategy: chemo-selective alkylation of nitriles with alcohols.

Chemical communications (Cambridge, England)

Bera S, Bera A, Banerjee D.
PMID: 32432612
Chem Commun (Camb). 2020 Jun 23;56(50):6850-6853. doi: 10.1039/d0cc02261f.

The first nickel-catalyzed hydrogen-borrowing alkylation of a series of aryl acetonitriles with a variety of aryl, heteroaryl, allylic and alkyl alcohols releasing water as the by-product (>33 examples, up to 90% yield) is reported.

Cite
Bera S, Bera A, Banerjee D. Nickel-catalyzed hydrogen-borrowing strategy: chemo-selective alkylation of nitriles with alcohols. Chem Commun (Camb). 2020;56(50):6850-6853doi: 10.1039/d0cc02261f.
Bera, S., Bera, A., & Banerjee, D. (2020). Nickel-catalyzed hydrogen-borrowing strategy: chemo-selective alkylation of nitriles with alcohols. Chemical communications (Cambridge, England), 56(50), 6850-6853. https://doi.org/10.1039/d0cc02261f
Bera, Sourajit, et al. "Nickel-catalyzed hydrogen-borrowing strategy: chemo-selective alkylation of nitriles with alcohols." Chemical communications (Cambridge, England) vol. 56,50 (2020): 6850-6853. doi: https://doi.org/10.1039/d0cc02261f
Bera S, Bera A, Banerjee D. Nickel-catalyzed hydrogen-borrowing strategy: chemo-selective alkylation of nitriles with alcohols. Chem Commun (Camb). 2020 Jun 23;56(50):6850-6853. doi: 10.1039/d0cc02261f. PMID: 32432612.
Copy Download .nbib Format: NLM
Bis-Cyclometalated Indazole Chiral-at-Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations.

Chemistry (Weinheim an der Bergstrasse, Germany)

Steinlandt PS, Zuo W, Harms K, Meggers E.
PMID: 31541505
Chemistry. 2019 Dec 02;25(67):15333-15340. doi: 10.1002/chem.201903369. Epub 2019 Nov 13.

A new class of bis-cyclometalated rhodium(III) catalysts containing two inert cyclometalated 6-tert-butyl-2-phenyl-2H-indazole ligands and two labile acetonitriles is introduced. Single enantiomers (>99 % ee) were obtained through a chiral-auxiliary-mediated approach using a monofluorinated salicyloxazoline. The new chiral-at-metal complex is...

Cite
Steinlandt PS, Zuo W, Harms K, et al. Bis-Cyclometalated Indazole Chiral-at-Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations. Chemistry. 2019;25(67):15333-15340doi: 10.1002/chem.201903369.
Steinlandt, P. S., Zuo, W., Harms, K., & Meggers, E. (2019). Bis-Cyclometalated Indazole Chiral-at-Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations. Chemistry (Weinheim an der Bergstrasse, Germany), 25(67), 15333-15340. https://doi.org/10.1002/chem.201903369
Steinlandt, Philipp S, et al. "Bis-Cyclometalated Indazole Chiral-at-Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations." Chemistry (Weinheim an der Bergstrasse, Germany) vol. 25,67 (2019): 15333-15340. doi: https://doi.org/10.1002/chem.201903369
Steinlandt PS, Zuo W, Harms K, Meggers E. Bis-Cyclometalated Indazole Chiral-at-Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations. Chemistry. 2019 Dec 02;25(67):15333-15340. doi: 10.1002/chem.201903369. Epub 2019 Nov 13. PMID: 31541505; PMCID: PMC6916287.
Copy Download .nbib Format: NLM
Chiral-at-Iron Catalyst: Expanding the Chemical Space for Asymmetric Earth-Abundant Metal Catalysis.

Journal of the American Chemical Society

Hong Y, Jarrige L, Harms K, Meggers E.
PMID: 30839201
J Am Chem Soc. 2019 Mar 20;141(11):4569-4572. doi: 10.1021/jacs.9b01352. Epub 2019 Mar 06.

