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Sci Rep. 2016 Sep 15;6:33261. doi: 10.1038/srep33261.

High steady-state column density of I((2)P3/2) atoms from I2 photodissociation at 532 nm: Towards parity non-conservation measurements.

Scientific reports

G E Katsoprinakis, G Chatzidrosos, J A Kypriotakis, E Stratakis, T P Rakitzis

Affiliations

  1. Institute of Electronic Structure and Laser, Foundation for Research and Technology-Hellas, 71110 Heraklion-Crete, Greece.
  2. Department of Physics, University of Crete, 71003 Heraklion-Crete, Greece.

PMID: 27629914 PMCID: PMC5024090 DOI: 10.1038/srep33261

Abstract

Steady-state column densities of 10(17) cm(-2) of I((2)P3/2) atoms are produced from photodissociation of I2 vapour at 290.5 K using 5 W of 532 nm laser light. Recombination of the I((2)P3/2) atoms at the cell walls is minimized by coating the cell surface with a hydrophobic silane (dimethyldichlorosilane/DMDCS). Operation at room temperature, and at an I2 vapour pressure of ~0.2 mbar, without using a buffer gas, allows relatively low Lorentz and Doppler widths of ~2π × 1.5 (FWHM) and ~2π × 150 (HW at 1/e(2)) Mrad/s, respectively, at the M1 transition of atomic iodine at 1315 nm. These high column densities and low linewidths are favorable for parity nonconservation optical rotation measurements near this M1 transition. Furthermore, as the cell is completely sealed, this method of production of high-density (127)I((2)P3/2) atoms is also compatible with using iodine radioisotopes, such as for the production of high-density (129)I((2)P3/2).

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