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Li P, Goswami S, Otake KI, et al. Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal-Organic Framework. Inorg Chem. 2019;58(6):3586-3590doi: 10.1021/acs.inorgchem.8b03511.
Li, P., Goswami, S., Otake, K. I., Wang, X., Chen, Z., Hanna, S. L., & Farha, O. K. (2019). Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal-Organic Framework. Inorganic chemistry, 58(6), 3586-3590. https://doi.org/10.1021/acs.inorgchem.8b03511
Li, Peng, et al. "Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal-Organic Framework." Inorganic chemistry vol. 58,6 (2019): 3586-3590. doi: https://doi.org/10.1021/acs.inorgchem.8b03511
Li P, Goswami S, Otake KI, Wang X, Chen Z, Hanna SL, Farha OK. Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal-Organic Framework. Inorg Chem. 2019 Mar 18;58(6):3586-3590. doi: 10.1021/acs.inorgchem.8b03511. Epub 2019 Feb 25. PMID: 30799605.
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Inorg Chem. 2019 Mar 18;58(6):3586-3590. doi: 10.1021/acs.inorgchem.8b03511. Epub 2019 Feb 25.

Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal-Organic Framework.

Inorganic chemistry

Peng Li, Subhadip Goswami, Ken-Ichi Otake, Xingjie Wang, Zhijie Chen, Sylvia L Hanna, Omar K Farha

Affiliations

  1. Department of Chemistry and International Institute of Nanotechnology , Northwestern University , 2145 Sheridan Road , Evanston , Illinois 60208 , United States.
  2. School of Chemistry and Chemical Engineering , South China University of Technology , Guangzhou 510640 , P. R. China.

PMID: 30799605 DOI: 10.1021/acs.inorgchem.8b03511

Abstract

The crystal structures of thorium clusters are important for understanding the formation and transformation mechanisms of actinide species in solution, which can in turns benefit nuclear waste processing and management. However, stabilizing thorium clusters in aqueous solution is quite challenging because of their fast olation and oxolation reactions. Here, we report a thorium-based metal-organic framework, NU-905, with the formula [Th

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