A new class of chiral iron catalysts is introduced that contains exclusively achiral ligands with the overall chirality being the result of a stereogenic iron center. Specifically, iron(II) is cis-coordinated to two N-(2-pyridyl)-substituted N-heterocyclic carbene (PyNHC) ligands in a...

Cite
Hong Y, Jarrige L, Harms K, et al. Chiral-at-Iron Catalyst: Expanding the Chemical Space for Asymmetric Earth-Abundant Metal Catalysis. J Am Chem Soc. 2019;141(11):4569-4572doi: 10.1021/jacs.9b01352.
Hong, Y., Jarrige, L., Harms, K., & Meggers, E. (2019). Chiral-at-Iron Catalyst: Expanding the Chemical Space for Asymmetric Earth-Abundant Metal Catalysis. Journal of the American Chemical Society, 141(11), 4569-4572. https://doi.org/10.1021/jacs.9b01352
Hong, Yubiao, et al. "Chiral-at-Iron Catalyst: Expanding the Chemical Space for Asymmetric Earth-Abundant Metal Catalysis." Journal of the American Chemical Society vol. 141,11 (2019): 4569-4572. doi: https://doi.org/10.1021/jacs.9b01352
Hong Y, Jarrige L, Harms K, Meggers E. Chiral-at-Iron Catalyst: Expanding the Chemical Space for Asymmetric Earth-Abundant Metal Catalysis. J Am Chem Soc. 2019 Mar 20;141(11):4569-4572. doi: 10.1021/jacs.9b01352. Epub 2019 Mar 06. PMID: 30839201.
Copy Download .nbib Format: NLM
Active and Recyclable Catalytic Synthesis of Indoles by Reductive Cyclization of 2-(2-Nitroaryl)acetonitriles in the Presence of Co-Rh Heterobimetallic Nanoparticles with Atmospheric Hydrogen under Mild Conditions.

Organic letters

Choi I, Chung H, Park JW, Chung YK.
PMID: 27762564
Org Lett. 2016 Nov 04;18(21):5508-5511. doi: 10.1021/acs.orglett.6b02659. Epub 2016 Oct 20.

A cobalt-rhodium heterobimetallic nanoparticle-catalyzed reductive cyclization of 2-(2-nitroaryl)acetonitriles to indoles has been achieved. The tandem reaction proceeds without any additives under the mild conditions (1 atm H

Cite
Choi I, Chung H, Park JW, et al. Active and Recyclable Catalytic Synthesis of Indoles by Reductive Cyclization of 2-(2-Nitroaryl)acetonitriles in the Presence of Co-Rh Heterobimetallic Nanoparticles with Atmospheric Hydrogen under Mild Conditions. Org Lett. 2016;18(21):5508-5511doi: 10.1021/acs.orglett.6b02659.
Choi, I., Chung, H., Park, J. W., & Chung, Y. K. (2016). Active and Recyclable Catalytic Synthesis of Indoles by Reductive Cyclization of 2-(2-Nitroaryl)acetonitriles in the Presence of Co-Rh Heterobimetallic Nanoparticles with Atmospheric Hydrogen under Mild Conditions. Organic letters, 18(21), 5508-5511. https://doi.org/10.1021/acs.orglett.6b02659
Choi, Isaac, et al. "Active and Recyclable Catalytic Synthesis of Indoles by Reductive Cyclization of 2-(2-Nitroaryl)acetonitriles in the Presence of Co-Rh Heterobimetallic Nanoparticles with Atmospheric Hydrogen under Mild Conditions." Organic letters vol. 18,21 (2016): 5508-5511. doi: https://doi.org/10.1021/acs.orglett.6b02659
Choi I, Chung H, Park JW, Chung YK. Active and Recyclable Catalytic Synthesis of Indoles by Reductive Cyclization of 2-(2-Nitroaryl)acetonitriles in the Presence of Co-Rh Heterobimetallic Nanoparticles with Atmospheric Hydrogen under Mild Conditions. Org Lett. 2016 Nov 04;18(21):5508-5511. doi: 10.1021/acs.orglett.6b02659. Epub 2016 Oct 20. PMID: 27762564.
Copy Download .nbib Format: NLM
Synthesis of Dihydrochromeno[2,3-.

