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Showing 1 to 12 of 556 entries
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Carbon dioxide reduction to methylamines under metal-free conditions.

Angewandte Chemie (International ed. in English)

Blondiaux E, Pouessel J, Cantat T.
PMID: 25243949
Angew Chem Int Ed Engl. 2014 Nov 03;53(45):12186-90. doi: 10.1002/anie.201407357. Epub 2014 Sep 22.

The first metal-free catalysts are reported for the methylation of amines with carbon dioxide. Proazaphosphatrane superbases prove to be highly active catalysts in the reductive functionalization of CO2, in the presence of hydroboranes. The new methodology enables the methylation...

Chemical Reduction of Intrinsic Defects in Thicker Heterojunction Planar Perovskite Solar Cells.

Advanced materials (Deerfield Beach, Fla.)

Liu Z, Hu J, Jiao H, Li L, Zheng G, Chen Y, Huang Y, Zhang Q, Shen C, Chen Q, Zhou H.
PMID: 28417481
Adv Mater. 2017 Jun;29(23). doi: 10.1002/adma.201606774. Epub 2017 Apr 18.

Minimization of defects in absorber materials is essential for hybrid perovskite solar cells, especially when constructing thick polycrystalline layers in a planar configuration. Here, a simple methylamine solution-based additive is reported to improve film quality with nearly an order...

How to deal with the "matrix effect" as an unavoidable phenomenon.

European journal of mass spectrometry (Chichester, England)

Ryska M.
PMID: 26307723
Eur J Mass Spectrom (Chichester). 2015;21(3):423-32. doi: 10.1255/ejms.1355.

Adsorption effects in the chromatographic system and/or ion source may play a very important role in the ionization processes of liquid chromatography/mass spectrometry. They have been illustrated and considered as matrix effects extensively. These effects cannot be simply removed...

Hydrogen bonding and orientation effects on the accommodation of methylamine at the air-water interface.

The Journal of chemical physics

Hoehn RD, Carignano MA, Kais S, Zhu C, Zhong J, Zeng XC, Francisco JS, Gladich I.
PMID: 27276960
J Chem Phys. 2016 Jun 07;144(21):214701. doi: 10.1063/1.4950951.

Methylamine is an abundant amine compound detected in the atmosphere which can affect the nature of atmospheric aerosol surfaces, changing their chemical and optical properties. Molecular dynamics simulation results show that methylamine accommodation on water is close to unity...

Effects of basic drugs on prognosis of acute lung injury in mice.

International journal of clinical and experimental medicine

Jia L, Ren J, Zhang W, Qi Y, Zheng L, Guo Y.
PMID: 26770536
Int J Clin Exp Med. 2015 Oct 15;8(10):19079-85. eCollection 2015.

The aim of this study was to investigate the effects of basic drugs that alkalizes blood, on prognosis of acute lung injury in mice. Mice were randomized into three groups: Group normal saline, Group THAM, injected with 3.64% tri-(hydroxymethyl)...

High-Frequency/High-Field Electron Paramagnetic Resonance and Theoretical Studies of Tryptophan-Based Radicals.

The journal of physical chemistry. A

Davis I, Koto T, Terrell JR, Kozhanov A, Krzystek J, Liu A.
PMID: 29488750
J Phys Chem A. 2018 Mar 29;122(12):3170-3176. doi: 10.1021/acs.jpca.7b12434. Epub 2018 Mar 15.

Tryptophan-based free radicals have been implicated in a myriad of catalytic and electron transfer reactions in biology. However, very few of them have been trapped so that biophysical characterizations can be performed in a high-precision context. In this work,...

Novel synthesis of N-alkyl amines from tandem coupling of either methylamine or nitroalkane with aldehyde.

Chemical communications (Cambridge, England)

Lu S, Peng J, Wu J, Li C, Cao X, Gu H.
PMID: 26567982
Chem Commun (Camb). 2016 Jan 14;52(4):760-3. doi: 10.1039/c5cc07807e.

A novel tandem strategy for coupling of either methylamine or nitroalkane with aldehyde has been developed. This is the first demonstration that methylamine or nitroalkane is used as a methylation reagent, fabricating N-alkyl amines. The active Pt NWs allow...

Merger of visible light induced oxidation and enantioselective alkylation with a chiral iridium catalyst.

Chemistry (Weinheim an der Bergstrasse, Germany)

Wang C, Zheng Y, Huo H, Röse P, Zhang L, Harms K, Hilt G, Meggers E.
PMID: 25832794
Chemistry. 2015 May 11;21(20):7355-9. doi: 10.1002/chem.201500998. Epub 2015 Apr 01.

A single chiral octahedral iridium(III) complex is used for visible light activated asymmetric photoredox catalysis. In the presence of a conventional household lamp and under an atmosphere of air, the oxidative coupling of 2-acyl-1-phenylimidazoles with N,N-diaryl-N-(trimethylsilyl)methylamines provides aminoalkylated products...

The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive Layers.

Angewandte Chemie (International ed. in English)

Aristidou N, Sanchez-Molina I, Chotchuangchutchaval T, Brown M, Martinez L, Rath T, Haque SA.
PMID: 26014846
Angew Chem Int Ed Engl. 2015 Jul 06;54(28):8208-12. doi: 10.1002/anie.201503153. Epub 2015 May 27.

In this paper we report on the influence of light and oxygen on the stability of CH3 NH3 PbI3 perovskite-based photoactive layers. When exposed to both light and dry air the mp-Al2 O3 /CH3 NH3 PbI3 photoactive layers rapidly...

Influence of TMAO and urea on the structure of water studied by inelastic X-ray scattering.

Physical chemistry chemical physics : PCCP

Sahle CJ, Schroer MA, Juurinen I, Niskanen J.
PMID: 27270889
Phys Chem Chem Phys. 2016 Jun 28;18(24):16518-26. doi: 10.1039/c6cp01922f. Epub 2016 Jun 07.

We present a study on the influence of the naturally occurring organic osmolytes tri-methylamine N-oxide (TMAO) and urea on the bulk structure of water using X-ray Raman scattering spectroscopy. Addition of TMAO is known to stabilize proteins in otherwise...

Genetic resources for methane production from biomass described with the Gene Ontology.

Frontiers in microbiology

Purwantini E, Torto-Alalibo T, Lomax J, Setubal JC, Tyler BM, Mukhopadhyay B.
PMID: 25520705
Front Microbiol. 2014 Dec 03;5:634. doi: 10.3389/fmicb.2014.00634. eCollection 2014.

Methane (CH4) is a valuable fuel, constituting 70-95% of natural gas, and a potent greenhouse gas. Release of CH4 into the atmosphere contributes to climate change. Biological CH4 production or methanogenesis is mostly performed by methanogens, a group of...

Thylakoid membrane energization and swelling in photoinhibited Chlamydomonas cells is prevented in mutants unable to perform cyclic electron flow.

Photosynthesis research

Topf J, Gong H, Timberg R, Mets L, Ohad I.
PMID: 24408155
Photosynth Res. 1992 Apr;32(1):59-69. doi: 10.1007/BF00028798.

Photoinhibition of Photosystem II in unicellular algae in vivo is accompanied by thylakoid membrane energization and generation of a relatively high ΔpH as demonstrated by (14)C-methylamine uptake in intact cells. Presence of ammonium ions in the medium causes extensive...

Showing 1 to 12 of 556 entries