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Gilson SE, Fairley M, Hanna SL, et al. Unusual Metal-Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry. J Am Chem Soc. 2021;143(42):17354-17359doi: 10.1021/jacs.1c08854.
Gilson, S. E., Fairley, M., Hanna, S. L., Szymanowski, J. E. S., Julien, P., Chen, Z., Farha, O. K., LaVerne, J. A., & Burns, P. C. (2021). Unusual Metal-Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry. Journal of the American Chemical Society, 143(42), 17354-17359. https://doi.org/10.1021/jacs.1c08854
Gilson, Sara E, et al. "Unusual Metal-Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry." Journal of the American Chemical Society vol. 143,42 (2021): 17354-17359. doi: https://doi.org/10.1021/jacs.1c08854
Gilson SE, Fairley M, Hanna SL, Szymanowski JES, Julien P, Chen Z, Farha OK, LaVerne JA, Burns PC. Unusual Metal-Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry. J Am Chem Soc. 2021 Oct 27;143(42):17354-17359. doi: 10.1021/jacs.1c08854. Epub 2021 Oct 15. PMID: 34652154.
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J Am Chem Soc. 2021 Oct 27;143(42):17354-17359. doi: 10.1021/jacs.1c08854. Epub 2021 Oct 15.

Unusual Metal-Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry.

Journal of the American Chemical Society

Sara E Gilson, Melissa Fairley, Sylvia L Hanna, Jennifer E S Szymanowski, Patrick Julien, Zhijie Chen, Omar K Farha, Jay A LaVerne, Peter C Burns

Affiliations

  1. Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, United States.
  2. Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, United States.
  3. Department of Chemistry and International Institute of Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.
  4. Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, Indiana 46556, United States.
  5. Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556, United States.

PMID: 34652154 DOI: 10.1021/jacs.1c08854

Abstract

A Np(V) neptunyl metal-organic framework (MOF) with rod-shaped secondary building units was synthesized, characterized, and irradiated with γ rays. Single-crystal X-ray diffraction data revealed an anionic framework containing infinite helical chains of actinyl-actinyl interaction (AAI)-connected neptunyl ions linked together through tetratopic tetrahedral organic ligands (

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