The Journal of organic chemistry

Xiao X, Lu X, Zhang M, Hou H, Wan C, Liu J.
PMID: 34763424
J Org Chem. 2021 Dec 03;86(23):16795-16805. doi: 10.1021/acs.joc.1c02006. Epub 2021 Nov 11.

A tandem cyclization between 2-(2-aminophenyl)acetonitriles and 2-(hydroxy(aryl)methyl)phenols for the preparation of dihydrochromeno[2,3-

Cite
Xiao X, Lu X, Zhang M, et al. Synthesis of Dihydrochromeno[2,3-. J Org Chem. 2021;86(23):16795-16805doi: 10.1021/acs.joc.1c02006.
Xiao, X., Lu, X., Zhang, M., Hou, H., Wan, C., & Liu, J. (2021). Synthesis of Dihydrochromeno[2,3-. The Journal of organic chemistry, 86(23), 16795-16805. https://doi.org/10.1021/acs.joc.1c02006
Xiao, Xi, et al. "Synthesis of Dihydrochromeno[2,3-." The Journal of organic chemistry vol. 86,23 (2021): 16795-16805. doi: https://doi.org/10.1021/acs.joc.1c02006
Xiao X, Lu X, Zhang M, Hou H, Wan C, Liu J. Synthesis of Dihydrochromeno[2,3-. J Org Chem. 2021 Dec 03;86(23):16795-16805. doi: 10.1021/acs.joc.1c02006. Epub 2021 Nov 11. PMID: 34763424.
Copy Download .nbib Format: NLM
Modular Synthesis of Polysubstituted Quinolin-3-amines by Oxidative Cyclization of 2-(2-Isocyanophenyl)acetonitriles with Organoboron Reagents.

Organic letters

Wang S, Xu J, Song Q.
PMID: 34382811
Org Lett. 2021 Sep 03;23(17):6789-6794. doi: 10.1021/acs.orglett.1c02373. Epub 2021 Aug 12.

Polysubstituted quinolin-3-amines are vital structural motifs because of their broad biological activities as well as versatile transformational abilities. However, they are not easily accessible. We disclose a protocol with Mn(III) acetate as a mild one-electron oxidant promoting a radical...

Cite
Wang S, Xu J, Song Q. Modular Synthesis of Polysubstituted Quinolin-3-amines by Oxidative Cyclization of 2-(2-Isocyanophenyl)acetonitriles with Organoboron Reagents. Org Lett. 2021;23(17):6789-6794doi: 10.1021/acs.orglett.1c02373.
Wang, S., Xu, J., & Song, Q. (2021). Modular Synthesis of Polysubstituted Quinolin-3-amines by Oxidative Cyclization of 2-(2-Isocyanophenyl)acetonitriles with Organoboron Reagents. Organic letters, 23(17), 6789-6794. https://doi.org/10.1021/acs.orglett.1c02373
Wang, Shihui, et al. "Modular Synthesis of Polysubstituted Quinolin-3-amines by Oxidative Cyclization of 2-(2-Isocyanophenyl)acetonitriles with Organoboron Reagents." Organic letters vol. 23,17 (2021): 6789-6794. doi: https://doi.org/10.1021/acs.orglett.1c02373
Wang S, Xu J, Song Q. Modular Synthesis of Polysubstituted Quinolin-3-amines by Oxidative Cyclization of 2-(2-Isocyanophenyl)acetonitriles with Organoboron Reagents. Org Lett. 2021 Sep 03;23(17):6789-6794. doi: 10.1021/acs.orglett.1c02373. Epub 2021 Aug 12. PMID: 34382811.
Copy Download .nbib Format: NLM
Showing 37 to 45 of 45 entries